The effect of epoxy and tetramethyl thiuram disulfide on melt-grafting of maleic anhydride onto polypropylene by reactive extrusion

2016 ◽  
Vol 133 (22) ◽  
pp. n/a-n/a ◽  
Author(s):  
Jinfen Lou ◽  
Zhu Luo ◽  
Yang Li
Keyword(s):  
Maleic Anhydride ◽  
Reactive Extrusion ◽  
Melt Grafting

In the melt, grafting of polycarbonate onto polystyrene-block -poly(ethylene-butylene)-block -polystyrene-grafted -maleic anhydride: Reactive extrusion

2013 ◽  
Vol 54 (11) ◽  
pp. 2660-2668
Author(s):  
Celine Chevallier ◽  
Frederic Becquart ◽  
Cyril Benoit ◽  
Jean-Charles Majeste ◽  
Mohamed Taha
Keyword(s):  
Maleic Anhydride ◽  
Reactive Extrusion ◽  
Melt Grafting ◽  
Poly Ethylene

Functionalization of isotactic polypropylene with maleic anhydride by reactive extrusion: mechanism of melt grafting

Polymer ◽  
2001 ◽  
Vol 42 (13) ◽  
pp. 5549-5557 ◽  
Author(s):  
Dean Shi ◽  
Jinghui Yang ◽  
Zhanhai Yao ◽  
Yong Wang ◽  
Hongliang Huang ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Isotactic Polypropylene ◽  
Reactive Extrusion ◽  
Melt Grafting ◽  
Extrusion Mechanism

Melt grafting of maleic anhydride onto elastomeric ethylene-octene copolymer by reactive extrusion

2001 ◽  
Vol 41 (11) ◽  
pp. 1978-1986 ◽  
Author(s):  
K. Premphet ◽  
S. Chalearmthtlpa
Keyword(s):  
Maleic Anhydride ◽  
Reactive Extrusion ◽  
Melt Grafting ◽  
Ethylene Octene Copolymer

scholarly journals Acyloxyimide derivatives as efficient promoters of polyolefin C–H functionalization: application in the melt grafting of maleic anhydride onto polyethylene

2019 ◽  
Vol 10 (31) ◽  
pp. 4336-4345 ◽  
Author(s):  
Mamy Daniel Rakotonirina ◽  
Marc Baron ◽  
Didier Siri ◽  
Anouk Gaudel-Siri ◽  
Sébastien Quinebeche ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Melt Grafting

Acyloxyimides as a new H-abstracting agent have been developed for the radical grafting of maleic anhydride (MA) onto polyethylene in the melt state.

scholarly journals Preparation of Maleic Anhydride Grafted Poly(trimethylene terephthalate) (PTT-g-MA) by Reactive Extrusion Processing

2019 ◽  
Vol 3 (2) ◽  
pp. 37 ◽  
Author(s):  
Natália F. Braga ◽  
Henrique M. Zaggo ◽  
Thaís L. A. Montanheiro ◽  
Fabio R. Passador
Keyword(s):  
Thermal Properties ◽  
Maleic Anhydride ◽  
Acrylonitrile Butadiene Styrene ◽  
Reactive Extrusion ◽  
Processing Route ◽  
Parallel Plates ◽  
Reactive Processing ◽  
Scanning Calorimetry ◽  
Trimethylene Terephthalate ◽  
Compatibilizing Agent

Maleic anhydride (MA) grafted with poly(trimethylene terephthalate) (PTT)—abbreviated as PTT-g-MA—can be used as a compatibilizing agent to improve the compatibility and dispersion of nanofillers and a dispersed polymer phase into PTT matrix. This work suggests the preparation of PTT-g-MA using a mixture of PTT, MA, and benzoyl peroxide (BPO) by a reactive extrusion process. PTT-g-MA was characterized to confirm the grafting reaction of maleic anhydride on PTT chains by Fourier transform infrared (FTIR) spectroscopy. Thermal properties (differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA)) and rheological analysis (parallel plates rheology) were used to prove the changes that occurred after the graphitization reaction. The reactive processing route allowed the production of the compatibilizing agent (PTT-g-MA) with good thermal properties and with lower viscosity compared to neat PTT, and this could be an alternative for the compatibilization of polymer blends, as example for PTT/ABS (acrylonitrile butadiene styrene) blends and nanocomposites based on PTT matrix.

scholarly journals Effects of Methylenediphenyl 4,4’-Diisocyanate and Maleic Anhydride as Coupling Agents on the Properties of Polylactic Acid/Polybutylene Succinate/Wood Flour Biocomposites by Reactive Extrusion

