A Calculation Method for the Coupling of Temperature and Concentration during Inconel 718 Alloy Solidification

Due to the temperature and concentration determine the kinetic undercooling of interface growth and nucleation undercooling inside the melt, they play an important role in the solidification microstructure of the alloy. In this paper, the effect of temperature gradient and cooling rate on the dynamic undercooling was studied and the mechanism of the concentration at the solid-liquid interface on the kinetic undercooling during the continuous cooling process was analyzed. A calculation method for the coupling of temperature and concentration during Inconel 718 alloy solidification was developed, which can solve the problem that the concentration and temperature are difficult to be calculated at the same time in the numerical calculation.

Experimental and modelling studies for solidification of undercooled Ni–Fe–Si alloys

We present experimental results, analytical calculations and phase-field simulations for undercooled Ni–Fe–Si alloy system. Undercooling experiments are performed using flux encapsulation along with in situ measurement of recalescence speed using a high-speed camera followed by microstructural characterization. Dendrite growth calculations are performed using a modified Boettinger, Coriell and Trivedi theory to incorporate constitutional undercooling due to multiple segregating elements and a modified kinetic undercooling term. Phase-field simulations are performed using a multi-component phase-field model to generate dendrites in this alloy. High growth velocities are observed and the analytical calculations are in good agreement with experiments. The microstructure evolution from the phase-field simulations indicates that there is a difference in solute segregation during growth of dendrites. This article is part of the theme issue ‘Heterogeneous materials: metastable and non-ergodic internal structures’.

Rigorous results in existence and selection of Saffman–Taylor fingers by kinetic undercooling

The selection of Saffman–Taylor fingers by surface tension has been extensively investigated. In this paper, we are concerned with the existence and selection of steadily translating symmetric finger solutions in a Hele–Shaw cell by small but non-zero kinetic undercooling (ε2). We rigorously conclude that for relative finger width λ near one half, symmetric finger solutions exist in the asymptotic limit of undercooling ε2 → 0 if the Stokes multiplier for a relatively simple non-linear differential equation is zero. This Stokes multiplier S depends on the parameter $\alpha \equiv \frac{2 \lambda -1}{(1-\lambda)}\epsilon^{-\frac{4}{3}}$ and earlier calculations have shown this to be zero for a discrete set of values of α. While this result is similar to that obtained previously for Saffman–Taylor fingers by surface tension, the analysis for the problem with kinetic undercooling exhibits a number of subtleties as pointed out by Chapman and King (2003, The selection of Saffman–Taylor fingers by kinetic undercooling, Journal of Engineering Mathematics, 46, 1–32). The main subtlety is the behaviour of the Stokes lines at the finger tip, where the analysis is complicated by non-analyticity of coefficients in the governing equation.

Mathematical modelling of Tyndall star initiation

The superheating that usually occurs when a solid is melted by volumetric heating can produce irregular solid–liquid interfaces. Such interfaces can be visualised in ice, where they are sometimes known as Tyndall stars. This paper describes some of the experimental observations of Tyndall stars and a mathematical model for the early stages of their evolution. The modelling is complicated by the strong crystalline anisotropy, which results in an anisotropic kinetic undercooling at the interface; it leads to an interesting class of free boundary problems that treat the melt region as infinitesimally thin.

Corner and finger formation in Hele-Shaw flow with kinetic undercooling regularisation

We examine the effect of a kinetic undercooling condition on the evolution of a free boundary in Hele-Shaw flow, in both bubble and channel geometries. We present analytical and numerical evidence that the bubble boundary is unstable and may develop one or more corners in finite time, for both expansion and contraction cases. This loss of regularity is interesting because it occurs regardless of whether the less viscous fluid is displacing the more viscous fluid, or vice versa. We show that small contracting bubbles are described to leading order by a well-studied geometric flow rule. Exact solutions to this asymptotic problem continue past the corner formation until the bubble contracts to a point as a slit in the limit. Lastly, we consider the evolving boundary with kinetic undercooling in a Saffman-Taylor channel geometry. The boundary may either form corners in finite time, or evolve to a single long finger travelling at constant speed, depending on the strength of kinetic undercooling. We demonstrate these two different behaviours numerically. For the travelling finger, we present results of a numerical solution method similar to that used to demonstrate the selection of discrete fingers by surface tension. With kinetic undercooling, a continuum of corner-free travelling fingers exists for any finger width above a critical value, which goes to zero as the kinetic undercooling vanishes. We have not been able to compute the discrete family of analytic solutions, predicted by previous asymptotic analysis, because the numerical scheme cannot distinguish between solutions characterised by analytic fingers and those which are corner-free but non-analytic.