Physically Switchable Antimicrobial Surfaces and Coatings: General Concept and Recent Achievements

Bacterial environmental colonization and subsequent biofilm formation on surfaces represents a significant and alarming problem in various fields, ranging from contamination of medical devices up to safe food packaging. Therefore, the development of surfaces resistant to bacterial colonization is a challenging and actively solved task. In this field, the current promising direction is the design and creation of nanostructured smart surfaces with on-demand activated amicrobial protection. Various surface activation methods have been described recently. In this review article, we focused on the “physical” activation of nanostructured surfaces. In the first part of the review, we briefly describe the basic principles and common approaches of external stimulus application and surface activation, including the temperature-, light-, electric- or magnetic-field-based surface triggering, as well as mechanically induced surface antimicrobial protection. In the latter part, the recent achievements in the field of smart antimicrobial surfaces with physical activation are discussed, with special attention on multiresponsive or multifunctional physically activated coatings. In particular, we mainly discussed the multistimuli surface triggering, which ensures a better degree of surface properties control, as well as simultaneous utilization of several strategies for surface protection, based on a principally different mechanism of antimicrobial action. We also mentioned several recent trends, including the development of the to-detect and to-kill hybrid approach, which ensures the surface activation in a right place at a right time.

Mitigating and adapting to climate change with a taxonomy of smart urban surfaces

Rapid urbanization is replacing natural land with dark, impervious surfaces. This has led to dire urban consequences including rising temperatures and stormwater deluge, resulting in significantly higher energy costs, greater stormwater damage, and associated health and comfort impacts. These issues can be mitigated using smart surfaces, those with high reflectivity and permeability, which can achieve sustainable and regenerative cities. The current literature on the benefits of urban surfaces is very segmented, focusing on either one specific surface type or one property of surfaces. A smart surface taxonomy with correlated heat, and water metrics has been developed to fill this gap. A range of city surfaces in three broad categories - roofs, streets and sidewalks, and parking lots - have been identified with various levels of reflectivity, permeability. Through literature review, the taxonomy reveals surface temperatures that range from 29.7°C for a green roof to 74.3°C for a black roof. Also, the taxonomy reveals Rainfall retention potential ranging from 1.27 mm for impervious pavement to 86.4 mm for bioswales. The development of a smart surface taxonomy with quantified benefits for mitigating or adapting to climate change will be critical for decision-makers to make informed decisions on city surface choices.

Bioinspired Smart Materials With Externally-Stimulated Switchable Adhesion

Living organisms have evolved, over billions of years, to develop specialized biostructures with switchable adhesion for various purposes including climbing, perching, preying, sensing, and protecting. According to adhesion mechanisms, switchable adhesives can be divided into four categories: mechanically-based adhesion, liquid-mediated adhesion, physically-actuated adhesion and chemically-enhanced adhesion. Mimicking these biostructures could create smart materials with switchable adhesion, appealing for many engineering applications in robotics, sensors, advanced drug-delivery, protein separation, etc. Progress has been made in developing bioinspired materials with switchable adhesion modulated by external stimuli such as electrical signal, magnetic field, light, temperature, pH value, etc. This review will be focused on new advance in biomimetic design and synthesis of the materials and devices with switchable adhesion. The underlying mechanisms, design principles, and future directions are discussed for the development of high-performance smart surfaces with switchable adhesion.

Link Budget Analysis for Reconfigurable Smart Surfaces in Aerial Platforms

<div>Non-terrestrial networks, including Unmanned Aerial Vehicles (UAVs), High Altitude Platform Station (HAPS) and Low Earth Orbiting (LEO) satellites, are expected to have a pivotal role in the sixth generation wireless networks. With their inherent features such as flexible placement, wide footprint, and preferred channel conditions, they can tackle several challenges in current terrestrial networks. However, their successful and widespread adoption relies on energy-efficient on-board communication systems. In this context, the integration of Reconfigurable Smart Surfaces (RSS) into aerial platforms is envisioned as a key enabler of energy-efficient and cost-effective deployments of aerial platforms. Indeed, RSS consist of low-cost reflectors capable of smartly directing signals in a nearly passive way. We investigate in this paper the link budget of RSS-assisted communications under the two discussed RSS reflection paradigms in the literature, namely the specular and the scattering reflection paradigm types. Specifically, we analyze the characteristics of RSS-equipped aerial platforms and compare their communication performance with that of RSS-assisted terrestrial networks, using standardized channel models. In addition, we derive the optimal aerial platforms placements under both reflection paradigms. The obtained results provide important insights for the design of RSS-assisted communications. For instance, given that a HAPS has a large RSS surface, it provides superior link budget performance in most studied scenarios. In contrast, the limited RSS area on UAVs and the large propagation loss in LEO satellite communications make them unfavorable candidates for supporting terrestrial users. Finally, the optimal location of the RSS-equipped platform may depend on the platform’s altitude, coverage footprint, and type of environment.</div>

Link Budget Analysis for Reconfigurable Smart Surfaces in Aerial Platforms

<div>Non-terrestrial networks, including Unmanned Aerial Vehicles (UAVs), High Altitude Platform Station (HAPS) and Low Earth Orbiting (LEO) satellites, are expected to have a pivotal role in the sixth generation wireless networks. With their inherent features such as flexible placement, wide footprint, and preferred channel conditions, they can tackle several challenges in current terrestrial networks. However, their successful and widespread adoption relies on energy-efficient on-board communication systems. In this context, the integration of Reconfigurable Smart Surfaces (RSS) into aerial platforms is envisioned as a key enabler of energy-efficient and cost-effective deployments of aerial platforms. Indeed, RSS consist of low-cost reflectors capable of smartly directing signals in a nearly passive way. We investigate in this paper the link budget of RSS-assisted communications under the two discussed RSS reflection paradigms in the literature, namely the specular and the scattering reflection paradigm types. Specifically, we analyze the characteristics of RSS-equipped aerial platforms and compare their communication performance with that of RSS-assisted terrestrial networks, using standardized channel models. In addition, we derive the optimal aerial platforms placements under both reflection paradigms. The obtained results provide important insights for the design of RSS-assisted communications. For instance, given that a HAPS has a large RSS surface, it provides superior link budget performance in most studied scenarios. In contrast, the limited RSS area on UAVs and the large propagation loss in LEO satellite communications make them unfavorable candidates for supporting terrestrial users. Finally, the optimal location of the RSS-equipped platform may depend on the platform’s altitude, coverage footprint, and type of environment.</div>

Stimuli-responsive surfaces for switchable wettability and adhesion

Diverse unique surfaces exist in nature, e.g. lotus leaf, rose petal and rice leaf. They show similar contact angles but different adhesion properties. According to the different wettability and adhesion characteristics, this review reclassifies different contact states of droplets on surfaces. Inspired by the biological surfaces, smart artificial surfaces have been developed which respond to external stimuli and consequently switch between different states. Responsive surfaces driven by various stimuli, e.g. stretching, magnetic, photo, electric, temperature, humidity and pH, are discussed. Studies reporting on either atmospheric or underwater environments are discussed. The application of tailoring surface wettability and adhesion includes microfluidics/droplet manipulation, liquid transport and harvesting, water energy harvesting and flexible smart devices. Particular attention is placed on the horizontal comparison of smart surfaces with the same stimuli. Finally, the current challenges and future prospects in this field are also identified.