Production of ammonia makes Venusian clouds habitable and explains observed cloud-level chemical anomalies

The atmosphere of Venus remains mysterious, with many outstanding chemical connundra. These include the unexpected presence of ∼10 ppm O2 in the cloud layers, an unknown composition of large particles in the lower cloud layers, and hard to explain measured vertical abundance profiles of SO2 and H2O. We propose a hypothesis for the chemistry in the clouds that largely addresses all of the above anomalies. We include ammonia (NH3), a key component that has been tentatively detected both by the Venera 8 and Pioneer Venus probes. NH3 dissolves in some of the sulfuric acid cloud droplets, effectively neutralizing the acid and trapping dissolved SO2 as ammonium sulfite salts. This trapping of SO2 in the clouds, together with the release of SO2 below the clouds as the droplets settle out to higher temperatures, explains the vertical SO2 abundance anomaly. A consequence of the presence of NH3 is that some Venus cloud droplets must be semisolid ammonium salt slurries, with a pH of ∼1, which matches Earth acidophile environments, rather than concentrated sulfuric acid. The source of NH3 is unknown but could involve biological production; if so, then the most energy-efficient NH3-producing reaction also creates O2, explaining the detection of O2 in the cloud layers. Our model therefore predicts that the clouds are more habitable than previously thought, and may be inhabited. Unlike prior atmospheric models, ours does not require forced chemical constraints to match the data. Our hypothesis, guided by existing observations, can be tested by new Venus in situ measurements.

Gaia’s detectability of black hole–main sequence star binaries formed in open clusters

Black hole–main sequence star (BH–MS) binaries are one of the targets of future data releases of the astrometric satellite Gaia. They are supposed to be formed in two main sites: a galactic field and star clusters. However, previous work has never predicted the number of BH–MS binaries originating in the latter sites. In this paper we estimate the number of BH–MS binaries formed in open clusters and detectable with Gaia based on the results of N-body simulations. By considering interstellar extinction in the Milky Way and observational constraints, we predict that ∼10 BH–MS binaries are observable. We also find that chemical abundance patterns of companion MSs will help us to identify the origin of the binaries as star clusters. Such MSs are not polluted by outflows of the BH progenitors, such as stellar winds and supernova ejecta. Chemical anomalies might be a good test to confirm the origin of binaries with relatively less massive MSs (≲5 M⊙), short orbital periods (∼1.5 yr), and higher eccentricities (e ≳0.1).

Searching for globular cluster chemical anomalies on the main sequence of a young massive cluster

ABSTRACT The spectroscopic and photometric signals of the star-to-star abundance variations found in globular clusters seem to be correlated with global parameters like the cluster’s metallicity, mass, and age. Understanding this behaviour could bring us closer to the origin of these intriguing abundance spreads. In this work we use deep HST photometry to look for evidence of abundance variations in the main sequence of a young massive cluster NGC 419 (∼105 M⊙, ∼1.4 Gyr). Unlike previous studies, here we focus on stars in the same mass range found in old globulars (∼0.75–1 M⊙), where light elements variations are detected. We find no evidence for N abundance variations among these stars in the Un − B and U − B colour–magnitude diagrams of NGC 419. This is at odds with the N variations found in old globulars like 47 Tuc, NGC 6352, and NGC 6637 with similar metallicity to NGC 419. Although the signature of the abundance variations characteristic of old globulars appears to be significantly smaller or absent in this young cluster, we cannot conclude if this effect is mainly driven by its age or its mass.

Mass transfer of low-mass binaries and chemical anomalies among unevolved stars in globular clusters

ABSTRACT While it is well known that mass transfer in binaries can pollute the surfaces of the accretors, it is still unclear whether this mechanism can reproduce the observed chemical inhomogeneities in globular clusters. We study the surface abundances of the accretors in low-mass binaries, as a first step towards understanding whether mass transfer in low-mass binaries is one of the potential origins of the aforementioned abundance anomalies in globular clusters. We use the mesa (Modules for Experiments in Stellar Astrophysics) code to calculate binary evolutionary models with different initial donor masses between 0.9 and 1.9 $\rm {M}_\odot$ for an initial metallicity of Z = 0.0034. The results show that in some low-mass binary systems, the accretors exhibit peculiar chemical patterns when they are still unevolved stars, e.g. C and O depletion; Na and N enhancement; and constant Mg, Al, and C+N+O. The abundance patterns of the accretors are significantly different from their initial abundances (or that of normal single stars), and can match the observed populations. These abundance patterns strongly depend not only on the initial parameters of binaries (donor mass, mass ratio, and orbital period), but also on the assumptions regarding mass-transfer efficiency and angular momentum loss. These results support the hypothesis that mass transfer in low-mass binaries is, at least, partly responsible for the unevolved anomalous stars in globular clusters. More work on binary evolutionary models and binary population synthesis is required to fully evaluate the contribution of this scenario.

