Photoinduced Exfoliation of a Polymeric N ‐Benzylideneaniline Liquid‐Crystalline Composite Based on a Photoisomerization‐Triggered Phase Transition

2021 ◽  
pp. 2100097
Author(s):  
Mizuho Kondo ◽  
Daijoro Kojima ◽  
Naoya Ootsuki ◽  
Nobuhiro Kawatsuki
Keyword(s):  
Phase Transition ◽  
Liquid Crystalline

Synthesis and Properties of Biodegradable Liquid Crystalline Poly(ester-Urethane)s Based on Poly(L-Lactic Acid)

2013 ◽  
Vol 652-654 ◽  
pp. 459-462
Author(s):  
Ya Tong Guo ◽  
Zhu Zheng ◽  
Zhen Qi Hou ◽  
Jie Du
Keyword(s):  
Phase Transition ◽  
Thermal Stability ◽  
Lactic Acid ◽  
Physical Properties ◽  
Liquid Crystalline ◽  
Degradation Rate ◽  
Hydrolytic Degradation ◽  
Hexamethylene Diisocyanate ◽  
Solution Polymerization ◽  
Phase Transition Temperatures

A series of biodegradable segmented liquid crystalline poly(ester-urethane)s were prepared by solution polymerization of poly(L-lactic acid) (PLLA), mesogenic diol prepolymer poly(butylene terephthaloyldioxy dibenzoates) (MD), and hexamethylene diisocyanate (HDI). The MD content was varied from 0 to 40 mol% so that the effects of the mesogen content on the thermal and physical properties, and hydrolytic degradation were examined respectively. It was found that introducing mesogens units could increase the thermal stability and the elastic properties, while reduced the phase transition temperatures and the hydrolytic degradation rate.

Characterization of some mesogenic alkyl 1-thioglycosides

2002 ◽  
Vol 80 (8) ◽  
pp. 1162-1165 ◽  
Author(s):  
B Henrissat ◽  
G K Hamer ◽  
M G Taylor ◽  
R H Marchessault
Keyword(s):  
Phase Transition ◽  
Liquid Crystal ◽  
Solid State ◽  
Solid State Nmr ◽  
Liquid Crystalline ◽  
Liquid Crystal Phase ◽  
X Ray Diffraction ◽  
X Ray ◽  
Liquid Crystalline Phases

A series of dodecyl 1-thio-β-D-glycosides has been synthesized and characterized (DSC, NMR, CP MAS, X-ray diffraction) as possible new marking materials with liquid-crystalline properties. These compounds undergo solid to liquid crystal phase transitions at various temperatures, which depend on the nature of the carbohydrate part of the structure. Their liquid-crystalline phases show extreme shear thinning behaviour.Key words: liquid crystal, powder X-ray diffraction, phase transition, thioglycoside, solid-state NMR, marking material

Thermal phase transition behaviours of the blue phase of bent-core nematogen and chiral dopant mixtures under different boundary conditions

Soft Matter ◽  
2014 ◽  
Vol 10 (41) ◽  
pp. 8224-8228 ◽  
Author(s):  
Min-Jun Gim ◽  
Gohyun Han ◽  
Suk-Won Choi ◽  
Dong Ki Yoon
Keyword(s):  
Phase Transition ◽  
Boundary Conditions ◽  
Liquid Crystalline ◽  
Isotropic Phase ◽  
Different Boundary Conditions ◽  
Various Boundary Conditions ◽  
Thermal Phase Transition ◽  
Thermal Phase ◽  
Blue Phase ◽  
Chiral Dopants

We have investigated dramatic changes in the thermal phase transition of a liquid-crystalline (LC) blue phase (BP) consisting of bent-core nematogen and chiral dopants under various boundary conditions during cooling from the isotropic phase.

scholarly journals In situ phase transition of microemulsions for parenteral injection yielding lyotropic liquid crystalline carriers of the antitumor drug bufalin

