Natural Emissions to Atmosphere: Biogenic Emissions in the Citrus Plantations of Western Cuba

2022 ◽  
pp. 123-136
Author(s):  
Ricardo Manso ◽  
Yosdany González ◽  
Javier Bolufé ◽  
Rosemary López ◽  
Israel Borrajero ◽  
...  
Keyword(s):  
Biogenic Emissions ◽  
Natural Emissions

Biogenic emissions from Pinus halepensis: a typical species of the Mediterranean area

2005 ◽  
Vol 74 (1-4) ◽  
pp. 37-48 ◽  
Author(s):  
V. Simon ◽  
L. Dumergues ◽  
G. Solignac ◽  
L. Torres
Keyword(s):  
Pinus Halepensis ◽  
Mediterranean Area ◽  
Biogenic Emissions ◽  
Typical Species ◽  
The Mediterranean

scholarly journals Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign

2013 ◽  
Vol 13 (4) ◽  
pp. 2091-2113 ◽  
Author(s):  
J. E. Shilling ◽  
R. A. Zaveri ◽  
J. D. Fast ◽  
L. Kleinman ◽  
M. L. Alexander ◽  
...  
Keyword(s):  
Mass Spectrometer ◽  
Organic Aerosol ◽  
Proton Transfer Reaction ◽  
Chemical Mechanism ◽  
Biogenic Emissions ◽  
Anthropogenic Emissions ◽  
Radiation Balance ◽  
Particle Phase ◽  
Aerosol Formation ◽  
Research Aircraft

Abstract. The CARES campaign was conducted during June, 2010 in the vicinity of Sacramento, California to study aerosol formation and aging in a region where anthropogenic and biogenic emissions regularly mix. Here, we describe measurements from an Aerodyne High Resolution Aerosol Mass Spectrometer (AMS), an Ionicon Proton Transfer Reaction Mass Spectrometer (PTR-MS), and trace gas detectors (CO, NO, NOx) deployed on the G-1 research aircraft to investigate ambient gas- and particle-phase chemical composition. AMS measurements showed that the particle phase is dominated by organic aerosol (OA) (85% on average) with smaller concentrations of sulfate (5%), nitrate (6%) and ammonium (3%) observed. PTR-MS data showed that isoprene dominated the biogenic volatile organic compound concentrations (BVOCs), with monoterpene concentrations generally below the detection limit. Using two different metrics, median OA concentrations and the slope of plots of OA vs. CO concentrations (i.e., ΔOA/ΔCO), we contrast organic aerosol evolution on flight days with different prevailing meteorological conditions to elucidate the role of anthropogenic and biogenic emissions on OA formation. Airmasses influenced predominantly by biogenic emissions had median OA concentrations of 2.2 μg m−3 and near zero ΔOA/ΔCO. Those influenced predominantly by anthropogenic emissions had median OA concentrations of 4.7 μg m−3 and ΔOA/ΔCO ratios of 35–44 μg m−3 ppmv. But, when biogenic and anthropogenic emissions mixed, OA levels were enhanced, with median OA concentrations of 11.4 μg m−3 and ΔOA/ΔCO ratios of 77–157 μg m−3 ppmv. Taken together, our observations show that production of OA was enhanced when anthropogenic emissions from Sacramento mixed with isoprene-rich air from the foothills. After considering several anthropogenic/biogenic interaction mechanisms, we conclude that NOx concentrations play a strong role in enhancing SOA formation from isoprene, though the chemical mechanism for the enhancement remains unclear. If these observations are found to be robust in other seasons and in areas outside of Sacramento, regional and global aerosol modules will need to incorporate more complex representations of NOx-dependent SOA mechanisms and yields into their algorithms. Ultimately, accurately predicting OA mass concentrations and their effect on radiation balance will require a mechanistically-based treatment of the interactions of biogenic and anthropogenic emissions.

scholarly journals Temperature-dependence of aerosol optical depth over the southeastern US

2016 ◽  
Author(s):  
Tero Mielonen ◽  
Anca Hienola ◽  
Thomas Kühn ◽  
Joonas Merikanto ◽  
Antti Lipponen ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Land Surface ◽  
Radiative Forcing ◽  
Climate Model ◽  
Biogenic Emissions ◽  
Anthropogenic Emissions ◽  
Model Estimate ◽  
Model Simulations ◽  
Southeastern Us ◽  
Biogenic Aerosols

