Tetrabenzocorrolazine dyes with high color strength and broad absorbance derived from a phthalocyanine moiety were designed and synthesized for a color filter on an array-mode black matrix of low dielectric constant. The prepared tetrabenzocorrolazine dyes focused the absorbance of phthalocyanine further into the visible light range so that the color was considerably closer to black, while making it easier to introduce an axial substituent in the vertical direction to the dye main body, thereby markedly improving its solubility in industrial solvents. Upon mixing with a perylene dye of 450-550 nm absorbance and a thermosetting resin composition, dye-based black matrix films with high optical density values, associated with superior light shielding capability, were fabricated. The prepared black matrix films not only ensured thermal resistance by allowing easy intermolecular cohesion but also served as an insulating membrane that did not interfere with the thin film transistor electric signals, exhibiting a value of 3-5 when dielectricity was measured as the most critical factor for the color filter on array mode display panels.
Molecular simulation studies of self-assembly for a chromonic perylene dye: all-atom studies and new approaches to coarse-graining
