Understanding Hydrodechlorination of Chloromethanes. Past and Future of the Technology

Chloromethanes are a group of volatile organic compounds that are harmful to the environment and human health. Abundant studies have verified that hydrodechlorination might be an effective treatment to remove these chlorinated pollutants. The most outstanding advantages of this technique are the moderate operating conditions used and the possibility of obtaining less hazardous valuable products. This review presents a global analysis of experimental and theoretical studies regarding the hydrodechlorination of chloromethanes. The catalysts used and their synthesis methods are summarized. Their physicochemical properties are analyzed in order to deeply understand their influence on the catalytic performance. Moreover, the main causes of the catalyst deactivation are explained, and prevention and regeneration methods are suggested. The reaction systems used and the effect of the operating conditions on the catalytic activity are also analyzed. Besides, the mechanisms and kinetics of the process at the atomic level are reviewed. Finally, a new perspective for the upgrading of chloromethanes, via hydrodechlorination, to valuable hydrocarbons for industry, such as light olefins, is discussed.

IMPACT OF PERSISTENT ORGANIC POLLUTANTS AND BENZ[A]PYRENE ON GERMINATION OF COMMON BARLEY SEEDS (HORDÉUM VULGÁRE L.)

The paper considers the influence of polychlorinated dibenzo-p-dioxins, dibenzofurans, biphenyls and benz[a] pyrene on the germination of barley seeds, as well as the influence of pollutants on seed storage. As a result of the experiments, the negative effect of polychlorinated biphenyls on seed germination at a concentration of 100 μg/ kg has been found, which can be explained by the high accumulation of low-chlorinated pollutants by seeds. The negative effect of benz[a]pyrene on seed germination at concentrations of 20 and 100 μg/kg has been registered.

Roles of Organohalide-Respiring Dehalococcoidia in Carbon Cycling

ABSTRACT The class Dehalococcoidia within the Chloroflexi phylum comprises the obligate organohalide-respiring genera Dehalococcoides, Dehalogenimonas, and “Candidatus Dehalobium.” Knowledge of the unique ecophysiology and biochemistry of Dehalococcoidia has been largely derived from studies with enrichment cultures and isolates from sites impacted with chlorinated pollutants; however, culture-independent surveys found Dehalococcoidia sequences in marine, freshwater, and terrestrial biomes considered to be pristine (i.e., not impacted with organohalogens of anthropogenic origin). The broad environmental distribution of Dehalococcoidia, as well as other organohalide-respiring bacteria, supports the concept of active halogen cycling and the natural formation of organohalogens in various ecosystems. Dechlorination reduces recalcitrance and renders organics susceptible to metabolic oxidation by diverse microbial taxa. During reductive dechlorination, hydrogenotrophic organohalide-respiring bacteria, in particular Dehalococcoidia, can consume hydrogen to low consumption threshold concentrations (<0.3 nM) and enable syntrophic oxidation processes. These functional attributes and the broad distribution imply that Dehalococcoidia play relevant roles in carbon cycling in anoxic ecosystems.