Thermal Effects in the Organocatalytic Asymmetric α-Amination of Disubstituted Aldehydes with Azodicarboxylates: A High-Temperature Organocatalysis

2008 ◽  
Vol 2008 (13) ◽  
pp. 2207-2212 ◽  
Author(s):  
Thomas Baumann ◽  
Michael Bächle ◽  
Caroline Hartmann ◽  
Stefan Bräse
1964 ◽  
Vol 8 ◽  
pp. 78-85 ◽  
Author(s):  
P. K. Gantzel ◽  
S. Langer ◽  
N. L. Baldwin ◽  
F. L. Kester

AbstractThermal analyses of samples of thorium dicarbide in equilibrium with graphite show arrests which indicate phase transitions at 1427 ± 21°C arid 1481 ± 28°C. These thermal effects have been observed on heating and cooling both in standard thermal analysis and in differential thermal analysis using graphite as a reference material. The microstructure of thorium dicarbide samples shows the characteristic “herringbone” pattern of a material which has undergone a martensitic-type transition.A high-temperature X-ray investigation has revealed that the observed thermal arrests correspond to erystallographic transformations. The monodinic modification found at room temperature is stable to 1427°C, at which temperature a tetragonal modification with a0 = 4.235 ± 0.002Å and c0 = 5.408 ± 0.002Å is formed. At 1481°C, the tetragonal is transformed to cubic with a0 = 5.809 ± 0.002 Å. The best agreement between observed and calculated intensities has been obtained with C-C units of 1.5-Å assumed bond length in space groups P42/mmc and Pa3 for the tetragonal and cubic modifications, respectively.


2019 ◽  
Vol 489 (3) ◽  
pp. 3456-3471 ◽  
Author(s):  
Antonella Garzilli ◽  
Andrii Magalich ◽  
Tom Theuns ◽  
Carlos S Frenk ◽  
Christoph Weniger ◽  
...  

ABSTRACT The observed Lyman-α flux power spectrum (FPS) is suppressed on scales below ${\sim} ~ 30\, {\rm km\, s}^{-1}$. This cut-off could be due to the high temperature, T0, and pressure, p0, of the absorbing gas or, alternatively, it could reflect the free streaming of dark matter particles in the early universe. We perform a set of very high resolution cosmological hydrodynamic simulations in which we vary T0, p0, and the amplitude of the dark matter free streaming, and compare the FPS of mock spectra to the data. We show that the location of the dark matter free-streaming cut-off scales differently with redshift than the cut-off produced by thermal effects and is more pronounced at higher redshift. We, therefore, focus on a comparison to the observed FPS at z > 5. We demonstrate that the FPS cut-off can be fit assuming cold dark matter, but it can be equally well fit assuming that the dark matter consists of ∼7 keV sterile neutrinos in which case the cut-off is due primarily to the dark matter free streaming.


2009 ◽  
Vol 18 (08) ◽  
pp. 1205-1226 ◽  
Author(s):  
C. C. MOUSTAKIDIS

We provide an equation of state for high density supernova matter by applying a momentum-dependent effective interaction. We focus on the study of the equation of state of high density and high temperature nuclear matter containing leptons (electrons and neutrinos) under the chemical equilibrium condition. The conditions of charge neutrality and equilibrium under the β-decay process lead first to the evaluation of the lepton fractions and afterward to the evaluation of internal energy, pressure, entropy and, in total to the equation of state of hot nuclear matter for various isothermal cases. Thermal effects on the properties and equation of state of nuclear matter are evaluated and analyzed in the framework of the proposed effective interaction model. Since supernova matter is characterized by a constant entropy, we also present the thermodynamic properties for the isentropic case. Special attention is devoted to the study of the contribution of the components of β-stable nuclear matter to the entropy per particle, a quantity of great interest for the study of structure and collapse of supernovas.


1996 ◽  
Vol 74 (11) ◽  
pp. 2009-2015 ◽  
Author(s):  
Chiharu Suzuki ◽  
Satoshi Miyoshi ◽  
Tomio Naitoh ◽  
Richard J. Wassersug

We examined the relationship between time of the year and sensitivity to emetics in the frogs Rana rugosa and Rana nigromaculata. In response to apomorphine hydrochloride at a dosage of 50 μg/g body mass (wet mass), both species vomited from the late autumn through the winter, when they naturally hibernate, but not during the spring or summer months, when they are normally active. Exposure to low temperature (7 °C) for 29 days made R. rugosa sensitive to apomorphine even in the summer. Exposure to high temperature (20.0–23.0 °C) for 7–10 days in the winter resulted in loss of the frogs' sensitivity to apomorphine. Based on these results, we conclude that seasonal fluctuation in sensitivity to apomorphine is caused by changes in temperature. Sensitivity to copper sulfate, administered orally at a dosage of 0.4 mg/g, also changed with the time of year. However, in contrast to emesis induced with apomorphine, there was an increase in the latency to emesis induced with copper sulfate in the winter compared with the summer for both species. Thus, the emetic responsiveness of ranid frogs depends on both seasonal changes in temperature and on the agent used to provoke emesis.


