New evidence for upper Permian crustal growth below Eifel, Germany, from mafic granulite xenoliths

Granulite xenoliths from the Quaternary West Eifel Volcanic Field in Germany record evidence of magmatism in the lower crust at the end of the Permian. The xenoliths sampled two distinct bodies: an older intrusion (ca. 264 Myr old) that contains clinopyroxene with flat, chondrite-normalised rare earth element (REE) profiles and a younger (ca. 253 Myr old) intrusion that crystallised middle-REE-rich clinopyroxene. The younger body is also distinguished based on the negative Sr, Zr and Ti anomalies in primitive mantle-normalised multi-element plots. REE-in-plagioclase–clinopyroxene thermometry records the magmatic temperature of the xenoliths (1100–1300 ∘C), whereas Mg-in-plagioclase and Zr-in-titanite thermometry preserve an equilibration temperature of ca. 800 ∘C. These temperatures, together with a model of the mineral assemblages predicted from the composition of one of the xenoliths, define the pressure of crystallisation as ∼1 GPa. The xenoliths also preserve a long history of reheating events whose age ranges from 220 to 6 Myr. The last of these events presumably led to breakdown of garnet; formation of symplectites of orthopyroxene, plagioclase and hercynite; and redistribution of heavy rare earth elements into clinopyroxene. The data from the West Eifel granulite xenoliths, when combined with the existing data from granulites sampled in the East Eifel, indicate that the lower crust has a long a complex history stretching from at least 1.6 Ga with intrusive events at ca. 410 and 260 Ma and reheating from the Triassic to late Miocene.

Temperature and Emissivity Separation ‘Draping’ Algorithm Applied to Hyperspectral Infrared Data

In the presented work, the spectral emissivity of basaltic melts at magmatic temperatures was retrieved in a laboratory-controlled experiment by measuring their spectral radiance. Granulated bombs of Etnean basalts were melted and the radiant energy from the melting surface was recorded by a portable spectroradiometer in the short wavelength infrared (SWIR) spectral range between 1500 and 2500 nm. The Draping algorithm, an improved algorithm for temperature and emissivity separation, was applied for the first time to SWIR hyperspectral data in order to take into account the non-uniform temperature distribution of the melt surface and, at the same time, solving the two temperatures and the spectral emissivity. The results have been validated by comparing our results with the emissivity measured at a "lava simulator". Basalt spectral emissivity does not vary significantly at magmatic temperature, but shows an absorption feature in the range 2180–2290 nm, an atmospheric window pivotal for the IR remote sensing of active volcanoes.

Gangdese magmatism in southern Tibet and India–Asia convergence since 120 Ma

A compilation of 290 zircon U–Pb ages of intrusive rocks indicates that the Gangdese Batholith in southern Tibet was emplaced from c. 210 Ma to c. 10 Ma. Two intense magmatic pulses within the batholith occur at: (1) 90 ± 5 Ma, which is restricted to 89–94° E in the eastern segment of the southern Lhasa subterrane; and (2) 50 ± 3 Ma, which is widespread across the entire southern Lhasa subterrane. The latter pulse was followed by a phase of widespread but volumetrically small, dominantly felsic adakitic intrusive rocks at 16 ± 2 Ma. The Linzizong volcanism in the Linzhou Basin was active from 60.2 to 52.3 Ma, rather than 69–44 Ma as previously estimated. During 120–75 Ma, Gangdese Batholith magmatism migrated from south to north, arguing against rollback of the downgoing, north-dipping Neo-Tethyan oceanic lithosphere for the generation of the 90 ± 5 Ma magmatic pulse. Petrological, geochemical and metamorphic data indicate that this pulse was likely to have been generated through subduction of the Neo-Tethyan oceanic ridge lithosphere. Subsequent Gangdese Batholith magmatism propagated both south and north during 70–45 Ma, and finally concentrated at the southern margin of the Lhasa Terrane at 45–30 Ma. The enhanced mafic magmatism since c. 70 Ma, magmatic flare-up with compositional diversity at c. 51 Ma and increased magmatic temperature at 52–50 Ma are interpreted as the consequences of slab rollback from c. 70 Ma and slab breakoff of the Neo-Tethyan oceanic lithosphere that began at c. 53 Ma. The India–Asia convergence was driven by Neo-Tethyan subduction with a normal rate of convergence at 120–95 Ma, ridge subduction at 95–85 Ma, then subduction of a young and buoyant oceanic lithosphere after ridge subduction with rate deceleration at 84–67 Ma, Deccan plume activity and slab rollback with rate acceleration at 67–51 Ma, slab breakoff for sudden drop of the convergence rate at c. 51 Ma, and finally the descent of the high-density Indian continental lithosphere beneath Asia since c. 50 Ma.

