Ionic liquids as boundary additives in water-based and PAO lubricants

Ionic liquids have been widely discussed as potential lubricants, however, their properties make them also very good potential candidates as lubricant additives (e.g., friction modifiers and anti-wear). In this work, the tribological study of two ionic liquids (tributylmethylphosphonium dimethylphosphate (PP), and 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate (BMP)) as lubricant additives has been performed on stainless steel (AISI 316L) exposed to polar (water-glycol) and non-polar (polyalphaolefin) based lubricants under boundary lubricating conditions. The performance of these ionic liquids as lubricant additives has been compared to a classical organic friction modifier (dodecanoic acid (C12)). The water-glycol lubricant formulated with the two ionic liquids showed friction values higher than the same base lubricant formulated with dodecanoic acid, however, opposite results were observed for polyalphaolefin (PAO). A detailed surface chemical analysis using X-ray photoelectron spectroscopy (XPS) revealed differences in the passive/tribofilm thickness and chemical composition of the stainless steel surface tested in all lubricants. In the case of the polar lubricant additivated with ionic liquids, the tribochemical reaction accompanied by a tribocorrosion process led to the formation of an unstable passive/tribofilm resulting in high friction and wear. However, in the absence of tribocorrosion process (polyalphaolefin base lubricant), the tribochemical reaction led to the formation of a stable passive/tribofilm resulting in low friction and wear. A detailed surface and subsurface investigation of the microstructure using scanning electron microscopy equipped with a focused ion beam (SEM-FIB) showed that high wear rates resulted in thicker recrystallization region under the wear track surface. Among all lubricant additives tested in this work, BMP in non-polar lubricant media showed the best tribological performance.

Contrasting Genesis of Lateritic Bauxite on Granodioritic and Andesitic Rocks of Mempawah Area, West Kalimantan

The lateritic bauxite deposits in the Mempawah area, West Kalimantan, were formed by the chemical weathering of Cretaceous granodioritic and andesitic rocks. They occurred locally on the low hills surrounded by swampy areas. Detailed surface geological mapping, test pits, mineralogical and geochemical analyses were performed to determine the characteristics and genesis of bauxite from different parent rocks. From bottom upward, the deposits are composed of fresh parent rocks, clay or pallid zone, bauxite zone with a few sparse ferricrete at the top of the bauxite zone, and soil. Bauxite derived from granodiorite exhibits brownish-red, massive, boulder to gravel-sized concretion in clay matrix and is composed of predominant gibbsite with subordinate kaolinite, quartz, goethite, and a minor amount of magnetite and hematite. In contrast, bauxite derived from andesitic rocks exhibits reddish-brown and is composed of predominant goethite. During the leaching process, SiO2 as a mobile compound decreased significantly in neutral pH, while Al2O3 and Fe2O3 precipitated as residual materials to form bauxite concretion. The enrichment anomaly of bauxite derived from andesitic rocks is caused by physio-chemical changes from hydrothermal alteration. Bauxite was formed by indirect bauxitization through the leaching of primary minerals under a tropical-humid climate.

Identifying the Association between Surface Heterogeneity and Electrochemical Properties in Graphite

Graphite materials for commercial Li-ion batteries usually undergo special treatment to control specific parameters such as particle size, shape, and surface area to have desirable electrochemical properties. Graphite surfaces can be classified into basal and edge planes in the aspect of the structure of carbons, with the existing defect sites such as functional groups and dislocations. The solid-electrolyte interphase (SEI) mostly forms at the edge plane and defect sites, as Li-ions only intercalate through these non-basal planes, whereas the electrochemical properties of graphite largely depend on its surface heterogeneity due to the difference of reactivity on each plane. In order to quantify the detailed surface structure of graphite materials, local-absorption isotherms were utilized, and the analyzed nanostructural parameters of various commercial graphite samples were correlated with the electrochemical properties of each graphite anode. Thereby, we have confirmed that the fraction of non-basal plane and fast-charging capability has strong linear relations. The pore/non-basal sites are also related to the cycle life by affecting the SEI formation, and the determination of surface heterogeneity and pores of graphite materials can provide powerful parameters that imply the electrochemical performances of commercial graphite.

