Preparation and properties of short oil alkyd resin/TiO2 nanocomposites based on surface modified TiO2 nanoparticles

2016 ◽  
Vol 39 (5) ◽  
pp. 1488-1499 ◽  
Author(s):  
Tijana S. Radoman ◽  
Jasna V. Džunuzović ◽  
Pavle M. Spasojević ◽  
Milena T. Marinović-Cincović ◽  
Katarina B. Jeremić ◽  
...  
2015 ◽  
Vol 9 (10) ◽  
pp. 916-931 ◽  
Author(s):  
T. S. Radoman ◽  
J. V. Dzunuzovic ◽  
K. T. Trifkovic ◽  
T. Palija ◽  
A. D. Marinkovic ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2817 ◽  
Author(s):  
Feng Zhan ◽  
Lei Xiong ◽  
Fang Liu ◽  
Chenying Li

In this study, we proposed a novel and facile method to modify the surface of TiO2 nanoparticles and investigated the influence of the surface-modified TiO2 nanoparticles as an additive in a polyurethane (PU) coating. The hyperbranched polymers (HBP) were grafted on the surface of TiO2 nanoparticles via the thiol-yne click chemistry to reduce the aggregation of nanoparticles and increase the interaction between TiO2 and polymer matrices. The grafting of HBP on the TiO2 nanoparticles surface was investigated by means of X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier transform infrared (FT-IR), nuclear magnetic resonance (NMR) and thermogravimetry analysis (TGA). The thermal and mechanical properties of nanocomposite coatings containing various amounts of TiO2 nanoparticles were measured by dynamic mechanical thermal (DMTA) and tensile strength measurement. Moreover, the surface structure and properties of the newly prepared nanocomposite coatings were examined. The experimental results demonstrate that the incorporation of the surface-modified TiO2 nanoparticles can improve the mechanical and thermal properties of nanocomposite coatings. The results also reveal that the surface modification of TiO2 with the HBP chains improves the nanoparticle dispersion, and the coating surface shows a lotus leaf-like microstructure. Thus, the functional nanocomposite coatings exhibit superhydrophobic properties, good photocatalytic depollution performance, and high stripping resistance.


2017 ◽  
Vol 155 ◽  
pp. 323-331 ◽  
Author(s):  
Vladan Bajić ◽  
Biljana Spremo-Potparević ◽  
Lada Živković ◽  
Andrea Čabarkapa ◽  
Jelena Kotur-Stevuljević ◽  
...  

2013 ◽  
Vol 143 (1) ◽  
pp. 233-239 ◽  
Author(s):  
Ivan M. Dugandžić ◽  
Dragana J. Jovanović ◽  
Lidija T. Mančić ◽  
Olivera B. Milošević ◽  
Scott P. Ahrenkiel ◽  
...  

2014 ◽  
Vol 23 (7) ◽  
pp. 513-524 ◽  
Author(s):  
Miao Wu ◽  
Feimin Zhang ◽  
Jiahui Yu ◽  
Hongye Zhou ◽  
Di Zhang ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2702 ◽  
Author(s):  
Evren Boyraz ◽  
Fatma Yalcinkaya ◽  
Jakub Hruza ◽  
Jiri Maryska

Preparing easily scaled up, cost-effective, and recyclable membranes for separation technology is challenging. In the present study, a unique and new type of modified polyvinylidene fluoride (PVDF) nanofibrous membrane was prepared for the separation of oil–water emulsions. Surface modification was done in two steps. In the first step, dehydrofluorination of PVDF membranes was done using an alkaline solution. After the first step, oil removal and permeability of the membranes were dramatically improved. In the second step, TiO2 nanoparticles were grafted onto the surface of the membranes. After adding TiO2 nanoparticles, membranes exhibited outstanding anti-fouling and self-cleaning performance. The as-prepared membranes can be of great use in new green separation technology and have great potential to deal with the separation of oil–water emulsions in the near future.


2019 ◽  
Vol 99 ◽  
pp. 175-181 ◽  
Author(s):  
T. Georgakopoulos ◽  
N. Todorova ◽  
S. Karapati ◽  
K. Pomoni ◽  
C. Trapalis

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