Relationship Between Summer Extreme Precipitation Anomaly in Central Asia and Surface Sensible Heat Variation on the Central-Eastern Tibetan Plateau

In the context of global warming, the frequency and intensity of extreme weather and climate events have increased, especially in Central Asia (CA). In this study, we investigate the characteristics of Summer Extreme Precipitation (SEP) in CA and its relationship with the Surface Sensible Heat (SSH) variation over the Central-Eastern Tibetan Plateau (CETP). Our results suggest that the distribution of SEP in CA is extremely uneven, and the SEP threshold ranges from 2 to 32 mm, 80% of them are concentrated in the range of 4–10mm. Both the total amount of SEP and the number of SEP days show significant increasing trends, with the climatic tendencies of 4.4 mm/decade and 0.4 day/decade, respectively. The SSH anomalies over the CETP can affect the SEP and the summer drought in CA by regulating the strength of the SAH and the subtropical jet over CA. The strong SSH anomalies over the CETP in late spring (April-May) can lead to the anomalously strong SAH in summer, anomalously weak subtropical westerly jet over CA and anomalously strong subtropical high over north Africa and the Arabian Peninsula. In addition, the Ural ridge strengthens, the CA trough weakens, and the northern CA is controlled by an abnormal warm high-pressure ridge with less anomalous water vapor convergence. Therefore, the SEP in northern CA will be abnormally less and the summer drought intensifies. Whereas, when the SSH over the CETP is anomalously weak in late spring, the key circulation characteristics are quite the opposite, at the same time, the anomalous water vapor from the Arctic, North Atlantic and western Pacific converges in northern CA and northern Xinjiang, China, which are conducive to the generation of widespread extreme precipitation and alleviates the summer drought in these regions.

Comprehensive Analysis on Anomalous Phenomenon of Ethanol-Soluble PVB Membrane for Ethanol Recovery via Pervaporation

Poly(vinyl butyral) is selected as a promising ethanol-permselective membrane based the solubility parameter theory, however it exhibits anomalous water perm-selectivity in practical pervaporation process. Comprehensive analysis based on experimental and theoretical methods were carried out to explore the inherent mechanism of the anomalous performance. Firstly, sum frequency generation vibrational spectra and contact angle were developed to quantify the surface reconstruction of membrane in air and ethanol, which indicated that hydrophilic hydroxyl tended to expose on membrane surface with ethanol thus improved the membrane affinity to water. Meanwhile, swelling behaviors proved more water would accumulate in the ethanol swollen membrane. Furthermore, theoretical analysis in terms of sorption and diffusion process, based on the UNIFAC-FV model and Fujita free volume theory, confirmed the mechanism of anomalous phenomenon of poly(vinyl butyral) membrane. The comprehensive investigation was expected to provide insights into the basic separation mechanism of pervaporation process.

F/OH ratio in a rare fluorine-poor blue topaz from Padre Paraíso (Minas Gerais, Brazil) to unravel topaz’s ambient of formation

Topaz [Al2SiO4(F,OH)2] is one of the main fluorine-bearing silicates occurring in environments where variably acidic (F)/aqueous (OH) fluids saturate the silicate system. In this work we fully characterized blue topaz from Padre Paraíso (Minas Gerais, Brazil) by means of in situ synchrotron X-Ray and neutron powder diffraction measurements (temperature range 298–1273 K) combined with EDS microanalyses. Understanding the role of OH/F substitution in topaz is important in order to determine the hydrophilicity and the exchange reactions of fluorine by hydroxyl groups, and ultimately to characterize the environmental redox conditions (H2O/F) required for mineral formation. The fluorine content estimated from neutron diffraction data is ~ 1.03 a.f.u (10.34 wt%), in agreement with the chemical data (on average 10.0 wt%). The XOH [OH/(OH + F)] (0.484) is close to the maximum XOH value (0.5), and represents the OH- richest topaz composition so far analysed in the Minas Gerais district. Topaz crystallinity and fluorine content sharply decrease at 1170 K, while mullite phase starts growing. On the basis of this behaviour, we suggest that this temperature may represent the potential initial topaz’s crystallization temperature from supercritical fluids in a pegmatite system. The log(fH2O/fHF)fluid (1.27 (0.06)) is coherent with the fluorine activity calculated for hydrothermal fluids (pegmatitic stage) in equilibrium with the forming mineral (log(fH2O/fHF)fluid = 1.2–6.5) and clearly different from pure magmatic (granitic) residual melts [log(fH2O/fHF)fluid < 1]. The modelled H2O saturated fluids with the F content not exceeding 1 wt% may represent an anomalous water-dominant / fluorine-poor pegmatite lens of the Padre Paraíso Pegmatite Field.

