Cyclochrome—The Recycle of Sodium Dichromate in Sodium Chlorate Manufacture

1992 ◽  
pp. 43-57
Author(s):  
R. E. Alford
1932 ◽  
Vol 7 (5) ◽  
pp. 499-519 ◽  
Author(s):  
Geo. L. Godel

The writer reviews the subject of weed control by chemicals in the growing crop mainly with reference to prairie conditions, and discusses it under the following heads: the herbicide, the sprayer, weather conditions, the crop, the experimental technique. A technique is described which permits the analysis of a large group of variable factors in the weed-control experiments carried on in Saskatchewan.An extensive program of weed research was undertaken in Saskatchewan in 1929, to determine the practicability of both methods of control by chemicals (control of perennial weeds in small patches, and control of annual weeds in the crop) under semi-arid conditions and with extensive farming methods. The experiments were conducted under the most variable conditions of soil and climate, and many chemical solutions were tested at varying concentrations and amounts of spray per acre. Treatments were made on stinkweed and wild mustard in wheat, oats, barley, rye, corn, sweet clover, western rye grass, alfalfa and brome grass. During the last three years the effects of the following chemicals have been studied: sodium chlorate, sodium dichromate, copper nitrate, copper sulphate, sulphuric acid, iron sulphate, sodium chloride and ammonium bisulphate. All of these, except the last, reduced the weed infestation of the treated crops; the chemicals are listed in order of effectiveness. The results showed, however, that many factors other than proper strength of solution and amount of spray per acre should be taken into account.The largest percentage of control of wild mustard in the crop of 1931 was obtained with weak solutions of sodium chlorate. The effects of this chemical on the crop are more severe than those of the others, and therefore its use should be further investigated before it can be recommended.The application of dry chemicals for control of weeds in the crop combine in general two farming operations—fertilizing of the soil and weed control. These methods offer little promise for Saskatchewan as they require cool, foggy, wet weather which is rarely found in the west; and because it has been found that, in order to be effective here, commercial fertilizers have to be drilled in with the seed and not broadcasted on the surface.It appears that, under Saskatchewan conditions, only a few weed species can be controlled successfully. In wheat, sulphuric acid will control common wild mustard, Indian mustard, wild radish, stinkweed, false flax, tumbling mustard and wild buckwheat. New shoots of Canada thistle are somewhat retarded in their development. Hare's ear mustard, ball mustard, cow cockle, lamb's-quarters, Russian pigweed, and the grasses, wild oats, darnel, etc., could not be controlled under the conditions of these experiments. It is thus important that chemical treatments be limited to fields where weed infestation consists mostly of susceptible weeds, because in controlling these the crop and resistant weeds are stimulated. At Watson, Sask., in 1931, when wild mustard or stinkweed was associated with either wild oats, lamb's-quarters or Russian pigweed, there was always an increase in the development of the latter weeds after treatment.In these experiments the cereals ranked as follows in resistance to sulphuric acid sprays:–resistant; wheat, oats: intermediate; barley, spring rye: susceptible; corn.


1935 ◽  
Vol 13c (2) ◽  
pp. 101-114 ◽  
Author(s):  
J. D. Newton ◽  
A. D. Paul

Further experiments at Edmonton to determine the effects on soils and on subsequent crop growth of copper sulphate, sodium chlorate, and sodium dichromate, are reported, together with new experiments with ammonium thiocyanate. The field plot experiments were limited to Edmonton black soil, but three typical Alberta soils, including Edmonton soil, were used in the laboratory experiments. Copper sulphate applied to a series of fallow plots in 1931 did not affect the yields of wheat on these plots significantly in 1932, or the yields of wheat, oats, rye and flax on these plots in 1933. The soil was not appreciably injured, even temporarily, by the copper sulphate. Sodium chlorate was applied to one series of fallow plots in 1930, and to another series in 1931. The effect of the heaviest applications (1300 lb. per acre) lasted for three years in one series, but serious injury to crops from such heavy applications did not last for more than two years in either series. Sodium dichromate was applied to a series of fallow plots and a series of wheat plots in 1932. It reduced the wheat yields very much in 1932, but did not reduce crop yields the following year in either series, as it decomposed and lost its toxicity in the soil rather quickly. Ammonium thiocyanate was applied to a series of fallow plots and a series of wheat plots in 1932, and it reduced the wheat yields even more than sodium dichromate in 1932. It retarded nitrification and did not decompose and lose its toxicity completely during the season of application, but even in the cases of the heavier applications (650 and 1300 lb. per acre) the toxic effect disappeared early in the following season. The total and straw yields of crops sown on these plots were generally increased by the lighter applications (160 and 325 lb. per acre) in 1933, but the grain yields were generally reduced by the heavier applications (650 and 1300 lb. per acre). Growth of certain annual weeds was considerably stimulated by this nitrogenous weed killer in 1933 and 1934, in the plots to which the heavier applications had been made. Laboratory experiments showed that the thiocyanate may be leached out of a soil with water; that it decomposes fairly rapidly in soils under favorable conditions of moisture and temperature and more rapidly in fertile soil rich in organic matter than in poorer soil; and that nitrification in soils is depressed for a time by the ammonium thiocyanate.


