Layered macrocycles with flexibility and tunable dynamic properties for wide-range thermoresponsive color changes

Layered materials exhibit unique properties, such as intercalation and exfoliation, originating from the two-dimensional anisotropic nanostructures. A variety of inorganic and organic layered materials have been synthesized for design of...

Formation of NiMoO4 Anisotropic Nanostructures under Hydrothermal Conditions

Abstract—The synthesis of NiMoO4 hierarchical nanostructures using the hydrothermal method has been studied. The decomposition of NiMoO4·xH2O crystalline hydrate formed during the synthesis has been studied using synchronous thermal analysis upon heating in a stream of air and argon. According to X-ray diffraction as well as scanning and transmission electron microscopies, the proposed conditions allow one to synthesize single-phase nanosized (average CSR size of about 25 ± 2 nm) nickel(II) molybdate, which has a spinel-type monoclinic structure (space group C2/m) without impurity inclusions.

Green synthesis and characterization of gold-based anisotropic nanostructures using bimetallic nanoparticles as seeds

Nanostructured noble metals are of great interest because of their tunable optical and electronic properties. However, the green synthesis of anisotropic nanostructures with a defined geometry by a systematic nanoassembly...

Advances in exploiting the degrees of freedom in nanostructured metasurface design: from 1 to 3 to more

The unusual electromagnetic responses of nanostructured metasurfaces endow them with an ability to manipulate the four fundamental properties (amplitude, phase, polarization, and frequency) of lightwave at the subwavelength scale. Based on this, in the past several years, a lot of innovative optical elements and devices, such as metagratings, metalens, metaholograms, printings, vortex beam generators, or even their combinations, have been proposed, which have greatly empowered the advanced research and applications of metasurfaces in many fields. Behind these achievements are scientists’ continuous exploration of new physics and degrees of freedom in nanostructured metasurface design. This review will focus on the progress on the design of different nanostructured metasurfaces for lightwave manipulation, including by varying/fixing the dimensions and/or orientations of isotropic/anisotropic nanostructures, which can therefore provide various functionalities for different applications. Exploiting the design degrees of freedom of optical metasurfaces provides great flexibility in the design of multifunctional and multiplexing devices, which can be applied in anticounterfeiting, information encoding and hiding, high-density optical storage, multichannel imaging and displays, sensing, optical communications, and many other related fields.

Chitosan-Stabilized Noble Metal Nanoparticles: Study of their Shape Evolution and Post-Functionalization Properties

Noble metal anisotropic nanostructures have achieved a growing interest in both academic and industrial domains mostly because of their shape-dependent plasmonic properties in the near-infrared region. In this paper, gold and gold-silver anisotropic nanostructures were synthesized in very high shape-yields through a wet, seed-mediated approach based on the use of nearly spherical silver nanoparticles as seeds and chitosan as stabilizing agent. Two chitosans of different origin and molecular properties were selected for the synthetic pathway, leading to the formation of variously sized and shaped end products. In detail, quite homogeneous nanoplatelets of about 25-nm size and 7-nm thickness or nearly spherical, highly porous nanocages of about 50-nm size were obtained, depending on the type of polysaccharide employed. The shape transition towards anisotropic morphologies occurred through a slow, spontaneous process, in which the chitosan nature seemed to play a key role. As expected, both nanoplatelets and nanocages exhibit shape-dependent plasmonic features and surface properties tunable for a variety of application fields. To prove this point, the nanostructures were successfully post-functionalized with poly(10,12-pentacosadiynoic acid) (PCDA), a carboxylic-endowed diacetylene able to anchor on noble metal substrates, to obtain versatile, chromic platforms suitable for sensing and spectroscopic purposes.

Identification of preferentially exposed crystal facets by X-ray diffraction

Intensification of X-ray diffraction peaks can be used to get information about doping, presence of vacancies, anisotropic nanostructures, or preferred orientation of crystals with largely exposed facets.

Enzyme-assisted mineralization of calcium phosphate: exploring confinement for the design of highly crystalline nano-objects

Calcium phosphate mineralization is initiated through heterogenous enzymatic catalysis, resulting in the formation of highly ordered anisotropic nanostructures. The mineral phase features are modulated by physicochemical factors and confinement.