Original In-Situ Method to Quantify the SiC Active Corrosion Rate and Active/Passive Transition in Ar/O2and Ar/H2O Gas Mixtures at Very High Temperatures

2012 ◽  
pp. 77-88
Author(s):  
Mathieu Q. Brisebourg ◽  
Bernard Boilait ◽  
Francis Rebillat ◽  
Francis Teyssandier
Keyword(s):  
Corrosion Rate ◽  
High Temperatures ◽  
Gas Mixtures ◽  
In Situ Method ◽  
Passive Transition ◽  
Very High ◽  
Active Corrosion

In-situ Hrem Heating Experiments at Very High Temperatures

1995 ◽  
Vol 404 ◽  
Author(s):  
T. Kamino ◽  
H. Saka
Keyword(s):  
High Temperature ◽  
High Temperatures ◽  
Atomic Resolution ◽  
Very High

AbstractA specimen-heating holder which allows an observation of reactions of more than one materials, in a controlled manner, at such a high temperature as 1723K has been developed. Facet-unfacet transformation and reconstruction of Au-deposited Si surfaces have been observed at very high temperatures at near-atomic resolution.

High Resolution Electron Microscopy In Situ Observation of Dynamic Behavior of Grain Boundaries and Interfaces at Very High Temperatures

1997 ◽  
Vol 3 (5) ◽  
pp. 393-408 ◽  
Author(s):  
T. Kamino ◽  
K. Sasaki ◽  
H. Saka
Keyword(s):  
Electron Microscopy ◽  
High Resolution ◽  
Grain Boundaries ◽  
Dynamic Behavior ◽  
High Temperatures ◽  
High Resolution Electron Microscopy ◽  
In Situ Observation ◽  
Resolution Electron ◽  
Very High

High Resolution Electron Microscopy In Situ Observation of Dynamic Behavior of Grain Boundaries and Interfaces at Very High Temperatures

In situ REM imaging of surface processes on ceramic bulk crystals from 300 to 1670 K in a conventional TEM

1991 ◽  
Vol 49 ◽  
pp. 660-661
Author(s):  
Z. L. Wang ◽  
J. Bentley
Keyword(s):  
High Temperatures ◽  
Image Resolution ◽  
Atomic Processes ◽  
Crystal Surfaces ◽  
Beam Radiation ◽  
Surface Areas ◽  
Transmission Electron ◽  
Reflection Electron Microscopy ◽  
Gas Reactions

Studying the behavior of surfaces at high temperatures is of great importance for understanding the properties of ceramics and associated surface-gas reactions. Atomic processes occurring on bulk crystal surfaces at high temperatures can be recorded by reflection electron microscopy (REM) in a conventional transmission electron microscope (TEM) with relatively high resolution, because REM is especially sensitive to atomic-height steps.Improved REM image resolution with a FEG: Cleaved surfaces of a-alumina (012) exhibit atomic flatness with steps of height about 5 Å, determined by reference to a screw (or near screw) dislocation with a presumed Burgers vector of b = (1/3)<012> (see Fig. 1). Steps of heights less than about 0.8 Å can be clearly resolved only with a field emission gun (FEG) (Fig. 2). The small steps are formed by the surface oscillating between the closely packed O and Al stacking layers. The bands of dark contrast (Fig. 2b) are the result of beam radiation damage to surface areas initially terminated with O ions.

The Nature of Chemisorbed CO2 in Zeolite A

2019 ◽  
Author(s):  
Przemyslaw Rzepka ◽  
Zoltán Bacsik ◽  
Andrew J. Pell ◽  
Niklas Hedin ◽  
Aleksander Jaworski
Keyword(s):  
Solid State ◽  
Ir Spectroscopy ◽  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Surface Coverage ◽  
Gas Mixtures ◽  
Mas Nmr ◽  
Significant Fraction ◽  
Zeolite A

Formation of CO<sub>3</sub><sup>2-</sup> and HCO<sub>3</sub><sup>-</sup> species without participation of the framework oxygen atoms upon chemisorption of CO<sub>2</sub> in zeolite |Na<sub>12</sub>|-A is revealed. The transfer of O and H atoms is very likely to have proceeded via the involvement of residual H<sub>2</sub>O or acid groups. A combined study by solid-state <sup>13</sup>C MAS NMR, quantum chemical calculations, and <i>in situ</i> IR spectroscopy showed that the chemisorption mainly occurred by the formation of HCO<sub>3</sub><sup>-</sup>. However, at a low surface coverage of physisorbed and acidic CO<sub>2</sub>, a significant fraction of the HCO<sub>3</sub><sup>-</sup> was deprotonated and transformed into CO<sub>3</sub><sup>2-</sup>. We expect that similar chemisorption of CO<sub>2</sub> would occur for low-silica zeolites and other basic silicates of interest for the capture of CO<sub>2</sub> from gas mixtures.

Beyond Ni-based superalloys: Development of CoRe-based alloys for gas turbine applications at very high temperatures

2011 ◽  
Vol 102 (9) ◽  
pp. 1125-1132 ◽  
Author(s):  
Debashis Mukherji ◽  
Joachim Rösler ◽  
Pavel Strunz ◽  
Ralph Gilles ◽  
Gerhard Schumacher ◽  
...  
Keyword(s):  
Gas Turbine ◽  
High Temperatures ◽  
Very High

COOPER ALLOY 22W

Alloy Digest ◽  
1963 ◽  
Vol 12 (8) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Creep Rate ◽  
Corrosion Rate ◽  
Physical Properties ◽  
High Strength ◽  
Heat Treating ◽  
Casting Alloy ◽  
Hot Gas ◽  
Gas Corrosion ◽  
Very High

Abstract Cooper Alloy 22W is a high strength, heat resistant casting alloy with a low creep rate. It is recommended for heat applications where stress and hot gas corrosion rate are very high. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as casting, heat treating, machining, joining, and surface treatment. Filing Code: SS-146. Producer or source: Cooper Alloy Corporation.

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