DEVELOPMENT OF THE COMPONENT COMPOSITION OF THE BIODEGRADABLE LIQUID LUBRICANT FOR SAW CHAINS

The procedure of working out of the component composition of the biodegradable liquid lubricant for the saw chains is shown. The experimental statistical mathematical model is developed for the optimization of the formulation of the main base taking into account the necessary viscosity and temperature parameters. At the same time the kinematic viscosity of the base body at the temperature of 40 °C and its pure point are chosen as the optimization criteria and the following three factors are used as the optimization parameters: the content of vegetable (rapeseed) oil in the composition, the viscosity of mineral oil at the temperature of 40 °C and the content of an adhesive additive in the base composition. The component composition of the lubricant is adjusted to achieve the required level of tribological properties of the saw chain oil and to ensure the stability of all its characteristics during storage (at least 12 months) and operation at a given level of biodegradability (at least 90 %). In particular, the biodegradable calcium sulfonate grease OIMOL KSC BIO was selected as an additive to improve tribological parameters. The special adhesive additive for vegetable oils of the Petrolad 484BD brand is used to increase the sedimentation stability, and the highly refined oil of group III according to the API standard is recommended to use as a mineral component. The developed lubricant has the following characteristics: density at 15 °C — 926 kg/m3, kinematic viscosity at 40 °C — 47.3 mm2/s, kinematic viscosity at 100 °C — 9.9 mm2/s, viscosity index — 202, pour point — –28 °C, flash point — 272 °C, critical load — 872 N, welding load — 1,600 N, wear index at 200 N — 0.39 mm, biodegradability — 93 %.

Study on the Tribological Mechanism of Ultrafine SiO2/MoS2 Powders in Complex Calcium Sulfonate Grease

The purpose of this work was to study and further clarify the anti-wear and anti-friction mechanism of ultrafine SiO2/MoS2 powders in the complex calcium sulfonate grease. In this paper, 15nm nanoSiO2, 1μm MoS2 and commercial NLGI Grade No.2 complex calcium sulfonate grease were used as the research objects, SEM, EDS and XPS were used to study the morphology, composition and film chemical constitution of the long friction wear spots of grease containing single nanoSiO2 powder, ultrafine MoS2 powder and the two compound powders, which formed in the process of four ball long friction. The results show that nanoSiO the grease plays a role in filling the undercut, ball bearings and polishing and forming high hardness Ca3Fe2(SiO4)3 and part of Fe2O3 anti-wear films in the process of long friction. The ultrafine MoS2 powder has a self-repairing effect to fill the grooves,forming the MoS2, MoO3 anti-friction films and Fe2(SO4)3 anti-wear film. The two powders in the composite grease have a synergistic effect, acting on the friction pair together, and simultaneously forming self-repairing anti-friction and anti-wear films, thereby further improving the tribological performance of the base grease.

Tribological Properties of Complex Calcium Sulfonate Grease with Ultrafine SiO2/MoS2 Powders

For the development of complex calcium sulfonate grease containing ultrafine SiO2/MoS2 powders with self-reparing performance. On the basis of the dispersion of the nanoSiO2 particles, the effects of particle size,addition amount,load and the mass ratio of nanoSiO2 to ultrafine MoS2 powders on the tribological properties of commercial No.2 complex calcium sulfonate grease were systematically studied by four ball friction and wear tester. The results show that suitable particle size and addition amount of single SiO2 and MoS2 powders can significantly reduce the coefficient of friction (COF) and the wear scar diameter (WSD) of the grease. The composite of nanoSiO2 and MoS2 powder can broaden the load range of base grease and further improve the tribological properties of complex calcium sulfonate grease. When the mass ratio of nanoSiO2 powder to MoS2 powder is 3:7 and the total addition amount is 0.8wt%, the COF and the WSD of the grease are decreased by 53.64% and 27.08%, respectively, compared with the base grease. The two powders in the composite grease have synergy effect for improving the tribological performance and the friction stability of the grease during the process of long friction.