Swelling properties of graphite oxides and graphene oxide multilayered materials

Swelling defines graphite oxides and multilayered graphene oxides. It is a key property of GO in applications which involve sorption from vapors, immersion into liquid water or polar solvents and solution based chemical reactions.

Synthesis, Composition, and Properties of Partially Oxidized Graphite Oxides

The aim of this paper is to prepare and characterize partially-oxidized graphite oxide and consider if it is possible to affect the level of oxidation of particles by an adjustment of the oxidizing agent. Several samples were prepared, using different amounts of oxidizing agent. The samples were subsequently analyzed. The C/O ratio was evaluated from XPS, EDS, and EA. The amount and type of individual oxygen functionalities were characterized by XPS, Raman spectroscopy, and cyclic voltammetry. The structure was studied by SEM and XRD. Thermal stability was investigated by STA-MS in argon atmosphere. The results can be useful in order to design simple technology for graphite oxide synthesis with required oxygen content.

Removal of arsenic from water using crumpled graphite oxide

In this work, we fabricated crumpled graphite oxides (CGOs) from discharged electrodes of waste batteries by the cathodic plasma electrolysis process and applied it for arsenic (As) removal from water solutions. Several factors that affect the removal efficiency of As(III) were investigated, including pH, initial concentrations, and contact time. After 120 min of experiment [10 mg of CGO in 40 ml of 1 mg/l As(III) solution], the removal efficiency reached to as high as 98.6%. From the Langmuir isotherm model, the calculated maximum adsorption capacity (qmax) was found to be 47.39 mg/g. The results from this study showed that CGOs could be an effective adsorbent for As(III) removal from the water environment and acts as a promising adsorbent for other heavy metals from contaminated water.

REMOVAL OF Cd(II) FROM AQUEOUS SOLUTIONS BY CRUMPLED GRAPHITE OXIDE

In this study, crumpled graphite oxides (CGOs) were fabricated from graphite electrode of exhausted dry batteries (RG) by cathodic plasma electrolysis method (CPE) and applied for removing Cd(II) from aqueous solutions. The effects of pH, contact time, and initial concentrations on the removal of Cd(II) ions were studied. A removal efficiency of ∼98 % was obtained after 120 min, via the dispersion of 15 mg of CGO in Cd(II) solutions (40 mL, 1 ppm) at pH 6. The maximum adsorption capacity (qmax) was calculated to be 40.82 mg/g. Results showed that CGO is an effective adsorbent for the removal of Cd(II) from aqueous environment and acts as a promising adsorbent for the removal of other heavy metals from the polluted water.