IMPROVEMENT OF SURFACE POTENTIAL ENERGY OF INDIUM TIN OXIDE THIN FILM MODIFIED WITH ORGANIC SEMICONDUCTOR MATERIAL BASED ON PHENYL GROUP

This study focuses on surface characterization of modified indium tin oxide (ITO) for potential applications as anode in organic electronics devices. [4-iodophenyl]-silanetriol molecules were coated by self-assembled monolayers method on ITO surface. Kelvin Probe Microscopy, Scanning Tunneling Microcopy and X-ray Photoelectron Spectroscopy techniques were used to analyze the modified ITO surface. The results show that organic semiconductor material based on Phenyl group enhance surface morphology and increase the surface potential energy of ITO around [Formula: see text][Formula: see text]meV and contribute the tunneling current that inject from Fermi energy level of the ITO. This study includes the influence of surface interactions on electrochemical and spectral features of compounds. The results are important in developing surface structures in amorphous layers, better understanding the mechanism of creation of such structures on ITO surface.

Protein and Organic-Molecular Crystallography With 300kV Electrons on a Direct Electron Detector

Electron 3D crystallography can reveal the atomic structure from undersized crystals of various samples owing to the strong scattering power of electrons. Here, a direct electron detector DE64 was tested for small and thin crystals of protein and an organic molecule using a JEOL CRYO ARM 300 electron microscope. The microscope is equipped with a cold-field emission gun operated at an accelerating voltage of 300 kV, quad condenser lenses for parallel illumination, an in-column energy filter, and a stable rotational goniometer stage. Rotational diffraction data were collected in an unsupervised manner from crystals of a heme-binding enzyme catalase and a representative organic semiconductor material Ph-BTBT-C10. The structures were determined by molecular replacement for catalase and by the direct method for Ph-BTBT-C10. The analyses demonstrate that the system works well for electron 3D crystallography of these molecules with less damaging, a smaller point spread, and less noise than using the conventional scintillator-coupled camera.

Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes

Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions with two different substrates. Similar to conventional electrosynthesis, the primary redox intermediates afford only separate oxidized and reduced products or, more rarely, combine to one addition product. Here, we report that a stable organic semiconductor material, mesoporous graphitic carbon nitride (mpg-CN), can act as a visible-light photoredox catalyst to orchestrate oxidative and reductive interfacial electron transfers to two different substrates in a two- or three-component system for direct twofold carbon–hydrogen functionalization of arenes and heteroarenes. The mpg-CN catalyst tolerates reactive radicals and strong nucleophiles, is straightforwardly recoverable by simple centrifugation of reaction mixtures, and is reusable for at least four catalytic transformations with conserved activity.

Integrated Piezoelectric Energy Harvesting and Organic Storage System

An experimental investigation of an integrated piezo-electric based energy harvester and an organic energy storage device is performed. The energy is harvested from a vibrating composite unimorph beam. The storage device is made out of an organic semiconductor material and storage elements from synthesized nanoparticles. The semiconducting polymer is obtained by blending poly (vinyl alcohol) and poly (acrylic acid) in crystal state polymers with sorbitol acting as the plasticizer. Zinc-Oxide nanoparticles with a diameter size between 50 and 70 nm are used as charge storage elements. A piezoelectric energy generation element made out of macro-fiber composite is used to harvest the energy from the vibrating beam. The harvested energy is stored in the organic capacitor. The performance of the organic device is evaluated through its comparison with commercial capacitors. The results show that the voltage produced was high enough to store the harvested energy in the organic capacitor. The charge and energy levels of the organic capacitor are reported.