Vibrational‐vibrational and vibrational‐thermal energy transfers of CO 2 with N 2 from MIPAS high‐resolution limb spectra

2015 ◽  
Vol 120 (15) ◽  
pp. 8002-8022 ◽  
Author(s):  
Á. A. Jurado‐Navarro ◽  
M. López‐Puertas ◽  
B. Funke ◽  
M. García‐Comas ◽  
A. Gardini ◽  
...  
1995 ◽  
Vol 50 (4-5) ◽  
pp. 405-412
Author(s):  
Michael Prager ◽  
Da Zhang ◽  
Al. Weiss

Abstract Mixed PbcSn1-c(CH3)4 samples with c = 0.0, 0.1, 0.2,0.25, 0.48, 0.5, 0.75,0.85, and 1.0 and mixed [Pb(CH3)4](.[Sn(CD3)4]1-c. samples with c = 0.02 and 0.09 were investigated by high resolution inelastic neutron scattering. Rotational tunnelling transitions are observed for energy transfers hω<100 μeV. The global features are interpreted in a single particle model. A strong matrix effect of the Pb component is attributed to changes of potential symmetry. Effects beyond the expectation of the single particle description are found


1976 ◽  
Vol 13 (2) ◽  
pp. 584-594 ◽  
Author(s):  
D. Bassi ◽  
M. G. Dondi ◽  
F. Tommasini ◽  
F. Torello ◽  
U. Valbusa

2021 ◽  
Author(s):  
Kazuho Daicho ◽  
Kayoko Kobayashi ◽  
Shuji Fujisawa ◽  
Tsuguyuki Saito

Abstract Crystallite refers to a single crystalline grain in crystal aggregates, and multiple crystallites form a grain boundary or the inter-crystallite interface. A grain boundary is a structural defect that hinders the efficient directional transfer of mechanical stress or thermal phonons in crystal aggregates. We observed that grain boundaries within an aggregate of a-few-nanometers-wide fibrillar crystallites of wood cellulose were crystallized by enhancing their inter-crystallite interactions; multiple crystallites were coupled into single fusion crystals without passing through a melting or dissolving state. Accordingly, the crystallinity of wood cellulose, which has been considered irreversible once decreased, was significantly enhanced, and the thermal energy transfer in the aggregate was improved. Other fibrillar crystallites of crab shell chitin also showed a similar fusion phenomenon by enhancing the inter-crystallite interactions. These findings imply that such crystallite fusion naturally occurs in biological structures with network skeletons of aggregated fibrillar crystallites.


2013 ◽  
Vol 135 (4) ◽  
Author(s):  
Krishnakumar Rajagopalan ◽  
Gérard C. Nihous

Global rates of ocean thermal energy conversion (OTEC) are assessed with a high-resolution (1 deg × 1 deg) ocean general circulation model (OGCM). In numerically intensive simulations, the OTEC process is represented by a pair of sinks and a source of specified strengths placed at selected water depths across the oceanic region favorable for OTEC. Results broadly confirm earlier estimates obtained with a coarse (4 deg × 4 deg) OGCM, but with the greater resolution and more elaborate description of key physical oceanic mechanisms in the present case, the massive deployment of OTEC systems appears to affect the global environment to a relatively greater extent. The maximum global OTEC power production drops to 14 TW, or about half of previously estimated levels, but it would be achieved with only one-third as many OTEC systems. Environmental effects at maximum OTEC power production are generally similar in both sets of simulations. The oceanic surface layer would cool down in tropical OTEC regions with a compensating warming trend elsewhere. Some heat would penetrate the ocean interior until the environment reaches a new steady state. A significant boost of the oceanic thermohaline circulation (THC) would occur. Although all simulations with given OTEC flow singularities were run for 1000 years to ensure stabilization of the system, convergence to a new equilibrium was generally achieved much faster, i.e., roughly within a century. With more limited OTEC scenarios, a global OTEC power production of the order of 7 TW could still be achieved without much effect on ocean temperatures.


2015 ◽  
Vol 1793 ◽  
pp. 47-52
Author(s):  
Daniele Paradiso ◽  
Enrico Perelli Cippo ◽  
Giuseppe Gorini ◽  
Giorgio Rossi ◽  
J. Z. Larese

ABSTRACTUsing a combination of x-ray diffraction, volumetric adsorption and inelastic neutron scattering (INS) the adsorption properties of methane within the channels of L-Isoleucyl-L-Valine (IV) and L-Valyl-L-Alanine (VA) dipeptides have been investigated. These biomaterials have quasi one-dimensional channels of tunable diameters in the range of 3-6 Å and offer possibilities for selective adsorption, as well as, water and gas transport properties. High-resolution volumetric methane adsorption measurements performed near 100K for IV find that this biomaterial exhibits an adsorption capacity of ∼100 m2/g. High-resolution Inelastic Neutron Scattering (INS) measurements were performed at the Spallation Neutron Source using the BASIS spectrometer with ∼ 3.5 μeV resolution. The data clearly indicate that at least two spectral features at energy transfers near 100 and 200 μeV are present, which suggests a lowering of the hindering potential for methane reorientation primarily about the three-fold axis within the IV channels. Such features play a key role in understanding details concerning the potential energy surface. These thermodynamic and INS studies suggest that the flexibility and dynamical motion within the dipeptide channels may play a significant role in the adsorption properties.


2005 ◽  
Vol 16 (12) ◽  
pp. 3137-3141 ◽  
Author(s):  
Sunwoo Lee ◽  
Haiwon Lee ◽  
Byung-jae Park ◽  
Geun Young Yeom

1967 ◽  
Vol 31 ◽  
pp. 45-46
Author(s):  
Carl Heiles

High-resolution 21-cm line observations in a region aroundlII= 120°,b11= +15°, have revealed four types of structure in the interstellar hydrogen: a smooth background, large sheets of density 2 atoms cm-3, clouds occurring mostly in groups, and ‘Cloudlets’ of a few solar masses and a few parsecs in size; the velocity dispersion in the Cloudlets is only 1 km/sec. Strong temperature variations in the gas are in evidence.


2019 ◽  
Vol 42 ◽  
Author(s):  
J. Alfredo Blakeley-Ruiz ◽  
Carlee S. McClintock ◽  
Ralph Lydic ◽  
Helen A. Baghdoyan ◽  
James J. Choo ◽  
...  

Abstract The Hooks et al. review of microbiota-gut-brain (MGB) literature provides a constructive criticism of the general approaches encompassing MGB research. This commentary extends their review by: (a) highlighting capabilities of advanced systems-biology “-omics” techniques for microbiome research and (b) recommending that combining these high-resolution techniques with intervention-based experimental design may be the path forward for future MGB research.


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