Peptide Cross-β Nanoarchitectures: Characterizing Self-Assembly Mechanisms, Structure, and Physicochemical Properties

2021 ◽  
pp. 179-207
Author(s):  
Christopher W. Jones ◽  
Hannah E. Distaffen ◽  
Bradley L. Nilsson
ChemPlusChem ◽  
2017 ◽  
Vol 82 (5) ◽  
pp. 721-731 ◽  
Author(s):  
Delfina Quiñone ◽  
Nicolás Veiga ◽  
Julia Torres ◽  
Carla Bazzicalupi ◽  
Antonio Bianchi ◽  
...  

2019 ◽  
Vol 293 ◽  
pp. 35-49 ◽  
Author(s):  
Wiktor Matysiak ◽  
Tomasz Tański ◽  
Weronika Smok

Today, one of the most popular nanomaterials are thin nanofibrous layers, which are used in many fields of industry, eg electronics, optics, filtration and the textile industry. They can be produced by various methods, such as drawing, template synthesis, molecular self-assembly or phase separation method, but the most common method is electrospinning from a solution or melts. Electrospinning is gaining more and more interest due to its versatility, simplicity and economy as well as the possibility of producing fibers from various types of polymeric, ceramic and metalic materials. Nanofibrous layers produced by this method are characterized by high quality and the desired physicochemical properties.


2014 ◽  
Vol 4 (2) ◽  
pp. 144-154 ◽  
Author(s):  
Maria L.C. Gonzaga ◽  
Thiago M.F. Menezes ◽  
Luciana M. Rebêlo ◽  
José R.R. de Souza ◽  
Nágila M.P.S. Ricardo ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 312 ◽  
Author(s):  
Zhiwen Xi ◽  
Zhe Hong ◽  
Fangtao Huang ◽  
Zhirong Zhu ◽  
Wenzhi Jia ◽  
...  

A series of Pt/WOx-ZrO2-TiO2 catalysts with different Ti/Zr molar ratios was prepared by an evaporation induced self-assembly method, and used to efficient hydrogenolysis of glycerol to 1-PO and 1,3-PDO. BET, XRD, Raman, TEM, XPS and Py-IR were employed to characterize the physicochemical properties of the catalysts. The structural and acidic properties of the catalysts were affected by the Ti/Zr ratio of the support ZrO2-TiO2. Two new crystalline phases of ZrTiO4 and Ti2ZrO6 and the amount of acid sites were detected in the Pt/WOx-ZrO2-TiO2 catalysts. 1-PO is dominant in all products of glycerol hydrogenolysis over the supported Pt-WOx catalysts, which is attributed to more Lewis acid sites on the catalyst surface. The Pt/WOx-ZrO2-TiO2 catalyst with a Ti/Zr ratio of 7/3 showed the highest 1,3-PDO yield (25.3%) and 1-PO yield (42.3%), due to its more acid sites including Brønsted and Lewis, and higher concentration of surface Pt0.


2016 ◽  
Vol 20 (08n11) ◽  
pp. 966-986 ◽  
Author(s):  
Giovanni Bottari ◽  
Andrés de la Escosura ◽  
David González-Rodríguez ◽  
Gema de la Torre

This review, dedicated to Professor Tomás Torres on the occasion of his 65th birthday, offers an overview of the main achievements in his research career. Having a strong background in organic chemistry, he and his group have constantly devoted much effort to the development of synthetic methods towards novel systems based on phthalocyanines and other porphyrinoid analogues. Not less important, the founding of solid collaborations with other prominent scientists has led to study the physicochemical properties of these [Formula: see text]-conjugated dyes, and to evaluate their potential application in multidisciplinary areas such as self-assembly, nanochemistry, optoelectronics and biomedicine.


2015 ◽  
Vol 44 (12) ◽  
pp. 5672-5687 ◽  
Author(s):  
Navnita Kumar ◽  
Sadhika Khullar ◽  
Sanjay K. Mandal

In this paper we report six chiral ligands based on l-tyrosine, l-serine and l-phenylalanine and their homochiral CuII complexes to study the effect of various substitutions in the ligands on the formation of diverse coordination architectures.


2011 ◽  
Vol 64 (2) ◽  
pp. 180 ◽  
Author(s):  
Jiayi Wang ◽  
Tamar L. Greaves ◽  
Danielle F. Kennedy ◽  
Asoka Weerawardena ◽  
Gonghua Song ◽  
...  

The thermal phase transitions and physicochemical properties of a series of 21 amino acid-derived protic ionic liquids and four protic molten salts have been investigated. Structure–property comparisons for this series were investigated for alkyl- and cyclic amino acid cations, and ethoxy and methoxy groups on the cation, combined with nitrate or various carboxylate-containing anions. All the protic fused salts were found to be ‘fragile’. Most of the protic fused salts exhibited a glass transition, with the transition temperatures ranging from –90° to –42°C. Viscosities and conductivities ranged from 0.03 to 15.46 Pa s and 0.02 to 2.20 mS cm–1 at 25°C respectively. The protic ionic liquids alanine methyl ester glycolate, proline methyl ester nitrate, and proline methyl ester glycolate were found to be capable of supporting amphiphile self-assembly. Lamellar or hexagonal liquid crystalline phases were observed with the cationic surfactant hexadecyltrimethylammonium bromide and the non-ionic surfactant Myverol 18–99K.


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