The search for multiple populations in Magellanic Clouds clusters – V. Correlation between cluster age and abundance spreads

ABSTRACT In our HST photometric survey, we have been searching for multiple stellar populations (MPs) in Magellanic Clouds (MCs) massive star clusters which span a significant range of ages (∼1.5–11 Gyr). In the previous papers of the series, we have shown that the age of the cluster represents one of the key factors in shaping the origin of the chemical anomalies. Here, we present the analysis of four additional clusters in the MCs, namely Lindsay 38, Lindsay 113, NGC 2121, and NGC 2155, for which we recently obtained new UV HST observations. These clusters are more massive than ∼104 M⊙ and have ages between ∼2.5 and ∼6 Gyr, i.e. located in a previously unexplored region of the cluster age/mass diagram. We found chemical anomalies, in the form of N spreads, in three out of four clusters in the sample, namely in NGC 2121, NGC 2155, and Lindsay 113. By combining data from our survey and HST photometry for three additional clusters in the Milky Way (namely 47 Tuc, M15, and NGC 2419), we show that the extent of the MPs in the form of N spread is a strong function of age, with older clusters having larger N spreads with respect to the younger ones. Hence, we confirm that cluster age plays a significant role in the onset of MPs.

HD 226766: a hierarchical SB3 system with two twin Am stars

ABSTRACT In this paper, we present a detailed revision of the orbital parameters and the first quantitative abundance analysis of the spectroscopic triple system HD 226766. By means of a simultaneous fit of the radial velocities of all the three components, we derived precise orbital parameters for the system, in particular inner pair has P(d) = 31.9187 ± 0.0001, e = 0.28 ± 0.01, and MA/MB = 1.03 ± 0.03, while the C component orbits around the inner pair with a period of P(d) = 1615 ± 59 in a very eccentric orbit (e = 0.54 ± 0.11). From the fit of the Hβ and Hα profiles, we determined the effective temperatures and surface gravities of each component of the inner pair: Teff = 8600 ± 500 K and log g = 3.8 ± 0.2 for HD 226766 A and Teff = 8500 ± 400 K and log g = 4.0 ± 0.2 for HD 226766 B. In the hypothesis that component C is a main sequence star (log g = 4.0) we derived Teff = 8000 ± 500 K. Rotational velocities have been estimated by modeling the profiles of metallic lines: v sin i = 13 ± 1 km s−1 for inner pair and v sin i = 150 ± 20 km s−1 for the C component. We find that the inner pair is heterogeneous from the point of view of the chemical composition: both stars are very similar and show chemical anomalies typical of Am stars. With some hypothesis about the masses of the components, we estimated the orbital inclination angle for the inner binary, i = (47 ± 1)○, and for the outer orbit, i = (54 ± 19)○.

The role of cluster age on the onset of multiple populations in stellar clusters

The origin of the chemical anomalies in star clusters is still an open question, although much effort has been employed both from a theoretical and observational point of view. The exploration of the dependence of such multiple stellar populations based on certain cluster properties (e.g. mass, age, metallicity) has represented a compelling line of investigation so far. Here I report an overview of the results obtained from our latest surveys aimed at characterising the phenomenon of chemical variations in star clusters that are much younger with respect to the ancient globular clusters. The fundamental question we are asking is whether these abundance patterns are only restricted to the old massive clusters; and if not, is there a difference between young and old objects?

Super star clusters and their multiple stellar populations

We present a scenario for the formation of super star clusters (with masses larger than 105 M⊙) in which multiple generations of star formation will occur. We stress that the gas left over (∼50%) from first generation (1G) star formation should be retained in such massive clusters (thanks to their deep potential wells, with escape speeds larger than 10 km/s) and be available for a second or even third generation of stars, with the basic HeCNONaMgAl chemical anomalies observed in globular clusters, the latter assumed to be the descendents of these super star clusters. One new feature of this model is the role of C+ cooling of the dense warm trapped neutral or ionized gas which defines a characteristic temperature of ∼100 K, leading to a second generation (2G) of stars with a top-heavy IMF (M > 5 M⊙). The ashes of the 2G very massive stars (VMS, M > 100 M⊙) sampled in this IMF quickly pollute and dilute the left-over pristine gas with their slow winds (that cannot escape the cluster), while the majority of massive stars develop fast winds (that actually can escape from the cluster). Meanwhile, much of the remaining dense T = 100 K gas contracts gravitationally in the massive cluster and may reach densities of the order of 109 cm−3, in which case the Jeans mass drops to about 0.2 M⊙ and leads to a substantial low-mass pre-MS 3G population (most likely on a very short timescale). In this way, we may solve both the mass budget and the excess Helium problem in proto-globular clusters, while also explaining the Na-O and Mg-Al anti-correlations resulting from hot H-burning of very massive stars at 45MK and 75MK, respectively.