Abstract. Previous studies have indicated that summer-time aerosol optical depths (AOD) over the southeastern US are dependent on temperature but the reason for this dependence and its radiative effects have so far been unclear. To quantify these effects we utilized AOD and land surface temperature (LST) products from the Advanced Along-Track Scanning Radiometer (AATSR) with observations of tropospheric nitrogen dioxide (NO2) column densities from the Ozone Monitoring Instrument (OMI). Furthermore, simulations of the global aerosol-climate model ECHAM-HAMMOZ have been used to identify the possible processes affecting aerosol loads and their dependence on temperature over the studied region. Our results showed that the level of AOD in the southeastern US is mainly governed by anthropogenic emissions but the observed temperature dependent behaviour is most likely originating from non-anthropogenic emissions. Model simulations indicated that biogenic emissions of volatile organic compounds (BVOC) can explain the observed temperature dependence of AOD. According to the remote sensing data sets, the non-anthropogenic contribution increases AOD by approximately 0.009 ± 0.018 K−1 while the modelled BVOC emissions increase AOD by 0.022 ± 0.002 K−1. Consequently, the regional direct radiative effect (DRE) of the non-anthropogenic AOD is −0.43 ± 0.88 W/m2/K and −0.17 ± 0.35 W/m2/K for clear- and all-sky conditions, respectively. The model estimate of the regional clear-sky DRE for biogenic aerosols is also in the same range: −0.86 ± 0.06 W/m2/K. These DRE values indicate significantly larger cooling than the values reported for other forested regions. Furthermore, the model simulations showed that biogenic emissions increased the number of biogenic aerosols with radius larger than 100 nm (N100, proxy for cloud condensation nuclei) by 28 % per one degree temperature increase. For the total N100, the corresponding increase was 4 % which implies that biogenic emissions could also have a small effect on indirect radiative forcing in this region.

Biogenic emissions and gaseous precursors to forest aerosols

Tellus B ◽  
2001 ◽  
Vol 53 (4) ◽  
pp. 423-440 ◽  
Author(s):  
R. JANSON ◽  
K. ROSMAN ◽  
A. KARLSSON ◽  
H.-C. HANSSON
Keyword(s):  
Biogenic Emissions

scholarly journals Detection of Outflow of Formaldehyde and Glyoxal from the African continent to the Atlantic Ocean with a MAX-DOAS Instrument

2019 ◽  
Author(s):  
Lisa K. Behrens ◽  
Andreas Hilboll ◽  
Andreas Richter ◽  
Enno Peters ◽  
Leonardo M. A. Alvarado ◽  
...  
Keyword(s):  
Atlantic Ocean ◽  
Cape Verde ◽  
Trace Gas ◽  
Biogenic Emissions ◽  
African Continent ◽  
Satellite Measurements ◽  
Model Simulations ◽  
Spatial Gradients ◽  
Volatile Organic ◽  
Continental Outflow

Abstract. Trace gas maps retrieved from satellite measurements show enhanced levels of the atmospheric volatile organic compounds formaldehyde (HCHO) and glyoxal (CHOCHO) over the Atlantic Ocean. To validate the spatial distribution of this continental outflow, ship-based measurements were taken during the project Continental Outflow of Pollutants towards the MArine tRoposphere (COPMAR). A Multi-AXis Differential Optical Absorption Spectrometer (MAX-DOAS) was operated on board the research vessel (RV) Maria S. Merian during the cruise MSM58/2. This cruise was conducted in October 2016 from Ponta Delgada (Azores) to Cape Town (South Africa), crossing between Cape Verde and the African continent. The instrument was continuously scanning the horizon looking towards the African continent. Enhanced levels of HCHO and CHOCHO were found in the area of expected outflow during this cruise. The observed spatial gradients of HCHO and CHOCHO along the cruise track agree with the spatial distributions from satellite measurements and MOZART-4 model simulations. The continental outflow from the African continent is observed in an elevated layer, higher than 1000 m, and probably originates from biogenic emissions or biomass burning according to FLEXPART emission sensitivities.

scholarly journals Particle formation and growth at five rural and urban sites

2010 ◽  
Vol 10 (5) ◽  
pp. 11615-11657 ◽  
Author(s):  
C.-H. Jeong ◽  
G. J. Evans ◽  
M. L. McGuire ◽  
R. Y.-W. Chang ◽  
J. P. D. Abbatt ◽  
...  
Keyword(s):  
Ultrafine Particle ◽  
Particle Formation ◽  
Nucleation And Growth ◽  
Biogenic Emissions ◽  
Traffic Density ◽  
Particle Nucleation ◽  
Size Distributions ◽  
Industrial Sources ◽  
Rural Sites ◽  
Particle Formation And Growth