Subthermocline eddies in the Kuroshio Extension region observed by mooring arrays

Subthermocline eddies (STEs), also termed intra-thermocline eddies or submesoscale coherent vortices, are lens-shaped eddies with anomalous water properties located in or below the thermocline. Although STEs have been discovered in many parts of the world ocean, most of them were observed accidentally in hydrographic profiles, and direct velocity measurements are very rare. In this study, dynamic features of STEs in the Kuroshio Extension (KE) region are examined in detail using concurrent temperature/salinity and velocity measurements from mooring arrays. During the moored observation periods of 2004-2006 and 2015-2019, eleven single-core STEs, including eight with warm/salty cores and three with cold/fresh cores, were captured. The thermohaline properties in their cores suggest that these STEs may originate from the subarctic front and the upstream Kuroshio south of Japan. The estimated radius of these STEs varied from 8 to 66 km with the mean value of ~30 km. The warm/salty STEs seemed to be larger and rotate faster than the cold/fresh ones. In addition to single-core STEs, a dual-core STE was observed in the KE recirculation region, which showed that the upper cold/fresh cores stacked vertically over the lower warm/salty cores. Based on the observed parameters of the STEs, their Rossby number and Burger number were further estimated, with values up to 0.5 and 1, respectively. Furthermore, a low Richardson number O (0.25) was found at the periphery of these STEs, suggesting that shear instability-induced turbulent mixing may be an erosion route for the STEs.

Investigating the Interannual Variability of the Boreal Summer Water Vapor Source and Sink over the Tropical Eastern Indian Ocean-Western Pacific

Using the four-times daily and monthly-mean reanalysis datasets of NCEP/NCAR for the 1958 to 2018 period, we investigate the interannual variability of the June-July-August (JJA)–mean water vapor source and sink over the tropical eastern Indian Ocean-Western Pacific (TEIOWP) and the underlying mechanism. It is found that the two major modes (EOF1 and EOF2) of the water vapor source and sink anomalies over the TEIOWP present a southwest-northeast oriented dipole and a southwest-northeast oriented tripole. Specifically, when the western maritime continent shows an anomalous water vapor source, the northwestern Pacific is characterized by anomalous water vapor sink and source in EOF1 and EOF2 modes, respectively. The EOF1 and EOF2 modes are primarily driven by a single and a double meridional cell anomaly, which corresponds to the in-phase and out-of-phase linkage between evaporation anomalies over the western maritime continent and precipitation anomalies over the northwestern Pacific, respectively. Furthermore, the EOF1 mode is regulated by the quick transition of the El Niño-Southern Oscillation (ENSO) phase, whereas the EOF2 mode probably originates from internal atmospheric variability. Considering that the standard deviation of PC1 is much higher during ENSO years than that during non-ENSO years, it is probable that the water source and sink anomalies over the TEIOWP tend to be dominant by EOF1 mode during ENSO years. In contrast, the EOF2 mode may play an important role in the water source and sink anomalies over the TEIOWP during non-ENSO years. Accordingly, the water vapor source and sink anomalies over the TEIOWP may be well predicted based on the ENSO state in the previous December-January-February. These results are useful for understanding the predictability of water vapor source and sink anomalies over the TEIOWP.