1933 ◽  
Vol 8 (6) ◽  
pp. 509-544 ◽  
Author(s):  
W. H. Cook

The combustibility of organic matter-sodium chlorate mixtures in various proportions has been tested at different relative humidities. It was found that mixtures containing more than 10% of sodium chlorate are sufficiently combustible to be hazardous at all relative humidities below 75% but are non-hazardous at higher humidities. Data were obtained showing the minimum moisture content required for protecting such mixtures and this information may be used to calculate the approximate amount of any water-absorbing chemical that has to be added to sodium chlorate to render it safe. Admixture of calcium chloride or magnesium chloride with the sodium chlorate renders the mixture safe when these protecting salts form one-half and one-third respectively of the resulting herbicide. Judging from the chlorate content the above sodium chlorate-magnesium chloride mixture would be the most effective "safe" herbicide of those tested, but it would be about only half as toxic as pure sodium chlorate. Several other salts were tested as protecting agents but they were either ineffective or resulted in the decomposition of the chlorate. Combustibility tests were also conducted on barium chlorate- and calcium chlorate-organic matter mixtures. These mixtures are less inflammable than those containing sodium chlorate but are sufficiently combustible to be a fire hazard in districts where the atmospheric humidity is low. Addition of one part of anhydrous calcium chloride or magnesium chloride to two parts of barium chlorate results in a safe mixture. Sodium dichromate-organic matter mixtures are much less combustible than those containing chlorate, but these mixtures also are somewhat dangerous at ordinary humidities when there is a high proportion of sodium dichromate in the mixture. When 10% of anhydrous calcium or magnesium chloride is added to the sodium dichromate the resultant mixture is safe under ordinary atmospheric humidities, regardless of the proportion of organic matter present. Mixtures of sodium chlorate and sodium dichromate with organic material are extremely combustible.


1933 ◽  
Vol 8 (1) ◽  
pp. 73-100 ◽  
Author(s):  
W. E. Bowser ◽  
J. D. Newton

Experiments were conducted to determine the residual effect of sulphuric acid, copper sulphate, sodium chlorate, barium chlorate and sodium dichromate on three typical Alberta soils. No problem of residual effect was found with the two leaf sprays, sulphuric acid and copper sulphate. Sodium chlorate will remain toxic over a period of about two years, depending mainly on the organic matter content of the soil and the amount of leaching that takes place. The distance that the chlorate will leach down into the subsoil will depend on the amount of rainfall and the character of the soil. As soon as the chlorate is leached out or is reduced the soil returns to its normal productive power. Sodium dichromate decomposes very rapidly in the soil. It has a depressing effect on nitrification and on the activity of the soil micro-organisms. However, there is practically no residual effect from the use of sodium dichromate on soils of medium to high organic matter content.


2014 ◽  
Vol 9 (12) ◽  
pp. 581-585 ◽  
Author(s):  
Zhou Junbo ◽  
Hao Shan ◽  
Huang Wenjia ◽  
Mu Xiusong ◽  
Yang Jianfeng ◽  
...  

Author(s):  
R. E. Herfert ◽  
N. T. McDevitt

Durability of adhesive bonded joints in moisture and salt spray environments is essential to USAF aircraft. Structural bonding technology for aerospace applications has depended for many years on the preparation of aluminum surfaces by a sulfuric acid/sodium dichromate (FPL etch) treatment. Recently, specific thin film anodizing techniques, phosphoric acid, and chromic acid anodizing have been developed which not only provide good initial bond strengths but vastly improved environmental durability. These thin anodic films are in contrast to the commonly used thick anodic films such as the sulfuric acid or "hard" sulfuric acid anodic films which are highly corrosion resistant in themselves, but which do not provide good initial bond strengths, particularly in low temperature peel.The objective of this study was to determine the characteristics of anodic films on aluminum alloys that make them corrosion resistant. The chemical composition, physical morphology and structure, and mechanical properties of the thin oxide films were to be defined and correlated with the environmental stability of these surfaces in humidity and salt spray. It is anticipated that anodic film characteristics and corrosion resistance will vary with the anodizing processing conditions.


2002 ◽  
Vol 14 (1) ◽  
Author(s):  
Robin C. Anderson ◽  
Todd R. Callaway ◽  
Timothy J. Anderson ◽  
Leon F. Kubena ◽  
Nancy K. Keith ◽  
...  

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