Silsesquioxane-Based Triphenylamine-Linked Fluorescent Porous Polymer for Dyes Adsorption and Nitro-Aromatics Detection

In order to enrich hybrid materials, a novel fluorescent silsesquioxane-based polymer (denoted as PCS-OTS) was synthesized by Friedel-Crafts reaction starting from octavinylsilsesquioxane (OVS) with triphenylamine-functionalized silsesquioxane monomer (denoted as OTS) with AlCl3 as catalyst. PCS-OTS possessed a high surface area of 816 m2/g and a unique bimodal pore structure. The triphenylamine unit endowed PCS-OTS with excellent luminescence, which made it act as a sensitive chemical sensor and detect p-nitrophenol with high sensitivity (KSV = 81,230 M−1). Moreover, PCS-OTS can significantly remove dyes, and the respective adsorption capacity for Rhodamine B (RB), Congo red (CR) and Methyl Orange (MO) is 1935, 1420 and 155 mg/g. Additionally, it could simultaneously remove multiple dyes from water by simple filtration and be easily regenerated. This hybrid porous polymer can be a good choice for water treatment.

Pt–CeO2 nanoporous spheres – an excellent catalyst for partial oxidation of methane: effect of the bimodal pore structure

Bimodal pore size distribution played the most important role for the catalyst's superior activity during POM.

Recyclable 3D graphene aerogel with bimodal pore structure for ultrafast and selective oil sorption from water

Development of graphene based porous sorbent to overcome the challenges, such as low uptake capacity, slow sorption rate, and non-recyclability, associated with conventional sorbents.