Hybrid Sol-Gel Matrices Doped with Colorimetric/Fluorimetric Imidazole Derivatives

Organic-inorganic hybrids (OIH) are materials that can be easily synthesized by the sol-gel method and combine the advantages of organic and inorganic moieties within a single polymeric matrix. Imidazole derivatives are versatile organic compounds that can change their optical properties with the variation of pH due to the protonation or deprotonation of the nitrogen atoms. This work reports the preparation of different OIHs doped with different contents of two imidazole compounds (3a,b). The obtained materials were characterized structurally by FTIR, and the dielectric properties were studied by electrochemical impedance spectroscopy. The optical properties were studied by UV-Vis absorption and fluorescence spectroscopies. The FTIR analysis showed that the presence of the imidazole does not change the structural properties of the matrices. The normalized resistance values obtained for the doped matrices ranged between 8.57 and 9.32 Ω cm2, all being higher than the undoped matrix. The σ ranged between 9.49 and 10.28 S cm−1, being all higher than the pure OIH samples. Compound 3a showed a maximum absorption peak at 390 nm, which is present in the OIH spectra, proving the presence of the compound. In the case of compound 3b, a maximum absorption wavelength at 412 nm was found, and the compound peak was not clear, which may indicate that an interaction between the compound and the matrix occurred. A synergetic effect between the intrinsic emission of the matrix and the fluorescence of 3a is found on the OIH-doped matrices.

Purcell Effect and Beaming of Emission in Hybrid AlGaAs Nanowires with GaAs Quantum Dots

Control of directionality of emissions is an important task for the realization of novel nanophotonic devices based on nanowires. Most of the existing approaches providing high directionality of the light emitted from nanowires are based on the utilization of the tapered shape of nanowires, serving as nanoantenna coupling with the light waveguided in nanowire and the directional output beam. Here we report the beaming of the emitted light with wavelength near 800 nm by naturally formed core-shell AlGaAs NW with multiply GaAs quantum dots (QDs) diameter 30 nm and height 10 nm, while the diameter of NW 130 nm, what does not support efficient emission into waveguided modes, including the mode HE11. Experimental measurements show that intensity of emission for directions in the vicinity of the axis of NW is about two orders of magnitude higher than for perpendicular directions. The developed theoretical approach allowed us to calculate the probability of spontaneous emission for various directions and into waveguided modes and showed that highly directional radiation can be provided by the intrinsic emission properties of cylindrical NW. Our results suggest that for the small diameter of NW, directional emissions are associated with an TM0 leaky mode (when electric field oriented in axial direction) and therefore manifests in an existence of axial electric dipole transitions in quantum dots.

Narrow-band giant pulses from the Crab pulsar

ABSTRACT We used a new spectral-fitting technique to identify a subpopulation of 6 narrow-band giant pulses from the Crab pulsar out of a total of 1578. These giant pulses were detected in 77 min of observations with the 46-m dish at the Algonquin Radio Observatory at 400–800 MHz. The narrow-band giant pulses consist of both main- and inter-pulses, thereby being more likely to be caused by an intrinsic emission mechanism as opposed to a propagation effect. Fast radio bursts (FRBs) have demonstrated similar narrow-band features, while only little has been observed in the giant pulses of pulsars. We report the narrow-band giant pulses with Δν/ν of the order of 0.1, which is close to the value of 0.05 reported for the repeater FRB 20190711A. Hence, the connection between FRBs and giant pulses of pulsars is further established.

Intrinsic emission and electron-hole trapping centers in crystals Li2SO4-Cu

In the present work, the emission and excitation spectra in Li2SO4-Cu crystals have been obtained by the methods of vacuum-ultraviolet and thermoactivation spectroscopy. We have studied the nature of emission from a pressed and annealed sample of Li2SO4-Cu powders. It has been revealed that at low temperatures Cu0-SO4--centers are formed during the trap of electrons by Cu+-centers and during localization of SO4--radicals in the form of localized hole centers.