Application of Floating TiO2 Photocatalyst for Methylene Blue Decomposition and Salmonella Typhimurium Inactivation

The growing level of wastewater as well as pollution of freshwater by various bacteria are essential worldwide issues which have to be solved. In this contribution, nanocrystalline anatase TiO2 films deposited by magnetron sputtering on high-density polystyrene (HDPE) beads were applied as floating photocatalysts for Salmonella Typhimurium bacterial inactivation in water for the first time. Additionally, the photocatalytic degradation of methylene blue dye in the presence of HDPE beads with TiO2 film under UV-B irradiation was investigated. The suitability to adopt such floating photocatalyst structures for practical applications was tested in cycling experiments. The detailed surface morphology, crystal structure, elemental mapping, surface chemical composition and bond analysis of deposited TiO2 films were investigated by scanning electron microscope, X-ray diffractometer and X-ray photoelectron spectroscope techniques. The bacterial viability as well as MB decomposition experiments showed promising results by demonstrating that 6% of bacterial colonies were formed after the first run and only about 1% after the next four runs, which is an appropriate outcome for practical applications. NPN uptake results showed that the permeability of the outer membrane was significantly increased as well.

POSSIBILITIES OF USING PHASE ONE 190MP AERIAL SYSTEM AERIAL SURVEY RESULTS DURING CREATION OF A TERRITORY GEOINFORMATION SPACE

Results of using in Russia Phase One 190MP Aerial System are presented. Qualitative characteristics of the obtained photographic materials and a possibility of its use during creation of territories digital information models are investigated. Technical features and range of Phase One 190MP Aerial System using in aerial survey, specifics of planning software and management of aero survey works and also some results of photogrammetric processing of pictures are discussed. Possibilities of the software for photogrammetric processing of pictures for the purpose of creation of True Ortophoto are tested. An assessment of labor input of photogrammetric works is given. In addition to creation of digital Orthophoto on the basis of the data obtained from the Phase One 190MP aerial camera the dense cloud of points, the detailed surface and 3-D digital terrain model are made. The possibility of use of digital models for specialized engineering calculations in geoinformation space by means of automated design engineering systems for the purpose of replenishment of model of territories is investigated by derived spatial data.

Combined Manufacturing Process of Copper Electrodes for Micro Texturing Applications (AMSME)

Surface texturing has brought significant improvements in the functional properties of parts and components. Sinker electro discharge machining (SEDM) is one of the processes which generates great texturing results at different scale. An electrode is needed to reproduce the geometry to be textured. Some geometries are difficult or impossible to achieve on an electrode using conventional and even unconventional machining methods. This work sets out the advances made in the manufacturing of copper electrodes for electro erosion by additive manufacturing, and their subsequent application to the functional texturing of Al-Cu UNS A92024-T3 alloy. A combined procedure of digital light processing (DLP) additive manufacturing, sputtering and micro-electroforming (AMSME), has been used to produce electrodes. Also, a specific laboratory equipment has been developed to reproduce details on a microscopic scale. Shells with outgoing spherical geometries pattern have been manufactured. AMSME process has shown ability to copper electrodes manufacturing. A highly detailed surface on a micrometric scale have been achieved. Copper shells with minimum thickness close to 300 µm have been tested in sinker electro discharge machining (SEDM) and have been shown very good performance in surface finishing operations. The method has shown great potential for use in surfaces texturing.

