SDSS-IV MaStar: Data-driven Parameter Derivation for the MaStar Stellar Library

The Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) Stellar Library (MaStar) is a large collection of high-quality empirical stellar spectra designed to cover all spectral types and ideal for use in the stellar population analysis of galaxies observed in the MaNGA survey. The library contains 59,266 spectra of 24,130 unique stars with spectral resolution R ∼ 1800 and covering a wavelength range of 3622–10,354 Å. In this work, we derive five physical parameters for each spectrum in the library: effective temperature (T eff), surface gravity ( log g ), metallicity ([Fe/H]), microturbulent velocity ( log ( v micro ) ), and alpha-element abundance ([α/Fe]). These parameters are derived with a flexible data-driven algorithm that uses a neural network model. We train a neural network using the subset of 1675 MaStar targets that have also been observed in the Apache Point Observatory Galactic Evolution Experiment (APOGEE), adopting the independently-derived APOGEE Stellar Parameter and Chemical Abundance Pipeline parameters for this reference set. For the regions of parameter space not well represented by the APOGEE training set (7000 ≤ T ≤ 30,000 K), we supplement with theoretical model spectra. We present our derived parameters along with an analysis of the uncertainties and comparisons to other analyses from the literature.

Expanding the Time Domain of Multiple Populations: Evidence of Nitrogen Variations in the ∼1.5 Gyr Old Star Cluster NGC 1783

We present the result of a detailed analysis of Hubble Space Telescope UV and optical deep images of the massive and young (∼1.5 Gyr) stellar cluster NGC 1783 in the Large Magellanic Cloud. This system does not show evidence of multiple populations (MPs) along the red giant branch (RGB) stars. However, we find that the cluster main sequence (MS) shows evidence of a significant broadening (50% larger than what is expected from photometric errors) along with hints of possible bimodality in the MP sensitive (m F343N − m F438W, m F438W) color–magnitude diagram (CMD). Such an effect is observed in all color combinations including the m F343N filter, while it is not found in the optical CMDs. This observational evidence suggests we might have found light-element chemical abundance variations along the MS of NGC 1783, which represents the first detection of MPs in a system younger than 2 Gyr. A comparison with isochrones including MP-like abundances shows that the observed broadening is compatible with a N abundance enhancement of Δ([N/Fe]) ∼ 0.3. Our analysis also confirms previous results about the lack of MPs along the cluster RGB. However, we find that the apparent disagreement between the results found on the MS and the RGB is compatible with the mixing effects linked to the first dredge up. This study provides new key information about the MP phenomenon and suggests that star clusters form in a similar way at any cosmic age.

Chemo-dynamics and asteroseismic ages of seven metal-poor red giants from the Kepler field

In this work we combine information from solar-like oscillations, high-resolution spectroscopy and Gaia astrometry to derive stellar ages, chemical abundances and kinematics for a group of seven metal-poor Red Giants and characterise them in a multidimensional chrono-chemo-dynamical space. Chemical abundance ratios were derived through classical spectroscopic analysis employing 1D LTE atmospheres on Keck/HIRES spectra. Stellar ages, masses and radii were calculated with grid-based modelling, taking advantage of availability of asteroseismic information from Kepler. The dynamical properties were determined with Galpy using Gaia EDR3 astrometric solutions. Our results suggest that underestimated parallax errors make the effect of Gaia parallaxes more important than different choices of model grid or – in the case of stars ascending the RGB – mass-loss prescription. Two of the stars in this study are identified as potentially evolved halo blue stragglers. Four objects are likely members of the accreted Milky Way halo, and their possible relationship with known accretion events is discussed.

APOGEE Chemical Abundance Patterns of the Massive Milky Way Satellites

The SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey has obtained high-resolution spectra for thousands of red giant stars distributed among the massive satellite galaxies of the Milky Way (MW): the Large and Small Magellanic Clouds (LMC/SMC), the Sagittarius Dwarf Galaxy (Sgr), Fornax (Fnx), and the now fully disrupted Gaia Sausage/Enceladus (GSE) system. We present and analyze the APOGEE chemical abundance patterns of each galaxy to draw robust conclusions about their star formation histories, by quantifying the relative abundance trends of multiple elements (C, N, O, Mg, Al, Si, Ca, Fe, Ni, and Ce), as well as by fitting chemical evolution models to the [α/Fe]–[Fe/H] abundance plane for each galaxy. Results show that the chemical signatures of the starburst in the Magellanic Clouds (MCs) observed by Nidever et al. in the α-element abundances extend to C+N, Al, and Ni, with the major burst in the SMC occurring some 3–4 Gyr before the burst in the LMC. We find that Sgr and Fnx also exhibit chemical abundance patterns suggestive of secondary star formation epochs, but these events were weaker and earlier (∼5–7 Gyr ago) than those observed in the MCs. There is no chemical evidence of a second starburst in GSE, but this galaxy shows the strongest initial star formation as compared to the other four galaxies. All dwarf galaxies had greater relative contributions of AGB stars to their enrichment than the MW. Comparing and contrasting these chemical patterns highlight the importance of galaxy environment on its chemical evolution.

