Disposal of pharmaceuticals wastes by the population of an outcrop area of the Guarani Aquifer System in Southern Brazil

Pharmaceutical waste is considered emerging pollutant that can contaminate water sources and underground water, besides is serious problem for waste management in Brazil. The objective of this study was to evaluate the pharmaceutical consumption for human use and the way expired and unused medicines are disposed by the population. The study was carried out in two neighborhoods of the Lages, under outcrop of the Guarani Aquifer, in southern Brazil. In this descriptive and quantitative study, data collection occurred between August and October of 2018 via a questionnaire completed by 309 participants. The questions addressed about sociodemographic data, information on the medicine consumption, disposal of pharmaceuticals residue and about the basic sanitation in the neighborhood. The pharmaceuticals class most used were anti-hypertension and diuretics, indicating an elevated occurrence of non-transmittable chronic illnesses. About 68% of participants stated that there are leftovers of medications after medical treatment and 70.2% that there is expired medication at household. The disposal of leftover and expired pharmaceutical was in domestic waste, followed by discharged into domestic sewage. Only a small percentage (<15%) of the participants adequately dispose of their medication waste. The inadequate disposal of household pharmaceutical in the study area can result in contamination by chemical substances of the Guarani Aquifer and superficial waters.

Compartmentation in the Guarani Aquifer System northeastern region of the Rio Grande do Sul State

This study aims to evaluate the structural compartmentation of the Guarani Aquifer System (GAS) in the northeastern region of the Rio Grande do Sul (RS) state. For this purpose, an integrated analysis of 747 morphostructural lineaments identified in the scale 1:1,000,000 with geometry features and potentiometry of the GAS was performed. Based on this evaluation, a main set of structures, N30W and N60E oriented, responsible for the GAS compartmentation within the study area, was identified. These directions are related to the main tectonic structures that originated from the basement of the Paraná Basin, which could indicate that these identified structures are part of large fault systems in this region. The variations in the GAS potentiometry and altimetry of the top related to the compartmentation show the existence of several blocks formed under the influence of NW and NE structures located mainly in the large valleys, which sometimes work as a discharge zone of the aquifer. According to the analysis, the GAS in the northeastern region of RS seems to be divided into compartments of different sizes. This structural and geometrical framework imposed by tectonic structures influences the GAS potentiometry and flow dynamics.

National Sovereignty Versus Transboundary Water Cooperation: Can You See International Law Reflected in the Water?

Could Turkey dam the Tigris and Euphrates and deprive its downstream neighbors of vital water resources? Could Brazil over-pump the Guarani Aquifer System to the detriment of the other aquifer states? Could Egypt put pressure on upstream Nile states and prevent them from developing river related infrastructure that might limit downstream flow? International law in the field of transboundary water cooperation has evolved and would appear to condemn unilateral practices such as the ones suggested above. However, hydro politics and the lack of reception of international water law instruments by many countries sometimes make it difficult to see international law properly reflected in the management of major rivers, lakes and aquifers around the world. In this essay, I first highlight what international law dictates when it comes to the tension between national sovereignty and transboundary water cooperation. I then explore how this tension plays out in the three examples noted above. Due to limited acceptance of the existing international, bilateral, or regional legal instruments, the resolution of the tension between national sovereignty and transboundary water cooperation will often be left to customary international law.

Determining a composite value for the saturated hydraulic conductivity in a recharge area of the Guarani Aquifer System, using pedotransfer functions

ABSTRACT The saturated hydraulic conductivity (Ks) is an essential property for modeling water and contaminants movement into aquifers. However, Ks is extremely variable, even when considering nearby locations, which poses a challenge for modeling at catchment scales. Field measurements of Ks are most of the time expensive, time-consuming and labor-intensive. This study aimed to obtain, for modeling purposes, and using pedotransfer functions (PTFs), a composite value of Ks at a catchment scale, in a recharge area of the Guarani Aquifer System. Soil samples were taken across the study area, and the Ks for each sampling point were determined by several PTF methods. At the same locations, Ks field measurements were taken using a Guelph permeameter. Average values of Ks for all the sampling points calculated by PTFs were similar to the average value obtained by field measurements. The use of PTFs proved to be a faster and simpler method to efficiently determine the Ks value for the watershed and to capture the stochastic variation in terms of soil pore combination at the watershed scale.