Precise Measurements of CH Maser Emission and Its Abundance in Translucent Clouds

We present high-sensitivity CH 9 cm ON/OFF observations toward 18 extragalactic continuum sources that have been detected with OH 18 cm absorption in the Millennium survey with the Arecibo telescope. CH emission was detected toward 6 of the 18 sources. The excitation temperature of CH has been derived directly through analyzing all detected ON and OFF velocity components. The excitation temperature of CH 3335 MHz transition ranges from −54.5 to −0.4 K and roughly follows a log-normal distribution peaking within [−5, 0] K, which implies overestimation by 20% to more than 10 times during calculating CH column density by assuming the conventional value of −60 or −10 K. Furthermore, the column density of CH would be underestimated by a factor of 1.32 ± 0.03 when adopting local thermal equilibrium assumption instead of using the CH three hyperfine transitions. We found a correlation between the column density of CH and OH following log N(CH) = (1.80 ± 0.49) and log N(OH −11.59 ± 6.87. The linear correlation between the column density of CH and H2 is consistent with that derived from visible wavelengths studies, confirming that CH is one of the best tracers of H2 components in diffuse molecular gas.

Polarisation properties of methanol masers

Context. Astronomical masers have been effective tools in the study of magnetic fields for years. Observations of the linear and circular polarisation of different maser species allow for the determination of magnetic field properties, such as morphology and strength. In particular, methanol can be used to probe different parts of protostars, such as accretion discs and outflows, since it produces one of the strongest and the most commonly observed masers in massive star-forming regions. Aims. We investigate the polarisation properties of selected methanol maser transitions in light of newly calculated methanol Landé g-factors and in consideration of hyperfine components. We compare our results with previous observations and evaluate the effect of preferred hyperfine pumping and non-Zeeman effects. Methods. We ran simulations using the radiative transfer code, CHAMP, for different magnetic field values, hyperfine components, and pumping efficiencies. Results. We find a dependence between the linear polarisation fraction and the magnetic field strength as well as the hyperfine transitions. The circular polarisation fraction also shows a dependence on the hyperfine transitions. Preferred hyperfine pumping can explain some high levels of linear and circular polarisation and some of the peculiar features seen in the S-shape of observed V-profiles. By comparing a number of methanol maser observations taken from the literature with our simulations, we find that the observed methanol masers are not significantly affected by non-Zeeman effects related to the competition between stimulated emission rates and Zeeman rates, such as the rotation of the symmetry axis. We also consider the relevance of other non-Zeeman effects that are likely to be at work for modest saturation levels, such as the effect of magnetic field changes along the maser path and anisotropic resonant scattering. Conclusions. Our models show that for methanol maser emission, both the linear and circular polarisation percentages depend on which hyperfine transition is masing and the degree to which it is being pumped. Since non-Zeeman effects become more relevant at high values of brightness temperatures, it is important to obtain good estimates of these quantities and the maser beaming angles. Better constraints on the brightness temperature will help improve our understanding of the extent to which non-Zeeman effects contribute to the observed polarisation percentages. In order to detect separate hyperfine components, an intrinsic thermal line width that is significantly smaller than the hyperfine separation is required.

Ellipsometric spectroscopy of rubidium vapor cell at near-normal incidence

Various efforts have been made to overcome Doppler broadening in hyperfine measurement limitations in the atomic vapors spectroscopy and associated applications. The present study measured and calculated hyperfine resolved ellipsometric parameters through the near-normal reflectance spectra of the rubidium vapor cell in two experimental setups based on continuous and modulated pathway. The results indicated that valuable information could be extracted from the ellipsometric parameters about the atomic medium. Change in the ellipsometric parameters in each transition line confirms the existence of the elliptical polarization of the reflected light when it is exposed to the alkali metal vapor. Our results show that the ellipticity at 5S1/2 (Fg = 1, 2) → 5P1/2 (Fe = 1, 2) hyperfine transitions of 87Rb (D1 line) is small, and accordingly hyperfine transitions between the ground 5S1/2 (Fg = 2, 3) and excited 5P1/2 (Fe = 2, 3) states of the 85Rb isotope are considerable. These ellipsometric parameters, as phase difference, can trace the behavior of the relative orientation of the electric field and atom velocity in the interface based on van der Waals dipole–dipole interaction and is directly proportional to the strength of the light-matter interaction which extremely useful instead complicated atomic spectroscopic methods.

Fine and hyperfine excitation of CCN by He

ABSTRACT The relative abundance of cyanide and isocyanide molecules is a sensitive tracer of the physical conditions in the interstellar and circumstellar media. Accurate modelling of collisional and radiative processes implying these species opens the way for accurate estimation of their abundances. The present paper focuses on the computation of collisional rate coefficients for fine and hyperfine (de-)excitation of the CCN molecule (one of the C2N isomers) in collision with He, for temperatures up to 150 K. Using a time independent coupled-channel approach, scattering calculations were performed for transitions implying the lowest 56 fine structure levels and the corresponding 166 hyperfine structure levels belonging to both 2Π1/2 and 2Π3/2 spin-orbit manifolds. We provided, for the first time, realistic collisional data for the CCN radical. Propensity rules for fine and hyperfine transitions are discussed. As a first application, we evaluated the impact of these new data on the astrophysical modelling through radiative transfer calculations. We obtained the brightness and excitation temperatures of selected lines observed towards circumstellar envelopes and we found that local thermodynamic equilibrium conditions are not fulfilled for this species. As a consequence, our results indicate that the abundance of the CCN derived from the observations has to be revised since the observation modelling strongly depends on the collisional data used.

