A three-dimensional model of CMSX-6 superalloy coupons was built in the paper, temperature field was calculated with software ProCAST. The temperature values of coupons were indicated from the measurement at the rate of 3 mm min-1 withdrawal velocity during directional solidification process, and the temperature gradient of different location of the coupons were calculated. It turned out that: the simulated results and the measured results are in good agreement; due to the different medial and lateral affected by radiation, isotherms showed sloped distributions in the process of the withdrawal; the temperature gradient of the measured positions in the coupons which are 10 mm, 50 mm, 100 mm, 150 mm far from the copper chill, are 8.0 Kmm-1, 3.0 Kmm-1, 2.5 Kmm-1, 1.8 Kmm-1 respectively.