Laser Fabrication of Titanium Alloy-Based Photothermal Responsive Slippery Surface

In recent years, biomimetic materials inspired from natural organisms have attracted great attention due to their promising functionalities and cutting-edge applications, emerging as an important research topic. For example, how to reduce the reflectivity of the solid surface and increase the absorption of the substrate surface is essential for developing light response smart surface. Suitable solutions to this issue can be found in natural creatures; however, it is technologically challenging. In this work, inspired from butterfly wings, we proposed a laser processing technology to prepare micro nanostructured titanium alloy surfaces with anti-reflection properties. The reflectivity is significantly suppressed, and thus, the light absorption is improved. Consequently, the anti-reflection titanium alloy surface can be further employed as a photothermal substrate for developing light-responsive slippery surface. The sliding behavior of liquid droplets on the smart slippery surface can be well controlled via light irradiation. This method facilitates the preparation of low-reflection and high-absorption metallic surfaces towards bionic applications.

Mitigating and adapting to climate change with a taxonomy of smart urban surfaces

Rapid urbanization is replacing natural land with dark, impervious surfaces. This has led to dire urban consequences including rising temperatures and stormwater deluge, resulting in significantly higher energy costs, greater stormwater damage, and associated health and comfort impacts. These issues can be mitigated using smart surfaces, those with high reflectivity and permeability, which can achieve sustainable and regenerative cities. The current literature on the benefits of urban surfaces is very segmented, focusing on either one specific surface type or one property of surfaces. A smart surface taxonomy with correlated heat, and water metrics has been developed to fill this gap. A range of city surfaces in three broad categories - roofs, streets and sidewalks, and parking lots - have been identified with various levels of reflectivity, permeability. Through literature review, the taxonomy reveals surface temperatures that range from 29.7°C for a green roof to 74.3°C for a black roof. Also, the taxonomy reveals Rainfall retention potential ranging from 1.27 mm for impervious pavement to 86.4 mm for bioswales. The development of a smart surface taxonomy with quantified benefits for mitigating or adapting to climate change will be critical for decision-makers to make informed decisions on city surface choices.

Bio-inspired smart surface to achieve controllable locomotion through adjustable anisotropic friction

Anisotropic friction generated by microstructured surfaces is crucial for performing functions such as directional locomotion and adhesion in biological systems. Hence, an epoxy-based shape memory polymer (SMP) incorporating Fe3O4 nanoparticles is used in this study to create a smart surface with oriented structures to mimic anisotropic friction and exploit human-developed controllable locomotion systems. Applying the specific properties of the epoxy-based SMP, fast switching friction can be achieved by adjusting the topography and stiffness of the microstructures on the surface. In addition, the photothermogenesis effect of Fe3O4 nanoparticles induces changes in the asymmetric topography and stiffness on the SMP surface under the irradiation of near-infrared (NIR) light, thereby inducing a rapid switching of the friction force. Furthermore, a microbot is created to demonstrate remotely controlled locomotion, such as unidirectional and round-trip movements, and braking by switching the friction force under NIR light. These results are promising for the design of new intelligent surfaces and interfaces; additionally, they may facilitate the investigation of biological structures and processes.