Importance of Magmatic Water Content and Oxidation State for Porphyry-Style Au Mineralization: An Example from the Giant Beiya Au Deposit, SW China

The Beiya Au deposit is the largest Cenozoic Au deposit in the Jinshajiang-Ailaoshan porphyry metallogenic belt. Numerous studies document that high water content and fO2 are vital factors for the generation of Au mineralization. In this belt, only the Wandongshan and Hongnitang districts are considered to be of economic importance, while the other districts, such as Bailiancun, are barren. So in order to reveal the importance of water content and oxidation state for Beiya porphyry-style Au mineralization, the amphiboles and zircons compositions are used to evaluate the physicochemical conditions (e.g., pressure, temperature, fO2, and water content) of the Wandongshan ore-fertile porphyries and Bailiancun ore-barren porphyries observed in the Beiya Au deposit. The results show that the water content of the Wandongshan parent magma (≤4.11 ± 0.4 wt %) are slightly higher than those of the parent magma at Bailiancun (≤3.91 ± 0.4 wt %), while the emplacement pressure of the Wandongshan parent magma (31.5–68.6 MPa) is much lower than that of the parent magma at Bailiancun (142.3–192.8 MPa), indicating that the Wandongshan magma reached water saturation earlier. In addition, the Wandongshan porphyries crystallized from more oxidized magma (average of ΔFMQ = +3.5) with an average temperature of 778 °C compared to the Bailiancun porphyries (average of ΔFMQ = +1.5) with a mean magmatic temperature of 770 °C. The Ce4+/Ce3+ ratio of zircon in the Wandongshan ore-related intrusions (average Ce4+/Ce3+ of 62.00) is much higher than that of the Bailiancun barren porphyries (average Ce4+/Ce3+of 23.15), which further confirmed Wandongshan ore-related magma is more oxidized than the Bailiancun barren magma. Therefore, melts that are more enriched in water and with a high oxidation state will be more fertile to form an economic porphyry-style Au system.

Genesis of the lower crustal garnet-orthopyroxene tonalites (S-type) of the Hidaka Metamorphic Belt, northern Japan

ABSTRACTThe Hidaka Metamorphic Belt (HMB) in Hokkaido, northern Japan, consists of tilted metamorphic layers of an island-arc type crust from lower (granulite facies) to upper (very low-grade metasedimentary) horizons. Abundant granitic rocks, mainly S-type tonalites of crustal origin, intrude various metamorphic layers and are classified into four depth types, namely upper, middle, lower and basal. The basal orthopyroxene-garnet (S-type) tonalities were intruded into granulite facies country rocks. Textural and compositional evidence from minerals in the basal tonalite indicates that the crystallisation sequence is Grt-Pl-Opx-Bt-Qtz-Crd-Kfs, and that crystallisation took place at about 600 MPa and 900°C-700°C.Some crystallisation experiments were carried out in an internally heated pressure vessel, using the basal tonalite, under the conditions of 300 and 600 MPa, 700-900°C, and with 0-20 wt% H2O, respectively. The results show that the primary S-type tonalite magma was at a temperature above 900°C and contained 3-4 wt% H2O at the beginning of crystallisation. In order to study the influence of normative orthoclase content on orthopyroxene crystallisation, some starting materials also included 15, 20 and 25% normative orthoclase, by adding KAlSi3O8 gel to the rock powder. Normative orthoclase content has an influence on the subliquidus crystallisation limit of orthopyroxene.The changes in P-T conditions and chemical composition of the magma during ascent would generate the sequence from the basal to upper S-type granite. Opx-free S-type granitic magma can be generated from lower crustal Grt-Opx S-type granitic magma, by differentiation with falling magmatic temperature.

BeO in pegmatitic cordierite

SummarySeveral cordierites from pegmatites were found by emission spectroscopy to contain as much as 0·7 wt. % of BeO. Structural crystallographic considerations suggest that the beryl molecule, Be3Al2Si6O18, may have appreciable solubility in the structure of cordierite. Some hydrothermal experiments carried out on this assumption indicated about the same amount of BeO substitution in the magmatic temperature range as is shown by the pegmatite cordierites. The natural BeO-bearing cordierites have distinctive infra-red absorption properties, which are reproduced in the synthetic solid solutions.