Ligand Cleavage Put into Reverse: PC Bond Breaking and Remaking in an Alkylphosphane Iron Complex

The study of the interaction between complexed iron and tumor cells in the presence of 67Ga-citrate indicates that a phenomenon of iron-binding related to the thermodynamic constant of stability of the iron complex, and a hydrolysis (or anion penetration) of the interaction product determine the uptake of 67Ga. The effects of various parameters such as ionic composition of the medium, nature of the iron complex, time of incubation and number of cells are discussed.

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MOLECULAR AND CRYSTAL STRUCTURE OF A CATIONIC DINITROSYL IRON COMPLEX WITH 1,3-DIMETHYLTHIOUREA

Журнал структурной химии ◽

10.15372/jsc20170217 ◽

2017 ◽

Keyword(s):

Crystal Structure ◽

Iron Complex ◽

Molecular And Crystal Structure ◽

Dinitrosyl Iron Complex ◽

Dinitrosyl Iron

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Atomistic simulation of the uniaxial compression of black phosphorene nanotubes

Vietnam Journal of Mechanics ◽

10.15625/0866-7136/10982 ◽

2018 ◽

Cited By ~ 1

Author(s):

Van-Trang Nguyen ◽

Minh-Quy Le

Keyword(s):

Finite Element Method ◽

Molecular Dynamics ◽

Finite Element ◽

Uniaxial Compression ◽

Critical Stress ◽

Atomistic Simulation ◽

Critical Strain ◽

Bond Breaking ◽

Black Phosphorene ◽

Weber Potential

We study through molecular dynamics finite element method with Stillinger-Weber potential the uniaxial compression of (0, 24) armchair and (31, 0) zigzag black phosphorene nanotubes with approximately equal diameters. Young's modulus, critical stress and critical strain are estimated with various tube lengths. It is found that under uniaxial compression the (0, 24) armchair black phosphorene nanotube buckles, whereas the failure of the (31, 0) zigzag one is caused by local bond breaking near the boundary.

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Recycling of Wastewater Containing Iron-Complex Cyanides Using UV Photodecomposition and UV Ozone Oxidation in Combination with an Ion-Exchange Resin Method

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.78.512 ◽

2005 ◽

Vol 78 (3) ◽

pp. 512-518 ◽

Cited By ~ 5

Author(s):

Hiromutsu Wada ◽

Kazuko Yanaga ◽

Yasuhiro Kuroda ◽

Sergio Hanela ◽

Yoshio Hirayama

Keyword(s):

Ion Exchange ◽

Exchange Resin ◽

Ion Exchange Resin ◽

Iron Complex ◽

Ozone Oxidation ◽

Uv Ozone ◽

Resin Method

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Helmet Phthalocyaninato Iron Complex as a Primary Drier for Alkyd Paints

Materials ◽

10.3390/ma14051220 ◽

2021 ◽

Vol 14 (5) ◽

pp. 1220

Author(s):

Jan Honzíček ◽

Eliška Matušková ◽

Štěpán Voneš ◽

Jaromír Vinklárek

Keyword(s):

Catalytic Performance ◽

Mechanical Tests ◽

Iron Complex ◽

Kinetic Measurements ◽

Time Resolved ◽

Strong Activity ◽

Vis Spectroscopy ◽

Order Of Magnitude ◽

Transparent Coatings ◽

Time Resolved Infrared Spectroscopy

This study describes the catalytic performance of an iron(III) complex bearing a phthalocyaninato-like ligand in two solvent-borne and two high-solid alkyd binders. Standardized mechanical tests revealed strong activity, which appeared in particular cases at concentrations about one order of magnitude lower than in the case of cobalt(II) 2-ethylhexanoate, widespread used in paint-producing industry. The effect of the iron(III) compound on autoxidation process, responsible for alkyd curing, was quantified by kinetic measurements by time-resolved infrared spectroscopy and compared with several primary driers. Effect of the drier concentration on coloration of transparent coatings was determined by UV–Vis spectroscopy.

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