Oxygen electrode response lag induced by liquid film resistance against oxygen transfer

1976 ◽  
Vol 18 (11) ◽  
pp. 1537-1555 ◽  
Author(s):  
V. Linek ◽  
V. Vacek
Author(s):  
G. Sriram ◽  
Y. Manjula Rao ◽  
K. Suresh ◽  
G. K. Sureshkumar

1982 ◽  
Vol 14 (1-2) ◽  
pp. 321-329 ◽  
Author(s):  
T Matsuo ◽  
K Hirayama

The liquid film coefficient of the oxygen transfer at air-water surfaces is dependent on turbulence characteristics of the flow. There are two methods for evaluating the liquid film coefficient with relation to turbulence; One is based on the root mean square velocity fluctuation and the larger scale movement and the other is based on the energy dissipation rate and the smaller scale movement. Conclusions obtained from some experimental and dimensional analyses imply that, for the mass transfer mechanism at the air-water surfaces, larger scale turbulent motion is dominated over smaller scale eddies represented by Kolmogoroff's micro-scale.


1989 ◽  
Vol 6 (4) ◽  
pp. 350-353
Author(s):  
Ho Nam Chang ◽  
Dong Jin Kim ◽  
Murray Moo-Young

2013 ◽  
Vol 864-867 ◽  
pp. 1784-1788
Author(s):  
Hong Jian Xu ◽  
Hao Ran Li ◽  
Shu Fang Wang ◽  
Ji Zhao Jin ◽  
Wei Guo Pan ◽  
...  

In this research, an experimental apparatus that composed of adiabatic packed absorption and regeneration columns was established to simulate H2S removal process. The results show that the reaction between CO2 and MDEA can be regarded as a rapid pseudo-first-order reversible reaction and the CO2 absorption mainly is controlled by liquid film resistance while the reaction between H2S and MDEA are reversible instantaneous. For H2S absorption, it is mainly controlled by gas film resistance but the rate of liquid film resistance to the total resistance of H2S absorption was distributed from 25.7% (column bottom) to 12.6% (column up).


1983 ◽  
Vol 48 (3) ◽  
pp. 798-804 ◽  
Author(s):  
Lumír Macholán ◽  
Hana Konečná

The paper describes a rapid method for the biospecific determination of sucrose using an oxygen electrode of the Clark type or a platinum disc anode, the measuring part of which is coated by a thin film of invertase, mutarotase and glucose oxidase co-crosslinked by glutardialdehyde together with serum albumin. After injecting the sample into the reaction vessel the current corresponding to the decrease of the oxygen content or to the formation of hydrogen peroxide in the enzyme reaction layer is registered. The steady state electrode response is proportional to the concentration of sucrose within the range of 0.03 to 1.5 mmol . l-1 and is attained during 1-2 minutes with a reproducibility of 3-4%.


2007 ◽  
Vol 55 (11) ◽  
pp. 183-191 ◽  
Author(s):  
H. Zhu ◽  
T. Imai ◽  
K. Tani ◽  
M. Ukita ◽  
M. Sekine ◽  
...  

In aerated ponds, oxygen is generally supplied through either diffused or mechanical aeration means. Surface transfer and bubble transfer both contribute significantly to oxygen transfer in a diffused aeration system. In the present study, a liquid-film-forming apparatus (LFFA) is successfully developed on a laboratory scale to improve considerably the surface transfer via the unique liquid film transfer technique. The experimental results show that the volumetric mass transfer coefficient for LFFA alone is found to be as much as 5.3 times higher than that for water surface and that the total volumetric mass transfer coefficient for the liquid film aeration system increases by 37% in comparison with a conventional aeration system. Additionally, by tuning finely the structural parameters of the LFFA, it can also lead to high dissolved oxygen (DO) water with the DO percent saturation greater than 90%. More importantly, this result is accomplished by simply offering a single-pass aeration at a depth as shallow as 26 cm. As a result, the objective of economical energy consumption in aerated ponds can be realized by lowering the aeration depth without sacrificing the aeration efficiency. It is noteworthy that the data presented in this study are acquired either numerically or experimentally.


2007 ◽  
Vol 28 (5) ◽  
pp. 511-519 ◽  
Author(s):  
H. Zhu ◽  
T. Imai ◽  
K. Tani ◽  
M. Ukita ◽  
M. Sekine ◽  
...  

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