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1660
Author(s):  
Young-Rok Seo ◽  
Sang-U Bae ◽  
Jaegyoung Gwon ◽  
Qinglin Wu ◽  
Birm-June Kim
Keyword(s):  
Maleic Anhydride ◽  
Polylactic Acid ◽  
Viscoelastic Properties ◽  
Interfacial Adhesion ◽  
Wood Flour ◽  
Flexural Modulus ◽  
Reactive Extrusion ◽  
Coupling Agents ◽  
Polybutylene Succinate

Polylactic acid (PLA)/polybutylene succinate (PBS)/wood flour (WF) biocomposites were fabricated by in situ reactive extrusion with coupling agents. Methylenediphenyl 4,4’-diisocyanate (MDI) and maleic anhydride (MA) were used as coupling agents. To evaluate the effects of MDI and MA, various properties (i.e., interfacial adhesion, mechanical, thermal, and viscoelastic properties) were investigated. PLA/PBS/WF biocomposites without coupling agents revealed poor interfacial adhesion leading to deteriorated properties. However, the incorporation of MDI and/or MA into biocomposites showed high performances by increasing interfacial adhesion. For instance, the incorporation of MDI resulted in improved tensile, flexural, and impact strengths and an increase in tensile and flexural modulus was observed by the incorporation of MA. Specially, remarkably improved thermal stability was found in the PLA/PBS/WF biocomposites with 1 phr MDI and 1 phr MA. Also, the addition of MDI or MA into biocomposites increased the glass transition temperature and crystallinity, respectively. For viscoelastic property, the PLA/PBS/WF biocomposites with 1 phr MDI and 1 phr MA achieved significant enhancement in storage modulus compared to biocomposites without coupling agents. Therefore, the most balanced performances were evident in the PLA/PBS/WF biocomposites with the hybrid incorporation of small quantities of MDI and MA.

scholarly journals Maleic Anhydride-Grafted Isotactic Polybutene-1 and Modified Polyamide 6

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 872 ◽  
Author(s):  
Yongxian Zhao ◽  
Chen Ma ◽  
Shijie Cheng ◽  
Wei Xu ◽  
Yuejuan Du ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Crystallization Rate ◽  
Polyamide 6 ◽  
Melt Flow Rate ◽  
Elongation At Break ◽  
Melt Grafting ◽  
Relative Molecular Weight ◽  
Two Phases ◽  
Optimized Conditions ◽  
Dsc Curves

Maleic anhydride (MAH)–divinyl benzene (DVB) multi-monomer melt-grafting onto isotactic polybutene-1 (iPB-1) was carried out in a torque rheometer. The effects of dicumyl peroxide (DCP), MAH, and DVB concentrations, and temperature, on the reaction, were investigated. The optimized conditions were 170 °C, DVB/MAH = 4:6 (mass ratio). DVB as a comonomer enhanced the grafting degree (Gd) and grafting efficiency (Ge) of iPB-g-MAH better than styrene. The initiator DCP had little effect on Gd as its concentration over 0.2 phr, but the grafts’ melt flow rate (MFR) increased significantly, and relative molecular weight decreased remarkably with increased DCP concentration. With increasing Gd, the contact angle of grafts with water decreased, and there was a larger crystallization rate. The study of iPB-1 and iPB-g-MAH (Gd = 1.5%)-modified polyamide 6 (PA6) showed that iPB-g-MAH had an obviously toughening effect on PA6. With increasing iPB-g-MAH concentration, the blends of impact strength and elongation at break increased obviously, tensile strength decreased slightly, and MFR decreased prominently, which greatly slowed the processing degradation of PA6. The properties of iPB-1/PA6 blends deteriorated. Both DSC curves and SEM micrographs confirmed that PA6/iPB-g-MAH blends had much better compatibility than PA6/iPB. The reason was that the anhydride group in iPB-g-MAH reacted with amide group in PA6 to improve the compatibility between two phases, and iPB-g-MAH is an excellent modifier for PA6.

Melt-grafting mechanism study of maleic anhydride onto polypropylene with 1-decene as the second monomer

2011 ◽  
Vol 121 (6) ◽  
pp. 3724-3732 ◽  
Author(s):  
Caihong Lei ◽  
Dahua Chen ◽  
Bo Wu ◽  
Yunqi Xu ◽  
Shanliang Li ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Mechanism Study ◽  
Melt Grafting
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