In the previous chapter, we considered fluid turbulence from a heuristic viewpoint, combining ideas based on fundamental conservation laws with more qualitative ideas about irreversible behavior. However, there have been many attempts to study turbulence in a more quantitative and deductive fashion, beginning with the governing dynamical equations for a fluid. None of these attempts is, or could be, mathematically rigorous; all involve approximations that are difficult to justify and hard to test. In fact, these more deductive theories are perhaps best viewed as approximations in which the exact dynamical equations are replaced by stochastic-model equations having some (but not all) of the same physical properties as the exact equations, in much the same way as the quasigeostrophic equations contain only a part of the physics in the more exact primitive equations. In this chapter, we examine fluid turbulence from the standpoint of equilibrium and nonequilibrium statistical mechanics. This is a complicated and controversial subject, and our discussion will be introductory and elementary. In fact, we shall be much more concerned with the philosophy behind the statistical methods than with the detailed structure of the theory or with its successes and failures at describing real turbulence. This philosophy appears to be applicable to a much wider range of problems than so far considered. Readers who want a more thorough and complete description of statistical turbulence theory should consult more specialized sources. This chapter continues a theme, begun in chapter 4, to be continued in chapter 6, that much of our understanding of turbulence is based on two general principles: the conservation principle, which states that quantities like energy and potential vorticity are conserved (apart from the effects of dissipation), and the irreversibility principle, which holds that a turbulent system tends toward ever greater complexity. In chapter 4, we met the irreversibility principle in the assumptions that a narrow spectral peak spreads out and that nearby fluid particles tend to move apart. In this chapter, we encounter the irreversibility principle again, as a kind of macroscopic form of the Second Law of Thermodynamics.