Phonolite Material as Catalyst Support for the Hydrotreatment of Gas Oil and Vegetable Oil Type Feedstocks

Phonolite material has shown to be promising catalyst support for the deoxygenation of triglycerides. In this work, we continue with our previous research by synthesising and testing three acid-treated phonolite-supported Co-Mo, Ni-Mo and Ni-W catalysts for the hydrotreating of atmospheric gas oil and co-processing with rapeseed oil at industrial operating conditions (350–370 °C, WHSV 1–2 h−1, 5.5 MPa) in the continuous regime for more than 270 h. The phonolite-supported catalysts showed hydrotreating activity comparable with commercial catalysts, together with a complete conversion of triglycerides into n-alkanes. During co-processing, the Ni-promoted catalyst showed strong stability, with similar activity previous to the rapeseed oil addition. Our results enable us to evaluate the suitability of phonolite as catalyst support for the development of plausible alternatives to conventional hydrotreating catalysts for the co-processing of middle distillates with vegetable oils.

Prospective randomised trial of bolus vs. continuous regime of jejunostomy feed

Enteral alimentation can be administered continuously, cyclically, intermittently, or by a bolus technique. Current literature does not suggest superiority of any one regime. Most studies have used nasogastric feeds, little is known about the outcome of jejunal feeding. This study compares the efficiency and safety of bolus and continuous jejunostomy feeding. 46 adults undergoing a feeding jejunostomy for nutritional support or as an adjunct to a major upper GI surgery, were randomised to bolus feeding (BF group, n = 24) and continuous feeding (CF group, n = 22). Demographic, anthropometric, and laboratory parameters were measured preoperatively and on post-operative days (POD) 3, 7, 15, and 30. These parameters; as well as nutritional and functional outcomes, and complications at POD 30; were comparable in both groups. Both groups tolerated jejunal feeds well. Bolus feeding is simple, inexpensive, and permits daily physical activities. Hence it may be preferred over continuous jejunostomy feeding for enteral alimentation.

Enhancing the environmental performance of biotrickling filters treating volatile organic compounds in air

The actual biotrickling filtration technology addresses volatile organic compounds (VOCs) removal from air, by their conversion into less harmful gaseous compounds (e.g. carbon dioxide). The actual study extends this capability towards not only VOCs removal, but also removal of carbon dioxide issued from biodegradation, in the same biotrickling filter (BTF). This upgrade results in higher C-capture and the reduction of greenhouses gases associated with this process, thus increasing the environmental performance of such BTFs. The model pollutant used in this study is ethanol, while a co-immobilised microalgae and compost-derived microorganisms is used for the first time accomplishing the above mentioned desiderate (simultaneously removal of VOC and carbon dioxide in the same BTF), under continuous regime and illumination provided by an array of light-emitting diodes (LED)). Very promising performances are obtained, revealing new competitive alternatives with high potential for further development, in the light of atmospheric protection and climate change issues.

Shadowing and shielding: Effective heuristics for continuous influence maximisation in the voting dynamics

Influence maximisation, or how to affect the intrinsic opinion dynamics of a social group, is relevant for many applications, such as information campaigns, political competition, or marketing. Previous literature on influence maximisation has mostly explored discrete allocations of influence, i.e. optimally choosing a finite fixed number of nodes to target. Here, we study the generalised problem of continuous influence maximisation where nodes can be targeted with flexible intensity. We focus on optimal influence allocations against a passive opponent and compare the structure of the solutions in the continuous and discrete regimes. We find that, whereas hub allocations play a central role in explaining optimal allocations in the discrete regime, their explanatory power is strongly reduced in the continuous regime. Instead, we find that optimal continuous strategies are very well described by two other patterns: (i) targeting the same nodes as the opponent (shadowing) and (ii) targeting direct neighbours of the opponent (shielding). Finally, we investigate the game-theoretic scenario of two active opponents and show that the unique pure Nash equilibrium is to target all nodes equally. These results expose fundamental differences in the solutions to discrete and continuous regimes and provide novel effective heuristics for continuous influence maximisation.

Embedded solitons with χ(2) and χ(3) nonlinear susceptibilities

GStudied in this work are embedded solitons with quadratic nonlinearity that includes the effect of spatio-temporal dispersion. Two integration schemes yield bright, dark, singular and combo singular soliton solutions from the continuous regime. The existence criteria for these solitons are also included.

A pulsed-Laser Rb atomic frequency standard for GNSS applications

We present the results of 10 years of research related to the development of a Rubidium vapor cell clock based on the principle of pulsed optical pumping (POP). Since in the pulsed approach, the clock operation phases take place at different times, this technique demonstrated to be very effective in curing several issues affecting traditional Rb clocks working in a continuous regime, like light shift, with a consequent improvement of the frequency stability performances. We describe two laboratory prototypes of POP clock, both developed at INRIM. The first one achieved the best results in terms of frequency stability: an Allan deviation of σy(τ) = 1.7 × 10−13 τ−1/2, being τ the averaging time, has been measured. In the prospect of a space application, we show preliminary results obtained with a second more recent prototype based on a loaded cavity-cell arrangement. This clock has a reduced size and exhibited an Allan deviation of σy(τ) = 6 × 10−13 τ−1/2, still a remarkable result for a vapor cell device. In parallel, an ongoing activity performed in collaboration with Leonardo S.p.A. and aimed at developing an engineered space prototype of the POP clock is finally mentioned. Possible issues related to space implementation are also briefly discussed. On the basis of the achieved results, the POP clock represents a promising technology for future GNSSs.

First Results: Innovative Solar Disinfection Technology for Treated Wastewater that Integrates Materiality, Geometry, and Reflective Panels

Climate change is having drastic consequences in Chile. The lack of water in various regions is causing environmental impacts on ecosystems, including the decrease in the productive activities of rural economies and the deterioration in the quality of life of the inhabitants that occupy the affected physical spaces. In this paper, we propose a sustainable, low-cost treatment of wastewater and its reuse as an adaptation and mitigation policy, patented in 2019, that consists of a wastewater disinfection system based on solar energy. This system can work in both continuous and discontinuous modes. The water passes through a canal of reflective material in the continuous regime, and in the batch regime, the water remains in the canal. The panels are located parallel to the lateral faces of the canal. These panels concentrate the radiation in the canal through reflection. The trapezoidal geometry of the disinfectant canal deflects the radiation and reflects in the direction of the front walls of the canal, radiating what is returned and vice versa. The fraction of the radiation reflected outside the canal reaches the reflective side panels that return the radiation to the canal. The synergy of these three considerations increases the radiation in the canal area, augmenting the elimination of the bacterial load. In the trapezoidal reflective canal without panels, only 5% of the measured radiation exceeded the atmospheric radiation, eliminating 83% of the coliforms. The incorporation of panels surpassed the atmospheric radiation over 36% of the measured radiations, and the removal of coliforms exceeded 99.7%.