The Missing Lead: Developments in the Lead (Pb) Discrepancy in Intrinsically s-Process Enriched Single Post-AGB Stars

Lead (Pb) is predicted to have large over-abundances with respect to other s-process elements in Asymptotic Giant Branch (AGB) stars, especially of low metallicities. However, our previous abundance studies of s-process enriched post-Asymptotic Giant Branch (post-AGB) stars in the Galaxy and the Magellanic Clouds show a discrepancy between observed and predicted Pb abundances. For the subset of post-AGB stars with low metallicities the determined upper limits based on detailed chemical abundance studies are much lower than what is predicted. Recent theoretical studies have pointed to the occurrence of the i-process to explain the observed chemical patterns, especially of Pb. A major development, in the observational context, is the release of the GAIA EDR3 parallaxes of the post-AGBs in the Galaxy, which has opened the gateway to systematically studying the sample of stars as a function of current luminosities (which can be linked to their initial masses). In this paper, we succinctly review the Pb discrepancy in post-AGB stars and present the latest observational and theoretical developments in this research landscape.

Antioxidant Profiling of Ginger via Reaction Flow Chromatography

Reaction flow (RF) chromatography is a powerful and efficient approach that utilizes conventional high-performance liquid chromatography (HPLC)–ultraviolet (UV)–visible detection. This technique exploits a novel column end-fitting and an extra HPLC pump that delivers a reagent specific for selective detection, in particular the antioxidant profiling of natural products. This study employed RF for the first time to identify antioxidants in a commercial ginger sample. This demonstrated the previously validated assay's ease and power to extract information about the natural product's antioxidant properties. Due to the simplicity involved with data analysis and peak matching process, the following information was revealed between the chemical and antioxidant profiles: three of the strongest antioxidant activity peaks in the ginger sample (593 nm) did not correlate with the three most abundant chemical profile peaks (UV absorbance at 254 and 280 nm); the ratio of seven antioxidant peaks may be potentially used for food authenticity purposes, and future research should target these peaks for the early discovery of novel antioxidants sourced in ginger. Utilization of this previously validated assay provided the resolution of numerous peaks in the ginger extract and information associated with their antioxidant attributes and chemical abundance. This approach is more informative than total antioxidant assays that lack compound specificity information. Furthermore, it is superior to mass spectrometric (MS) assays that cannot evaluate each compound's antioxidant strength, and does not involve the expense involved in the acquisition and maintenance of the MS detection hardware, and does not require the high level of expertise needed to conduct the MS data analysis.

Interrelations Between Astrochemistry and Galactic Dynamics

This paper presents a review of ideas that interconnect astrochemistry and galactic dynamics. Since these two areas are vast and not recent, each one has already been covered separately by several reviews. After a general historical introduction, and a needed quick review of processes such as stellar nucleosynthesis that gives the base to understand the interstellar formation of simple chemical compounds (e.g., H2, CO, NH3, and H2O), we focus on a number of topics that are at the crossing of the two big areas, dynamics and astrochemistry. Astrochemistry is a flourishing field that intends to study the presence and formation of molecules as well as the influence of them on the structure, evolution, and dynamics of astronomical objects. The progress in the knowledge on the existence of new complex molecules and of their process of formation originates from the observational, experimental, and theoretical areas that compose the field. The interfacing areas include star formation, protoplanetary disks, the role of the spiral arms, and the chemical abundance gradients in the galactic disk. It often happens that the physical conditions in some regions of the interstellar medium are only revealed by means of molecular observations. To organize a rough classification of chemical evolution processes, we discuss about how astrochemistry can act in three different contexts, namely, the chemistry of the early universe, including external galaxies, star-forming regions, and asymptotic giant branch (AGB) stars and circumstellar envelopes. We mention that our research is stimulated by plans for instruments and projects, such as the ongoing Large Latin American Millimeter Array (LLAMA), which consists in the construction of a 12 m sub-mm radio telescope in the Andes. Thus, modern and new facilities can play a key role in new discoveries not only in astrochemistry but also in radio astronomy and related areas. Furthermore, the research on the origin of life is also a stimulating perspective.

A comprehensive non-targeted analysis study of the prenatal exposome

Recent technological advances in mass spectrometry have enabled us to screen biological samples for a very broad spectrum of chemical compounds allowing us to more comprehensively characterize the human exposome in critical periods of development. The goal of this study was three-fold: 1) to analyze 590 matched maternal and cord blood samples (total 295 pairs) using non-targeted analysis (NTA); 2) examine the differences in chemical abundance between maternal and cord blood samples; and 3) examine the associations between exogenous chemicals and endogenous metabolites. We analyzed all samples with high-resolution mass spectrometry (HRMS) using liquid chromatography – quadrupole time-of-flight mass spectrometry (LC-QTOF/MS), in both positive and negative electrospray ionization modes (ESI+ and ESI-) and in soft ionization (MS) and fragmentation (MS/MS) modes for prioritized features. We confirmed 19 unique compounds with analytical standards, we tentatively identified 73 compounds with MS/MS spectra matching, and we annotated 98 compounds using an annotation algorithm. We observed 103 significant associations in maternal and 128 in cord samples between compounds annotated as endogenous and compounds annotated as exogenous. An example of these relationships was an association between 3 poly and perfluoroalkyl substances (PFAS) and endogenous fatty acids in both the maternal and cord samples indicating potential interactions between PFAS and fatty acid regulating proteins.