Thermal decomposition characteristics of poly[diethyl-2-(methacryloyloxy)ethyl phosphate] using thermogravimetric analysis/mass spectrometry

2002 ◽  
Vol 85 (4) ◽  
pp. 821-830 ◽  
Author(s):  
L. H. Perng ◽  
C. J. Tsai ◽  
Y. C. Ling ◽  
S. D. Wang ◽  
C. Y. Hsu
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Ethyl Phosphate

scholarly journals Unexpected thermal decomposition behavior of poly(N-vinylimidazole)-l-poly(tetrahydrofuran) amphiphilic conetworks, a class of chemically forced blends

RSC Advances ◽  
2015 ◽  
Vol 5 (23) ◽  
pp. 17413-17423 ◽  
Author(s):  
Csaba Fodor ◽  
János Bozi ◽  
Marianne Blazsó ◽  
Béla Iván
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Chemical Processes ◽  
Thermal Decomposition Behavior ◽  
Decomposition Behavior

The underlying chemical processes of the unexpected thermal decomposition behavior of poly(N-vinylimidazole)-l-poly(tetrahydrofuran) amphiphilic conetworks were investigated by thermogravimetric analysis and thermogravimetry-mass spectrometry.

A Study On The Thermal Decomposition of Ba(tmhd)2 and Sr(tmhd)2

1995 ◽  
Vol 415 ◽  
Author(s):  
Hyun-Kyu Ryu ◽  
Jae Hyun Han ◽  
Sang Heup Moon
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Metal Atom ◽  
Bond Energies ◽  
Partial Decomposition ◽  
Temperature Range ◽  
Long Period

ABSTRACTDecomposition of Sr(tmhd)2 and Ba(tmhd)2 was investigated by thermogravimetric analysis, in-situ FTIR, and mass spectrometry. Both compounds decomposed following 3 steps: 1) decomposition of the ligands, 2) simultaneous vaporization and partial decomposition of metal-organics, and 3) decomposition of the vaporized metal-organics which existed as the oligomeric species.The Sr source decomposed at lower temperatures and in a narrower temperature range than the Ba source. Also, the gaseous oligomeric species from the Sr source decomposed relatively quickly while the corresponding species from the Ba source decomposed slowly over a long period. Such a difference between the two compounds is due to different bond energies between the metal atom and the ligands, as indicated by our FTIR results.

Thermal decomposition kinetics and characteristics of Spartina alterniflora via thermogravimetric analysis

2014 ◽  
Vol 68 ◽  
pp. 111-117 ◽  
Author(s):  
Yue-gan Liang ◽  
Beijiu Cheng ◽  
You-bin Si ◽  
De-ju Cao ◽  
Hai-yang Jiang ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Spartina Alterniflora ◽  
Decomposition Kinetics ◽  
Thermal Decomposition Kinetics

scholarly journals Thermal degradation behaviour of some polydithiooxamide metal complexes

2006 ◽  
Vol 31 (1) ◽  
pp. 45-52 ◽  
Author(s):  
H. Al-Maydama ◽  
A. El-Shekeil ◽  
M. A. Khalid ◽  
A. Al-Karbouly
Keyword(s):  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Integral Method ◽  
Valence Shell ◽  
Degradation Behaviour ◽  
Thermal Stabilities ◽  
Electron Pairs ◽  
Thermal Decomposition Behavior ◽  
The Difference ◽  
Decomposition Behavior

The thermal decomposition behavior of the Fe(II), Co(II), Ni(II) and Zn(II) complexes of polydithiooxamide has been investigated by thermogravimetric analysis (TGA) at a heating rate of 20°C min-1 under nitrogen. The Coats-Redfern integral method is used to evaluate the kinetic parameters for the successive steps in the decomposition sequence observed in the TGA curves. The processes of thermal decomposition taking place in the four complexes are studied comparatively as the TGA curves indicate the difference in the thermal decomposition behavior of these complexes. The thermal stabilities of these complexes are discussed in terms of repulsion among electron pairs in the valence shell of the central ion and electronegativity effects.

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