Modeling of Nonlinear Optical Phenomena in Host-Guest Systems Using Bond Fluctuation Monte Carlo Model: A Review

We review the results of Monte Carlo studies of chosen nonlinear optical effects in host-guest systems, using methods based on the bond-fluctuation model (BFM) for a polymer matrix. In particular, we simulate the inscription of various types of diffraction gratings in degenerate two wave mixing (DTWM) experiments (surface relief gratings (SRG), gratings in polymers doped with azo-dye molecules and gratings in biopolymers), poling effects (electric field poling of dipolar molecules and all-optical poling) and photomechanical effect. All these processes are characterized in terms of parameters measured in experiments, such as diffraction efficiency, nonlinear susceptibilities, density profiles or loading parameters. Local free volume in the BFM matrix, characterized by probabilistic distributions and correlation functions, displays a complex mosaic-like structure of scale-free clusters, which are thought to be responsible for heterogeneous dynamics of nonlinear optical processes. The photoinduced dynamics of single azopolymer chains, studied in two and three dimensions, displays complex sub-diffusive, diffusive and super-diffusive dynamical regimes. A directly related mathematical model of SRG inscription, based on the continuous time random walk (CTRW) formalism, is formulated and studied. Theoretical part of the review is devoted to the justification of the a priori assumptions made in the BFM modeling of photoinduced motion of the azo-polymer chains.

Structured light using carbon nanostructures driven by Kerr nonlinearities and a magnetic field

A substantial influence of a magnetic field on the third-order nonlinear optical properties exhibited by aggregated networks of aligned carbon nanotubes (CNT) is reported by systematic measurements. A two-wave mixing...

Sequential Photodamage Driven by Chaotic Systems in NiO Thin Films and Fluorescent Human Cells

A laser ablation process assisted by the feedback of a sensor with chaotic electronic modulation is reported. A synchronous bistable logic circuit was analyzed for switching optical signals in a laser-processing technique. The output of a T-type flip-flop configuration was employed in the photodamage of NiO films. Multiphotonic effects involved in the ablation threshold were evaluated by a vectorial two-wave mixing method. A photoinduced thermal phenomenon was identified as the main physical mechanism responsible for the nonlinearity of index under nanosecond irradiation at 532 nm wavelength. Comparative experiments for destroying highly transparent human cells were carried out. Potential applications for developing hierarchical functions yielding laser-induced controlled explosions with immediate applications for biomedical photothermal processes can be contemplated.

Navigation of Silver/Carbon Nanoantennas in Organic Fluids Explored by a Two-Wave Mixing

Within this work are analyzed third-order nonlinear optical properties with a potential influence on the dynamic mechanics exhibited by metal/carbon nanofluids. The nanofluids were integrated by multiwall carbon nanotubes decorated with Ag nanoparticles suspended in ethanol or in acetone. Optical third-order nonlinearities were experimentally explored by vectorial two-wave mixing experiments with a Nd-YAG laser system emitting nanosecond pulses at a 532 nm wavelength. An optically induced birefringence in the metal/organic samples seems to be responsible for a significant modification in density and compressibility modulus in the nanosystems. The measured nonlinear refractive index was associated with a thermal process together with changes in density, compressibility modulus and speed of sound in the samples. Nanofluid diffusivity was studied to characterize the dynamic concentration gradients related to the precipitation of nanostructures in the liquid solutions. The evolution of the nanoparticle density suspended in the nanofluids was considered as a temporal-resolved probabilistic system. It is stated that the incorporation of Ag nanoparticles in carbon nanotubes produces strong mechanical changes in carbon-based nanofluids. According to numerical simulations and optical evaluations, immediate applications for developing dynamic nanoantennas optical logic gates and quantum-controlled metal/carbon systems can be contemplated.