Study of Complex Formation of the Lanthanides by Means of Fluorescence Spectroscopy

Author(s):  
B. A. Bilal
2019 ◽  
Vol 95 ◽  
pp. 526-532 ◽  
Author(s):  
Jaqueline de Paula Rezende ◽  
Eliara Acipreste Hudson ◽  
Hauster Maximiler Campos de Paula ◽  
Yara Luiza Coelho ◽  
Luis Henrique Mendes da Silva ◽  
...  

2004 ◽  
Vol 92 (8) ◽  
Author(s):  
M. Karbowiak ◽  
S. Hubert ◽  
B. Fourest ◽  
Christophe Moulin

SummaryThe uranyl/periodate system was investigated by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS), and Capillary Electrophoresis (CE) in 0.1 and 0.05 mol L


2004 ◽  
Vol 92 (12) ◽  
Author(s):  
Akira Kirishima ◽  
Takaumi Kimura ◽  
Osamu Tochiyama ◽  
Zenko Yoshida

SummaryThe complex formation of U(VI) with phosphate and with fluoride has been studied at elevated temperatures (20–150 °C) and pressures (0.1–40 MPa) using time-resolved laser-induced fluorescence spectroscopy (TRLFS). Emission spectra and lifetimes of 5×10


Molecules ◽  
2020 ◽  
Vol 25 (8) ◽  
pp. 1915
Author(s):  
Zoltán Nagymihály ◽  
Beáta Lemli ◽  
László Kollár ◽  
Sándor Kunsági-Máté

Interaction of 4-quinazolinone with tetrakis (3,5-dicarboxylatophenoxy)-cavitand derivative has been studied in methanol and dimethylformamide media using fluorescence spectroscopy and molecular modeling methods. Results show temperature dependent complex formation: either the entropy gain or the high enthalpy changes are responsible for the formation of stable complexes in two separated temperature regions. However, different thermodynamic parameters are associated to different conformations of the complexes: while the high entropy gain associated to the formation of deeply included guest in methanol, the high entropy gain is associated with the formation of weakly included guest in dimethylformamide solvent. This finding highlights the importance of dynamic properties of the species interacted in different solvents.


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