scholarly journals Tuning Nanofillers in In Situ Prepared Polyimide Nanocomposites for High‐Temperature Capacitive Energy Storage

2020 ◽  
Vol 10 (16) ◽  
pp. 1903881 ◽  
Author(s):  
Ding Ai ◽  
He Li ◽  
Yao Zhou ◽  
Lulu Ren ◽  
Zhubing Han ◽  
...  
2018 ◽  
Vol 48 (1) ◽  
pp. 219-243 ◽  
Author(s):  
Qi Li ◽  
Fang-Zhou Yao ◽  
Yang Liu ◽  
Guangzu Zhang ◽  
Hong Wang ◽  
...  

The demand for high-temperature dielectric materials arises from numerous emerging applications such as electric vehicles, wind generators, solar converters, aerospace power conditioning, and downhole oil and gas explorations, in which the power systems and electronic devices have to operate at elevated temperatures. This article presents an overview of recent progress in the field of nanostructured dielectric materials targeted for high-temperature capacitive energy storage applications. Polymers, polymer nanocomposites, and bulk ceramics and thin films are the focus of the materials reviewed. Both commercial products and the latest research results are covered. While general design considerations are briefly discussed, emphasis is placed on material specifications oriented toward the intended high-temperature applications, such as dielectric properties, temperature stability, energy density, and charge-discharge efficiency. The advantages and shortcomings of the existing dielectric materials are identified. Challenges along with future research opportunities are highlighted at the end of this review.


2021 ◽  
pp. 2101976
Author(s):  
Zhizhan Dai ◽  
Zhiwei Bao ◽  
Song Ding ◽  
Chuanchuan Liu ◽  
Haoyang Sun ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 6032
Author(s):  
Bo Yang ◽  
Yang Liu ◽  
Wenjie Ye ◽  
Qiyang Wang ◽  
Xiao Yang ◽  
...  

The encapsulation and heat conduction of molten salt are very important for its application in heat storage systems. The general practice is to solidify molten salt with ceramic substrate and enhance heat conduction with carbon materials, but the cycle stability is not ideal. For this reason, it is of practical significance to study heat storage materials with a carbon-free thermal conductive adsorption framework. In this paper, the in-situ reaction method was employed to synthetize the constant solid-state composites for high-temperature thermal energy storage. AlN is hydrolyzed and calcined to form h-Al2O3 with a mesoporous structure to prevent the leakage of molten eutectic salt at high temperature. Its excellent thermal conductivity simultaneously improves the thermal conductivity of the composites. It is found that 15CPCMs prepared with 15% water addition have the best thermal conductivity (4.928 W/m·K) and mechanical strength (30.2 MPa). The enthalpy and the thermal storage density of 15CPCMs are 201.4 J/g and 1113.6 J/g, respectively. Due to the excellent leak-proof ability and lack of carbon materials, the 15CPCMs can maintain almost no mass loss after 50 cycles. These results indicate that 15CPCMs have promising prospects in thermal storage applications.


2017 ◽  
Vol 9 (27) ◽  
pp. 22799-22807 ◽  
Author(s):  
Christian Reitz ◽  
Di Wang ◽  
Daniela Stoeckel ◽  
Andre Beck ◽  
Thomas Leichtweiss ◽  
...  

2020 ◽  
Author(s):  
Tapas Dutta ◽  
Abhijit Patra

<div> <p>Covalent organic frameworks (COFs) with layered architecture with open nanochannels and high specific surface areas are promising candidates for energy storage. However, the low electrical conductivity of two-dimensional COFs often limits their scope in energy storage applications. The conductivity of COFs can be enhanced through post-synthetic modification with conducting polymers. Herein, we developed polyaniline (PANI) modified triazine-based COFs via <i>in situ</i> polymerization of aniline with the porous frameworks. The composite materials showed high conductivity of 1.4-1.9 x 10<sup>-2</sup> S cm<sup>-1</sup> at room temperature with 10-fold enhancement in specific capacitance than the pristine frameworks. The fabricated supercapacitor exhibited a high energy density of 24.4 W h kg<sup>-1</sup> and a power density of 200 W kg<sup>-1</sup> at 0.5 A g<sup>-1 </sup>current density. Moreover, the device fabricated using the conducting polymer-triazine COF composite can light up a green light-emitting diode for 1 min after being charged for 10 s.</p></div>


2021 ◽  
Author(s):  
He Li ◽  
Yao Zhou ◽  
Yang Liu ◽  
Li Li ◽  
Yi Liu ◽  
...  

The growing demand for advanced electronics requires dielectrics operating at high temperatures. The development of high-temperature dielectric polymers is reviewed from the perspective of structure design, dielectric and capacitive performance.


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