2019 ◽  
Vol 173 ◽  
pp. 217-225 ◽  
Author(s):  
Yawen Li ◽  
Angelina Angelova ◽  
Jianwen Liu ◽  
Vasil M. Garamus ◽  
Na Li ◽  
...  
Keyword(s):  
Phase Transition ◽  
Liquid Crystalline ◽  
Antitumor Drug ◽  
Parenteral Injection

Hydrogen bonding liquid crystalline benzoic acids with alkylthio groups: phase transition behavior and insights into the cybotactic nematic phase

2017 ◽  
Vol 41 (14) ◽  
pp. 6514-6522 ◽  
Author(s):  
Yuki Arakawa ◽  
Yukito Sasaki ◽  
Kazunobu Igawa ◽  
Hideto Tsuji
Keyword(s):  
Phase Transition ◽  
Hydrogen Bonding ◽  
Nematic Phase ◽  
Liquid Crystalline ◽  
Benzoic Acids ◽  
Phase Transition Behavior ◽  
Transition Behavior

A novel class of hydrogen bonding liquid crystalline benzoic acids with alkylthio groups was established and their phase transition behavior was investigated in detail.

scholarly journals Perylene-like Dyes in Liquid Crystalline Media

1996 ◽  
Vol 51 (7) ◽  
pp. 843-850 ◽  
Author(s):  
Ewa Mykowska ◽  
Danuta Bauman
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Order Parameter ◽  
Liquid Crystalline ◽  
Fluorescent Dyes ◽  
Liquid Crystal Display ◽  
Isotropic Phase ◽  
Display Devices ◽  
Electrooptical Properties ◽  
Derivatives Of

Abstract The spectral and electrooptical properties of some dichroic fluorescent dyes (derivatives of 3.4,9,10-perylenetetracorboxylic acid and of 3,4,9-perylenetricarboxylic acid) in isotropic solvents and nematic liquid crystals have been studied. The order parameter of the dyes in the anisotropic matrices has been determined by means of optical spectroscopy methods. Moreover, the influence of the dye addition on the nematic-isotropic phase transition temperature of the pure host has been investigated. It was found that some of the dyes studied can be utilized in guest-host liquid crystal display devices.

scholarly journals 1H and13C NMR study of phase transition and molecular motion in ionic liquids forming lyotropic liquid-crystalline ionogels

2011 ◽  
Vol 51 (3) ◽  
pp. 212-220 ◽  
Author(s):  
Vytautas Balevičius ◽  
Lukas Džiaugys ◽  
Feliksas Kuliešius ◽  
Arūnas Maršalka
Keyword(s):  
Phase Transition ◽  
Ionic Liquids ◽  
Liquid Crystalline ◽  
Molecular Motion ◽  
1H And13c Nmr ◽  
Nmr Study

scholarly journals Order Parameters, Orientational Distribution Functions and Heliconical Tilt Angles of Oligomeric Liquid Crystals

2019 ◽  
Author(s):  
Richard Mandle ◽  
John W. Goodby
Keyword(s):  
Phase Transition ◽  
Liquid Crystals ◽  
Tilt Angle ◽  
Order Parameter ◽  
Nematic Phase ◽  
Liquid Crystalline ◽  
Thermal Evolution ◽  
Order Parameters ◽  
Distribution Functions ◽  
Orientational Distribution

We compare the order parameters, orientational distribution functions (ODF) and heliconical tilt angles of the TB phase exhibited by a liquid-crystalline dimer (CB7CB) to a tetramer (O47) and hexamer (O67) by SAXS/WAXS. Following the N-TB phase transition we find that all order parameters decrease, and while 〈P2 〉 remains positive 〈P4 〉 becomes negative. For all three materials the order parameter 〈P6 〉 is near zero in both phases. The ODF is sugarloaf-like in the nematic phase and volcano-like in the TB phase, allowing us to estimate the heliconical tilt angle of each material and its thermal evolution. The heliconical tilt angle appears to be largely independent of the material studied despite the differing number of mesogenic units.

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