Strong Band Gap Blueshift in Copper (I) Oxide Semiconductor via Bioinspired Route

2020 ◽  
Vol 30 (13) ◽  
pp. 1910405 ◽  
Author(s):  
Iryna Polishchuk ◽  
Nuphar Bianco‐Stein ◽  
Arad Lang ◽  
Mariam Kurashvili ◽  
Maytal Caspary Toroker ◽  
...  
2018 ◽  
Vol 4 (5) ◽  
pp. 542-545 ◽  
Author(s):  
R. Shabu ◽  
A. Moses Ezhil Raj

As major attention has been paid to transition metal oxide semiconductor suitable for solar cell, photo detector and gas sensor, present study embark on the structural, optical and electrical characterization of Ag doped CuO thin films prepared using chemical spray pyrolysis technique at the constant substrate temperature of 350 �C. For Ag doping, various concentrations of silver acetate (0.5-3.0 wt.%) was used in the sprayed precursor solution. Confirmed monoclinic lattice shows the tenorite phase formation of CuO in the pure and Ag doped films. The optical band gap of the films was in the range of 2.4 -3.4 eV. A minimum resistivity of 0.0017x103 ohmcm was achieved in the 0.5 wt.% Ag doped film, and its optical band gap was 2.74 eV.


2019 ◽  
Vol 126 (9) ◽  
pp. 095704 ◽  
Author(s):  
Jing Zhang ◽  
Yuejing Wang ◽  
Shoaib Khalid ◽  
Anderson Janotti ◽  
Greg Haugstad ◽  
...  

2010 ◽  
Vol 47 (3) ◽  
pp. 369-376 ◽  
Author(s):  
D. Schmeißer ◽  
K. Henkel ◽  
M. Bergholz ◽  
M. Tallarida

2012 ◽  
Vol 19 (06) ◽  
pp. 1250064 ◽  
Author(s):  
WEITAO SU ◽  
QIUHUI ZHUANG ◽  
DEXUAN HUO ◽  
BIN LI

The continuous downscaling of metal oxide semiconductor field effect transistors (MOSFET) on silicon, germanium, GaAs , etc. still demands the creation of new high-k dielectrics with even better material performance. In this research, a new ternary high-k dielectric film, LaSmO3 , is deposited using electron-beam evaporation. The structure and high temperature interfacial thermal stabilities are investigated by X-ray diffraction (XRD), X-ray photon electronic spectra (XPS), infrared attenuated total reflection (ATR) and time of flight second ion mass spectroscopy (ToF-SIMS). The band gap and band offset are determined using the O 1s energy loss spectra and valence band difference between film and substrate, respectively, from the XPS spectra. Capacitance-voltage (CV) and current-voltage (IV) curves are measured to give an insight of the dielectric and leakage current of this material. It is found that crystallization temperature of LaSmO3 is >1000°C. The high dielectric constant (k) = 24.6, large band gap (Eg) > 7 eV and low leakage current (1.8 × 10-4 A/cm2, 1 MV/cm) make LaSmO3 to be a promising high-k candidate.


2013 ◽  
Vol 2 (6) ◽  
pp. 637-678 ◽  
Author(s):  
Yan Zhu ◽  
Mantu K. Hudait

AbstractReducing supply voltage is a promising way to address the power dissipation in nano-electronic circuits. However, the fundamental lower limit of subthreshold slope (SS) within metal oxide semiconductor field effect transistors (MOSFETs) is a major obstacle to further scaling the operation voltage without degrading ON/OFF ratio in current integrated circuits. Tunnel field-effect transistors (TFETs) benefit from steep switching characteristics due to the quantum-mechanical tunneling injection of carriers from source to channel, rather than by conventional thermionic emission in MOSFETs. TFETs based on group III-V compound semiconductor materials further improve the ON-state current and reduce SS due to the low band gap energies and smaller carrier tunneling mass. The mixed arsenide/antimonide (As/Sb) InxGa1-xAs/GaAsySb1-y heterostructures allow a wide range of band gap energies and various staggered band alignments depending on the alloy compositions in the source and channel materials. Band alignments at source/channel heterointerface can be well modulated by carefully controlling the compositions of the mixed As/Sb material system. In particular, this review introduces and summarizes the progress in the development and optimization of low-power TFETs using mixed As/Sb based heterostructures including basic working principles, design considerations, material growth, interface engineering, material characterization, device fabrication, device performance investigation, band alignment determination, and high temperature reliability. A review of TFETs using mixed As/Sb based heterostructures shows superior structural properties and distinguished device performance, both of which indicate the mixed As/Sb staggered gap TFET as a promising option for high-performance, low-standby power, and energy-efficient logic circuit application.


Crystals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1216
Author(s):  
Gopal Singh Attar ◽  
Mimi Liu ◽  
Cheng-Yu Lai ◽  
Daniela R. Radu

Compositionally controlled, light-emitting, group IV semiconductor nanomaterials have potential to enable on-chip data communications and infrared (IR) imaging devices compatible with the complementary metal−oxide−semiconductor (CMOS) technology. The recent demonstration of a direct band gap laser in Ge-Sn alloys opens avenues to the expansion of Si-photonics. Ge-Sn alloys showed improved effective carrier mobility as well as direct band gap behavior at Sn composition above 6–11%. In this work, Ge1−xSnx alloy nanoparticles with varying Sn compositions from x = 0.124 to 0.178 were prepared via colloidal synthesis using sodium borohydride (NaBH4), a mild and non-hazardous reducing reagent. Successful removal of the synthesized long-alkyl-chain ligands present on nanoparticles’ surfaces, along with the passivation of the Ge-Sn nanoparticle surface, was achieved using aqueous (NH4)2S. The highly reactive surface of the nanoparticles prior to ligand exchange often leads to the formation of germanium oxide (GeO2). This work demonstrates that the (NH4)2S further acts as an etching reagent to remove the oxide layer from the particles’ surfaces. The compositional control and long-term stability will enable the future use of these easily prepared Ge1−xSnx nanoalloys in optoelectronic devices.


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