Lithium Enrichment Signatures of Planetary Engulfment Events in Evolved Stars

Planetary engulfment events have long been proposed as a lithium (Li) enrichment mechanism contributing to the population of Li-rich giants (A(Li) ≥ 1.5 dex). Using MESA stellar models and A(Li) abundance measurements obtained by the GALAH survey, we calculate the strength and observability of the surface Li enrichment signature produced by the engulfment of a hot Jupiter (HJ). We consider solar-metallicity stars in the mass range of 1–2 M ⊙ and the Li supplied by a HJ of 1.0 M J. We explore engulfment events that occur near the main-sequence turn-off (MSTO) and out to orbital separations of R ⋆ ∼ 0.1 au = 22 R ⊙. We map our results onto the Hertzsprung–Russell Diagram, revealing the statistical significance and survival time of Li enrichment. We identify the parameter space of masses and evolutionary phases where the engulfment of a HJ can lead to Li enrichment signatures at a 5σ confidence level and with meteoritic abundance strengths. The most compelling strengths and survival times of engulfment-derived Li enrichment are found among host stars of 1.4 M ⊙ near the MSTO. Our calculations indicate that planetary engulfment is not a viable enrichment pathway for stars that have evolved beyond the subgiant branch. For these sources, observed Li enhancements are likely to be produced by other mechanisms, such as the Cameron–Fowler process or the accretion of material from an asymptotic giant branch companion. Our results do not account for second-order effects, such as extra mixing processes, which can further dilute Li enrichment signatures.

Lithium systematics in global arc magmas and the importance of crustal thickening for lithium enrichment

Much of the world’s Li deposits occurs as basinal brines in magmatic orogens, particularly in continental volcanic arcs. However, the exact origin of Li enrichment in arc magmatic systems is not clear. Here, we show that, globally, primitive arc magmas have Li contents and Li/Y ratios similar to mid-ocean ridge basalts, indicating that the subducting slab has limited contribution to Li enrichment in arc magmas. Instead, we find that Li enrichment is enhanced by lower degrees of sub-arc mantle melting and higher extents of intracrustal differentiation. These enrichment effects are favored in arcs with thick crust, which explains why magmatism and differentiation in continental arcs, like the Andes, reach greater Li contents than their island arc counterparts. Weathering of these enriched source rocks mobilizes and transports such Li into the hydrologic system, ultimately developing Li brines with the combination of arid climate and the presence of landlocked extensional basins in thickened orogenic settings.

Lithium Enrichment in the No. 21 Coal of the Hebi No. 6 Mine, Anhe Coalfield, Henan Province, China

Lithium (Li) is an important strategic resource, and with the increasing demand for Li, there are some limitations in the exploitation and utilization of conventional deposits such as the pegmatite-type and brine-type Li deposits. Therefore, it has become imperative to search for Li from other sources. Li in coal is thought to be one of the candidates. In this study, the petrology, mineralogy, and geochemistry of No. 21 coal from the Hebi No. 6 mine, Anhe Coalfield, China, was reported, with an emphasis on the distribution, modes of occurrence, and origin of Li. The results show that Li is enriched in the No. 21 coal, and its concentration coefficient (CC) value is 6.6 on average in comparison with common world coals. Lithium in the studied coal is mainly present in aluminosilicates, mainly clay minerals, some of which contain a significant amount of Ti. The Li enrichment in the No. 21 coal is mainly controlled by the terrigenous materials and sourced from the moyite of the Yinshan Upland. Furthermore, Li in the No. 21 coal is more enriched in coals formed in acidic and humid conditions and coals influenced by fresh water during peat accumulation.