Solving numerically a non-Born-Oppenheimer time-dependent Schrödinger
equation to study the dissociative-ionization of H
subjected to strong field six-cycle laser pulses (I = 4 ×
10 W/cm, λ = 800 nm) leads to
newly ultrafast images of electron dynamics in
H. The electron distribution in
H oscillates symmetrically with
laser cycle with θ + π periodicity and gets trapped
between two protons for about 8 fs by a Coulomb potential well.
Nonetheless, this electron symmetrical distribution breaks up for the
H internuclear separation larger
than 9 a.u. in the field-free region at a time duration of 24 fs as a
result of the distortion of Coulomb potential where the ejected electron
preferentially localizes in one of the double-well potential separated
by the inner Coulomb potential barrier. Moreover, controlling laser
carrier-envelope phase θ enables one to generate the highest
total asymmetry A of 0.75 and
-0.75 at 10 and 190, respectively,
associated with the electron preferential directionality being ionized
to the left or the right paths along the
H molecular axis. Thus the
laser-controlled electron slightly reorganizes its position accordingly
to track the shift in the position of the protons despite much heavier
the proton’s mass.