Hyperfine excitation of SH+ by H

Context. SH+ is a surprisingly widespread molecular ion in diffuse interstellar clouds. There, it plays an important role by triggering the sulfur chemistry. In addition, SH+ emission lines have been detected at the UV-illuminated edges of dense molecular clouds, so-called photo-dissociation regions (PDRs), and toward high-mass protostars. An accurate determination of the SH+ abundance and of the physical conditions prevailing in these energetic environments relies on knowing the rate coefficients of inelastic collisions between SH+ molecules and hydrogen atoms, hydrogen molecules, and electrons. Aims. We derive SH+–H fine and hyperfine-resolved rate coefficients from recent quantum calculations for the SH+–H collisions, including inelastic, exchange, and reactive processes. Methods. The method we used is based on the infinite-order sudden approach. Results. State-to-state rate coefficients between the first 31 fine levels and 61 hyperfine levels of SH+ were obtained for temperatures ranging from 10 to 1000 K. Fine-structure resolved rate coefficients present a strong propensity rule in favor of Δj = ΔN transitions. The Δj = ΔF propensity rule is observed for the hyperfine transitions. Conclusions. The new rate coefficients will help significantly in the interpretation of SH+ spectra from PDRs and UV-irradiated shocks where the abundance of hydrogen atoms with respect to hydrogen molecules can be significant.

Inelastic rate coefficients for collisions of N2H+ with H2

ABSTRACT N2H+ is one of the first molecular ions observed in the interstellar medium and it is of particular interest to probe the physical conditions of cold molecular clouds. Accurate modelling of the observed lines requires the knowledge of collisional excitation rate coefficients. Thus, we have calculated rate coefficients for the excitation of N2H+ by H2, the most abundant collisional partner. The calculations are based on a new potential energy surface obtained from highly correlated ab initio calculations. This 4D-interaction surface exhibits a very deep well of ≈2530 cm−1 making fully converged scattering calculations very difficult to carry out, when one takes into account the rotational structure of H2. To overcome this difficulty, two approximate approaches, the adiabatic hindered rotor approach (AHR) and the statistical adiabatic channel model, were tested by comparing the results with those obtained from full 4D close-coupling calculations. The AHR treatment, which reduces the scattering calculations to a 2D problem was found to give the best results at all temperatures and even for transitions involving high N2H+ rotational levels. State-to-state rate coefficients between the 26 first N2H+ rotational levels were calculated for temperatures ranging from 5 K up to 500 K. Using a recoupling technique, rate coefficients are obtained among hyperfine transitions.

Sensing microwave photons with a Bose–Einstein condensate

We consider the interaction of a magnetically trapped Bose–Einstein condensate of Rubidium atoms with the stationary microwave radiation field sustained by a coplanar waveguide resonator. This coupling allows for the measurement of the magnetic field of the resonator by means of counting the atoms that fall out of the condensate due to hyperfine transitions to non-trapped states. We determine the quantum efficiency of this detection scheme and show that weak microwave fields at the single-photon level can be sensed.

First search for low-frequency CH with a Square Kilometre Array precursor telescope

The diatomic free radical methylidyne (CH) is an important tracer of the interstellar medium, and the study of it was critical to our earliest understanding of star formation. Although it is detectable across the electromagnetic spectrum, observations at radio frequencies allow for a study of the kinematics of the diffuse and dense gas in regions of new star formation. There is only two published (single-dish) detections of the low-frequency hyperfine transitions between 700 and 725 MHz, despite the precise frequencies being known. These low-frequency transitions are of particular interest as they are shown in laboratory experiments to be more sensitive to magnetic fields than their high-frequency counterparts (with more pronounced Zeeman splitting). In this work, we take advantage of the radio quiet environment and increased resolution of the Australian Square Kilometre Array Pathfinder (ASKAP) over previous searches to make a pilot interferometric search for CH at 724.7883 MHz (the strongest of the hyperfine transitions) in RCW 38. We found the band is clean of radio frequency interference, but we did not detect the signal from this transition to a five-sigma sensitivity limit of 0.09 Jy, which corresponds to a total column density upper limit of 1.9 $\times 10^{18}$ cm–2 for emission and 1.3 $\times 10^{14}$ cm–2 for absorption with an optical depth limit of 0.95. Achieved within 5 h of integration, this column density sensitivity should have been adequate to detect the emission or absorption in RCW 38, if it had similar properties to the only previous reported detections in W51.