Revealing the Surface Structure of CdSe Nanocrystals by Dynamic Nuclear Polarization-Enhanced 77Se and 113Cd Solid-State NMR Spectroscopy

<p>Dynamic nuclear polarization (DNP) solid-state NMR (SSNMR) spectroscopy was used to obtain detailed surface structures of zinc blende CdSe nanocrystals (NCs) with plate or spheroidal morphologies and which are capped by carboxylic acid ligands. 1D ¹¹³Cd and ⁷⁷Se cross-polarization magic angle spinning (CPMAS) NMR spectra revealed distinct signals from Cd and Se atoms on the surface of the NCs, and those residing in bulk-like environments below the surface. ¹¹³Cd cross-polarization magic-angle-turning (CP-MAT) experiments identified CdSe₃O, CdSe₂O₂, and CdSeO₃ Cd coordination environments on the surface of the NCs, where the oxygen atoms are presumably from coordinated carboxylate ligands. The sensitivity gain from DNP enabled natural isotopic abundance 2D homonuclear ¹¹³Cd-¹¹³Cd and ⁷⁷Se-⁷⁷Se and heteronuclear ¹¹³Cd-⁷⁷Se scalar correlation solid-state NMR experiments that reveal the connectivity of the Cd and Se atoms. Importantly, ⁷⁷Se{¹¹³Cd} scalar heteronuclear multiple quantum coherence (<i>J</i>-HMQC) experiments were used to selectively measure one-bond ⁷⁷Se-¹¹³Cd scalar coupling constants (¹<i>J</i>(⁷⁷Se, ¹¹³Cd)). With knowledge of ¹<i>J</i>(⁷⁷Se, ¹¹³Cd), heteronuclear ⁷⁷Se{¹¹³Cd} spin echo (<i>J</i>-resolved) NMR experiments were then used to determine the number of Cd atoms bonded to Se atoms and vice versa. The <i>J</i>-resolved experiments directly confirmed that major Cd and Se surface species have CdSe₂O₂ and SeCd₄ stoichiometries, respectively. Considering the crystal structure of zinc blende CdSe, and the similarity of the solid-state NMR data for the platelets and spheroids, we conclude that the surface of the spheroidal CdSe NCs is primarily composed of {100} facets. The methods outlined here will generally be applicable to obtain detailed surface structures of various main group semiconductors.</p>

Revealing the Surface Structure of CdSe Nanocrystals by Dynamic Nuclear Polarization-Enhanced 77Se and 113Cd Solid-State NMR Spectroscopy

<p>Dynamic nuclear polarization (DNP) solid-state NMR (SSNMR) spectroscopy was used to obtain detailed surface structures of zinc blende CdSe nanocrystals (NCs) with plate or spheroidal morphologies and which are capped by carboxylic acid ligands. 1D ¹¹³Cd and ⁷⁷Se cross-polarization magic angle spinning (CPMAS) NMR spectra revealed distinct signals from Cd and Se atoms on the surface of the NCs, and those residing in bulk-like environments below the surface. ¹¹³Cd cross-polarization magic-angle-turning (CP-MAT) experiments identified CdSe₃O, CdSe₂O₂, and CdSeO₃ Cd coordination environments on the surface of the NCs, where the oxygen atoms are presumably from coordinated carboxylate ligands. The sensitivity gain from DNP enabled natural isotopic abundance 2D homonuclear ¹¹³Cd-¹¹³Cd and ⁷⁷Se-⁷⁷Se and heteronuclear ¹¹³Cd-⁷⁷Se scalar correlation solid-state NMR experiments that reveal the connectivity of the Cd and Se atoms. Importantly, ⁷⁷Se{¹¹³Cd} scalar heteronuclear multiple quantum coherence (<i>J</i>-HMQC) experiments were used to selectively measure one-bond ⁷⁷Se-¹¹³Cd scalar coupling constants (¹<i>J</i>(⁷⁷Se, ¹¹³Cd)). With knowledge of ¹<i>J</i>(⁷⁷Se, ¹¹³Cd), heteronuclear ⁷⁷Se{¹¹³Cd} spin echo (<i>J</i>-resolved) NMR experiments were then used to determine the number of Cd atoms bonded to Se atoms and vice versa. The <i>J</i>-resolved experiments directly confirmed that major Cd and Se surface species have CdSe₂O₂ and SeCd₄ stoichiometries, respectively. Considering the crystal structure of zinc blende CdSe, and the similarity of the solid-state NMR data for the platelets and spheroids, we conclude that the surface of the spheroidal CdSe NCs is primarily composed of {100} facets. The methods outlined here will generally be applicable to obtain detailed surface structures of various main group semiconductors.</p>