Abstract. Ultrafine particle (UFP) number and size distributions were simultaneously measured at five urban and rural sites in Southern Ontario, Canada as part of the Border Air Quality and Meteorology Study (BAQS-Met 2007). Particle formation and growth events at these five sites were classified based on their strength and persistence as well as the variation in geometric mean diameter. Regional nucleation and growth events and local short-lived strong nucleation events were frequently observed at the near-border rural sites, upwind of industrial sources. Surprisingly, the particle number concentrations at one of these sites were higher than the concentrations at a downtown site in a major city, despite its high traffic density. Regional nucleation and growth events were favored at intense solar irradiance and less polluted cooler drier air. The most distinctive regional particle nucleation and growth event during the campaign was observed simultaneously at all five sites, which were up to 350 km apart. Although the ultrafine particle concentrations and size distributions generally were spatially heterogeneous across the region, a more uniform spatial distribution of UFP across the five areas was observed during this regional nucleation event. Thus, nucleation events can cover large regions, contributing to the burden of UFP in cities and potentially to the associated health impacts on urban populations. In addition, particle formation in southwestern Ontario appears to more often be related to anthropogenic gaseous emissions, although biogenic emissions may at times contribute. Local short-lived nucleation events at the near-border sites during this three-week campaign were associated with high SO2, which likely originated from US and Canadian industrial sources. These particle formation events may contribute to the production of cloud condensation nuclei, thus potentially influencing regional climate. Longer-term studies are needed to help resolve the relative contributions of anthropogenic and biogenic emissions to nucleation and growth in this region.

scholarly journals Impacts of future climate change and effects of biogenic emissions on surface ozone and particulate matter concentrations in US

2011 ◽  
Vol 11 (1) ◽  
pp. 2183-2231 ◽  
Author(s):  
Y. F. Lam ◽  
J. S. Fu ◽  
S. Wu ◽  
L. J. Mickley
Keyword(s):  
Climate Change ◽  
United States ◽  
Air Quality ◽  
Global Climate Change ◽  
Global Climate ◽  
Future Climate Change ◽  
Biogenic Emissions ◽  
Emissions Reduction ◽  
Annual Average ◽  
Future Emissions

Abstract. Simulations of present and future average regional ozone and PM2.5 concentrations over the United States were performed to investigate the potential impacts of global climate change and emissions on regional air quality using CMAQ. Various emissions and climate conditions with different biogenic emissions and domain resolutions were implemented to study the sensitivity of future air quality trends from the impacts of changing biogenic emissions. A comparison of GEOS-Chem and CMAQ was performed to investigate the effect of downscaling on the prediction of future air quality trends. For ozone, the impacts of global climate change are relatively smaller when compared to the impacts of anticipated future emissions reduction, except for the Northeast area, where increasing biogenic emissions due to climate change have stronger positive effects (increases) to the regional ozone air quality. The combination effect from both climate change and emission reductions leads to approximately a 10% or 5 ppbv decrease of the maximum daily average eight-hour ozone (MDA8) over the Eastern United States. For PM2.5, the impacts of global climate change have shown insignificant effect, where as the impacts of anticipated future emissions reduction account for the majority of overall PM2.5 reductions. The annual average 24-h PM2.5 of the future-year condition was found to be about 40% lower than the one from the present-year condition, of which 60% of its overall reductions are contributed to by the decrease of SO4 and NO3 particulate matters. Changing the biogenic emissions model increases the MDA8 ozone by about 5–10% or 3–5 ppbv in the Northeast area. Conversely, it reduces the annual average PM2.5 by 5% or 1.0 μg/m3 in the Southeast region.

scholarly journals On the relationship between acetone and carbon monoxide in air masses of different origin

2003 ◽  
Vol 3 (1) ◽  
pp. 1017-1049
Author(s):  
M. de Reus ◽  
H. Fischer ◽  
F. Arnold ◽  
J. de Gouw ◽  
R. Holzinger ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Monoxide ◽  
Field Experiments ◽  
Marine Boundary Layer ◽  
Biogenic Emissions ◽  
Model Calculations ◽  
Single Observation ◽  
Tropical Regions ◽  
Air Masses ◽  
Clean Air

Abstract. Carbon monoxide and acetone measurements are presented for five aircraft measurement campaigns at mid-latitudes, polar and tropical regions in the northern hemisphere. Throughout all campaigns, free tropospheric air masses, which were influenced by anthropogenic emissions, showed a similar linear relation between CO and acetone, with a slope of 21–25 pptv acetone/ppbv CO. Measurements in the anthropogenically influenced marine boundary layer revealed a slope of 13–16 pptv acetone/ppbv CO. The different slopes observed in the marine boundary layer and the free troposphere indicate that acetone is emitted by the ocean in relatively clean air masses and taken up by the ocean in polluted air masses. In the lowermost stratosphere, a good correlation between CO and acetone was observed as well, however, with a much smaller slope (~5 pptv acetone/ppbv CO) compared to the troposphere. This is caused by the longer photochemical lifetime of CO compared to acetone in the lower stratosphere, due to the increasing photolytic loss of acetone and the decreasing OH concentration with altitude. No significant correlation between CO and acetone was observed over the tropical rain forest due to the large direct and indirect biogenic emissions of acetone. The common slopes of the linear acetone-CO relation in various layers of the atmosphere, during five field experiments, makes them useful for model calculations. Often a single observation of the CO-acetone correlation, determined from stratospheric measurements, has been used in box model applications. This study shows that different slopes have to be considered for marine boundary layer, free tropospheric and stratospheric air masses, and that the CO-acetone relation cannot be used for air masses which are strongly influenced by biogenic emissions.

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