Analysis of the Shear-Thinning Viscosity Behavior of the Johnson–Segalman Viscoelastic Fluids

This paper presents a numerical comparison of viscoelastic shear-thinning fluid flow using a generalized Oldroyd-B model and Johnson–Segalman model under various settings. Results for the standard shear-thinning generalization of Oldroyd-B model are used as a reference for comparison with those obtained for the same flow cases using Johnson–Segalman model that has specific adjustment of convected derivative to assure shear-thinning behavior. The modeling strategy is first briefly described, pointing out the main differences between the generalized Oldroyd-B model (using the Cross model for shear-thinning viscosity) and the Johnson–Segalman model operating in shear-thinning regime. Then, both models are used for blood flow simulation in an idealized stenosed axisymmetric vessel under different flow rates for various model parameters. The simulations are performed using an in-house numerical code based on finite-volume discretization. The obtained results are mutually compared and discussed in detail, focusing on the qualitative assessment of the most distinct flow field differences. It is shown that despite all models sharing the same asymptotic viscosities, the behavior of the Johnson–Segalman model can be (depending on flow regime) quite different from the predictions of the generalized Oldroyd-B model.

Microrheology to Understand the Viscosity Behavior of a Sophorolipid Biosurfactant

The microstructure of the aqueous solutions of purified acidic Sophorolipid (SL) has previously been studied using highly sophisticated methods such as SANS and Cryo-TEM. We were interested in whether (a) the main findings also apply to commercially available SL (which is a mixture of acidic and lactonic SL) and (b) more readily available methods such as DLS can be used to gain insight into the molecular aggregation of SL. Our work was motivated by the increasing interest in biosurfactants for applications in personal and household care. Moreover, the origin behind the more or less lack of rheological response to changes in pH is of practical relevance, as it is somewhat unusual for a carboxylate-group containing surfactant. By using DLS microrheology, we could elucidate the aggregation structure and dynamics of the surfactant on a microscopic scale. Surprisingly, the different degrees of protonation only impacted the microscopic properties such as exchange kinetics and the plateau values of the storage moduli.

Effect of Solvent on the Hydrodynamic Properties of Collagen

In this study, the effect of solvent on the hydrodynamic properties of collagen extracted from tail tendons of young rats was researched. Collagen was dissolved in various aqueous carboxylic acid solutions, including acetic acid (AA), acetic acid with the addition of sodium chloride (AA/NaCl), formic acid (FA), lactic acid (LA), citric acid (CA), and also citrate buffer at pH = 3.7 (CB). The properties of collagen solutions at a concentration of 0.45 mg/mL were characterized based on the viscometric method. The reduced viscosity, intrinsic viscosity, and Huggins coefficient of collagen solutions and effect of solvent, temperature, and UV irradiation on these properties were investigated. Collagen solutions in acetic acid, acetic acid/NaCl, and citrate buffer were irradiated with UV light up to 1 h, and the viscosity of collagen solutions was measured. It was found that the organic acids used as solvent affected viscosity behavior, denaturation temperature, and stability of collagen solutions. The lowest values of studied parameters were obtained for the collagen solutions in acetic acid with the addition of sodium chloride. Thus, the effect of various aqueous carboxylic acid solutions on collagen solutions properties and denaturation temperature can also be affected by the sodium chloride addition. The results of this research can be crucial for the preparation of collagen solutions for both cosmetic and biomedical applications.

Viscosity Investigations on the Binary Systems of (1 ChCl:2 Ethylene Glycol) DES and Methanol or Ethanol

In this study, the viscosity behavior of two mixtures of Ethaline (1 ChCl:2 ethylene glycol) with either methanol or ethanol were investigated over the temperature range of 283.15–333.15 K at atmospheric pressure. The measured viscosities of neat Ethaline, methanol, and ethanol showed reliable agreement with the corresponding reported literature values. The mixture viscosities were modeled by an Arrhenius-like model to determine the behavior of viscosity with respect to temperature. The data were also modeled by the four well-known mixture viscosity models of Grunberg–Nissan, Jouyban–Acree, McAllister, and Preferential Solvation. All of the model results were reliable, with the Jouyban–Acree and Preferential Solvation models showing the most accurate agreement with the experimental measurements. The Jones–Dole viscosity model was also investigated for the measured viscosities, and by analyzing the results of this model, strong interactions among Ethaline and the alcohol molecules were proposed for both systems. As a final analysis, viscosity deviations of the investigated systems were calculated to study the deviations of the viscosity behaviors with respect to ideal behavior. Both systems showed negative viscosity deviations at all of the investigated temperatures, with the negative values tending towards zero, and hence more ideal behavior, with increasing temperatures. Moreover, in order to correlate the calculated viscosity deviations, the Redlich–Kister model was successfully used for both systems and at each investigated temperature.

Anomalous Terminal Shear Viscosity Behavior of Polycarbonate Nanocomposites Containing Grafted Nanosilica Particles

Viscosity controls an important issue in polymer processing. This paper reports on the terminal viscosity behavior of a polymer melt containing grafted nanosilica particles. The melt viscosity behavior of the nanocomposites was found to depend on the interaction between the polymer matrix and the nanoparticle surface. In the case of polycarbonate (PC) nanocomposites, the viscosity decreases by approximately 25% at concentrations below 0.7 vol% of nanosilica, followed by an increase at higher concentrations. Chemical analysis shows that the decrease in viscosity can be attributed to in situ grafting of PC on the nanosilica surface, leading to a lower entanglement density around the nanoparticle. The thickness of the graft layer was found to be of the order of the tube diameter, with the disentangled zone being approximately equal to the radius of gyration (Rg) polymer chain. Furthermore, it is shown that the grafting has an effect on the motion of the PC chains at all timescales. Finally, the viscosity behavior in the PC nanocomposites was found to be independent of the molar mass of PC. The PC data are compared with polystyrene nanocomposites, for which the interaction between the polymer and nanoparticles is absent. The results outlined in this paper can be utilized for applications with low shear processing conditions, e.g., rotomolding, 3D printing, and multilayer co-extrusion.