Mineral Inactivation of Zinc in Polluted Soil—Sustainability of Zeolite, Bentonite and Blends

The study outlines a novel and traceable procedure for inactivating zinc polluted soil (an Anthrosols) adjacent to a former zinc (Zn) ore mine “Orzel Biały” in Bytom (Poland), where the total content of Zn amounted to 3988.0 mg kg−1. This pollution level initiated an inactivation process involving two natural mineral sorbents, i.e., zeolite (Z) and bentonite (B), as well as their five blends (ZeoBen) expressed as ZB: (1) ZB15/85, (2) ZB30/70, (3) ZB50/50, (4) ZB70/30 and (5) ZB85/15. Next, phosphorus (P) as triple superphosphate (TSP, 46% P2O5) was added to individual ZB at rates: 0.25%, 0.5%, 1.0% and 2.0%. All sorbents were added to the Zn polluted soil at 0%, 0.25%, 0.5%, 1.0% and 2.0% (dry weight basis). Treatments (1.0 kg of Zn-polluted soil with ZB sorbents) were aged for 115 days. Data revealed that ZB85/15 with prevailing zeolite caused a Znact inactivation of 66–71%, while zeolite induced 54% and 47% for bentonite. Reactive zinc (Znreac) decreased much more (20%) when zeolite was incorporated at the rate 2.5 g·kg−1 soil, and bentonite was (10%) at the same rate. The application of the sorbent ZB50/50 enriched with triple superphosphate (TSP) raised the stabilization degree for both Zn fractions. The efficiency was significant at the TSP rate of 2.0% of the sorbent and at least the sorbent +TSP of 10 g·kg−1 soil. The cation exchange capacity (CEC) of about 2 cmol(+)·kg−1 controlled the activity −0.50 mmol·dm−3 of either γZnreac or γZnact, hence a very low zinc ionic activity. The use of mineral blends with higher sharing of zeolite is promising for remediating metal-polluted lands in the case of zinc.

Evaluation of Inoculated Waste Biological Stabilization Degree by Olfactometric Methods

As a result of compounds’ transformation in the waste biostabilization phases, there is an increase in odor nuisance and health problems among people exposed to odorants. Linking the odor concentration to the degree of waste biostabilization may be an important tool for the assessment of individual technological variants of biostabilization. The study aimed to link the odor emissions to the biostabilization degree in individual process variants that differed in the inoculum. The tests were carried out on inoculated windrows on the waste mechanical-bological treatment open site. Odor concentrations were measured during the entire seven-week process of biostabilization (weeks 1–7) and compared with kinetics parameters of organic compounds’ decomposition. The olfactometric tests showed the necessity of using the preparation to reduce the value of odor concentration. Research proved that the decrease of odor concentration values could be useful to indicate the particular phases of biostabilization. Also, the proposed method provides an opportunity to optimize the process concerning the function related to the low degree of odor nuisance of the technologies, including selection of environmentally safe inoculum. This issue has application values that may result in the implementation of new control systems for waste stabilization bioreactors and the evaluation of applied technological solutions.

Carbon–silicon alloy fibers: Optimizing tensile properties by control of the stabilization stage

The stabilization stage in the processing of carbon–silicon alloy (CSA) precursor fibers is investigated in this study. The critical stabilization parameters are identified and shown to control the mechanical properties of fibers both at the stabilization stage and, after further pyrolysis and controlled oxidation, to produce oxidation-resistant fibers. The attainment of infusibility in the stabilized fibers, necessary for the production of CSA fibers, determines the lowest stabilization degree, whereas the highest stabilization degree can be identified from the relationship between stabilization temperature and tensile properties of CSA fibers, thus enabling the optimum stabilization conditions to be determined. The CSA fibers produced by proper control of stabilization conditions significantly enhance mechanical properties, which are more than double those of CSA fibers obtained previously. Fourier transform infrared spectroscopy and nuclear magnetic resonance studies show that at stabilization temperatures above the optimum there is significant formation of silica in the stabilized fibers. This leads to a higher modulus but lower tensile strength and elongation.