Mercury Intrusion Porosimetry and Image Analysis of Cement-Based Materials

1999 ◽  
Vol 211 (1) ◽  
pp. 39-44 ◽  
Author(s):  
A.B. Abell ◽  
K.L. Willis ◽  
D.A. Lange
Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4164 ◽  
Author(s):  
Hayeon Kim ◽  
Hyeongmin Son ◽  
Joonho Seo ◽  
H. K. Lee

The present study evaluated the self-healing efficiency and mechanical properties of mortar specimens incorporating a bio-carrier as a self-healing agent. The bio-carrier was produced by immobilizing ureolytic bacteria isolated from seawater in bottom ash, followed by surface coating with cement powder to prevent loss of nutrients during the mixing process. Five types of specimens were prepared with two methods of incorporating bacteria, and were water cured for 28 days. To investigate the healing ratio, the specimens with predefined cracks were treated by applying a wet–dry cycle in three different conditions, i.e., seawater, tap water, and air for 28 days. In addition, a compression test and a mercury intrusion porosimetry analysis of the specimens were performed to evaluate their physico-mechanical properties. The obtained results showed that the specimen incorporating the bio-carrier had higher compressive strength than the specimen incorporating vegetative cells. Furthermore, the highest healing ratio was observed in specimens incorporating the bio-carrier. This phenomenon could be ascribed by the enhanced bacterial viability by the bio-carrier.


1991 ◽  
Vol 245 ◽  
Author(s):  
H. Igarashi ◽  
T. Takahashi

ABSTRACTMDF(Macro-Defect-Free ) cement pastes, which consist of portland cement and polyvinyl alcohol/acetate, were prepared by varying the temperature during pressing and drying operations. We then examined the expansion of MDF cement pastes at various constant humidities. There was a large difference in expansion above 60%R.H. between samples prepared varying temperature at which samples were pressed. Samples pressed at 90 °C showed less expansion than samples pressed at 40 °C.The pore structure of MDF cement pastes before exposure to moisture was measured by nitrogen adsorption, mercury intrusion porosimetry and image analysis. The properties of a matrix containing polyvinyl alcohol/acetate and cemnt hydrates were also investigated by TEM, IR and XPS.There were not large differences in the result of IR and XPS measurement between the MDF cement pastes prepared at various temperatures. Calcium hydroxide crystal, lying perpendicular to cement particles, were often observed only in the MDF cement pastes pressed at 90 °C which occurs by water absorption, seems to be suppressed by calcium hydroxide crystal.


2006 ◽  
Vol 302-303 ◽  
pp. 347-355 ◽  
Author(s):  
Chien Hung Chen ◽  
Ming Chin Ho ◽  
Shaing Hai Yeh ◽  
Ran Huang

The objective of this investigation is to evaluate the effect of surface treatments on cement-based materials, which include mortar and concrete samples. Penetrated sealers and methyl methacrylate (MMA) were used as surface treatment materials. Two concrete mixes (w/c = 0.35, 0.55) were selected and cubic/cylindrical specimens were prepared according to ASTM specifications. The treated specimens have higher compressive strengths than the control specimens. Also, the absorptions and total charge passed of rapid chloride penetration test (RCPT) are lower in the treated specimens. Scanning electronic microscope (SEM) was utilized to estimate the microstructure of the specimens. Denser pore structures and narrower pore-size distribution were observed in SEM micrographs and mercury intrusion porosimetry (MIP) spectrum for the treated specimens, which are correspondent to the macro-observation. The positive effect is most prominent in polymer treated specimens. For higher w/c ratio mix, large capillary pores were filled by most of treatment materials and compressive strength significantly increased, while, for lower w/c ratio mix, polymer and silicate sealer filled in medium capillary pores as indicated by MIP and RCPT results.


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