2000 ◽  
Vol 3 (03) ◽  
pp. 239-248 ◽  
Author(s):  
Cedric Clara ◽  
Marc Durandeau ◽  
Gerard Quenault ◽  
Tuyet-Hang Nguyen

Summary Air injection into light-oil reservoirs is now a proven field technique. Because of the unlimited availability and the nil access cost of the injectant, the application potential of this improved recovery process is promising when associated with the lack of available hydrocarbon gas sources for injection. One of the keys of a successful air injection project is the evaluation of the process by carrying out representative laboratory studies. Therefore, an original laboratory strategy was proposed to assess the recovery potential by air injection into light-oil reservoirs, and to help the determination and the quantification of optimal operating conditions. In this paper, the air injection technique applied to light-oil reservoirs is explained. Then, the laboratory strategy proposed for the evaluation of an air injection project is described, and the experimental objectives, devices, and procedures are explained. In order to provide reliable experimental data, high-pressure and high-temperature experiments (up to 40 MPa and 500°C) are performed with consolidated reservoir cores and reservoir oils, at representative conditions of the air injection process in light-oil reservoirs. Finally, a laboratory evaluation regarding a potential application for an air injection pilot in the Handil field (Mahakam delta, Indonesia) is presented and discussed. Introduction Air Injection Process into Light-Oil Reservoirs. When air is injected into a reservoir, the oxygen contained in the air reacts with the hydrocarbons by various oxidation reactions. Heat is evolved from these reactions. High initial reservoir temperatures promote larger heat production. Two study cases must then be differentiated in the light-oil reservoir.When the thermal losses through the rock are limited compared with the heat generated by the reactions, the temperature in the reservoir increases. In this case, complete oxidation reactions providing carbon-oxide gases can be self-ignited in the reservoir. As reported in recent studies, 1 the oxygen is then consumed in a confined zone called an oxidation (or combustion)front. The size of this zone depends on the air injection rate, the characteristics of the oil, and the formation. In light-oil reservoirs, typical oxidation front temperatures of 200 to 400°C (about 400 to 800°F) can be reached. The produced combustion gases consist of CO 2 and CO with CO/CO2˜0.15, depending on the temperatures reached and the oil characteristics.When the thermal losses through the rock are high, or when the heat release is not high enough to increase the temperature significantly (in the case of high-water saturations or low-oil saturations), the oxidation reactions occur at a temperature close to the initial reservoir temperature. In this case, oxidation reactions can be partial with a lower carbon-oxide generation than in the previous case. The oxygen consumption occurs then through a larger reservoir zone, the size of which depends upon the oil reactivity.2 Several field experiences**3,4 have shown that high levels of CO2 may be produced. This would suggest that spontaneous ignition, with generation of a high-temperature front and the production of associated carbon-oxide gases, is most likely occurring in light-oil reservoirs. The generation of a high-temperature oxidation zone (200 to 400°C) is preferable because of a higher oxygen uptake potential, a more efficient carbon-oxide generation, and the creation of an oil bank downstream of the thermal front. Both of the latter factors contribute to the improvement of the recovery. In both cases, the important point to assess is oxygen consumption to prevent oxygen arrival at the producers. This is one of the main objectives of air injection experiments. Reservoir Zones to be Distinguished. When a high-temperature thermal front is ignited, four main zones can be distinguished in the reservoir (Fig. 1):The zone swept by the combustion front, where the residual oil saturation is low and the temperature higher than the initial reservoir temperature.The oxidation front where oxygen is consumed. The temperature can reach400°C Part of the original oil is burnt (about 5 to 10% OOIP) and CO2 and CO are produced. The gas formed by the remaining nitrogen from the air and the combustion gases is called "flue gas" (typically, 85% of N2 13% of CO2 and 2%of CO) and sweeps the reservoir downstream.A short zone downstream of the combustion front where thermal effects participate in the formation of an oil bank. This oil bank is partially displaced by the flue gas and by hot water or a steam front according to the reservoir conditions.A wide zone downstream of the combustion front where no thermal effects occur. This zone, which contains original oil, is not affected by the thermal effects and is swept by the flue gas. When the oxidation reactions occur at low temperature (close to the reservoir temperature), three main zones can be distinguished:A zone around the injector which is swept by the injected air. In this area, residual oil saturation is low. The oil is partially oxidized but can no longer consume oxygen.A large oxidation zone where oxygen is consumed by the residual oil left after flue gas sweeping. The oxygen concentration in the gas phase progressively decreases from 21 to 0%.A wide zone downstream of the oxidation zone, swept by the flue gas at reservoir temperature, as in the previous case (high-temperature front).However, in this case, less carbon oxides have been generated by oxidation reactions and the flue gas is mainly composed of nitrogen. In practice, both cases can co-exist in a given reservoir, according to the local reservoir properties.


2020 ◽  
Vol 22 (1) ◽  
pp. 6-9
Author(s):  
Agnieszka Kijo-Kleczkowska ◽  
Adam Gnatowski ◽  
Magdalena Szumera ◽  
Dariusz Kwiatkowski

AbstractThis paper presents an analysis of DSC/TG/DTG thermal studies for PA6 polyamide, coal fuels and polyamide composites with these materials. The test results are aimed at comparing the thermal effects and behavior of these materials under high temperature conditions and are the basics to know of the creation and use of polymer composites with various coal fillers.


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