Effect of Environmental and Operational Parameters on Sequential Batch Reactor Systems in Dye Degradation

2021 ◽  
pp. 193-225
Author(s):  
Ahmad Hussaini Jagaba ◽  
Shamsul Rahman Mohamed Kutty ◽  
Mohamed Hasnain Isa ◽  
Augustine Chioma Affam ◽  
Nasiru Aminu ◽  
...  
1996 ◽  
Vol 34 (3-4) ◽  
pp. 413-420
Author(s):  
Y. C. Liao ◽  
D. J. Lee

Transient model of oxygen transfer rate in a sequencing batch reactor is derived and solved numerically. The dissolved oxygen response under several conditions is analyzed. Effects of operational parameters and liquid bath height are studied. When with short, intermittent aeration periods, the transient effects on oxygen transfer rate may be substantial and should be taken into considerations. An example considering bioreaction is also given.


Author(s):  
Natalija Koprivanac ◽  
Dinko Vujevic

Organic synthetic dyes are widely produced and used today. Significant losses of organic and inorganic content occurs during the manufacturing and application of dyes and its discharge in the effluent presents a threat to the eco-systems due to general toxicity and resistance to destruction by biological treatment methods. Particularly azo dyes are of special environmental concern due to their degradation products such as aromatic amines, which are considered highly carcinogenic. So, dyes have to be removed from coloured wastewater before discharge. However, traditional treatment methods (adsorption, coagulation/flocculation) mainly transfer the contaminants from wastewater to secondary waste. Therefore, advanced oxidation processes seem to be sustainable and clean technology to decolorize and minimize organic dyes content from wastewater. In this paper, degradation of an azo dye C.I. Direct Orange 39 (DO39) using Fenton type processes (Fe2+/H2O2, Fe3+/H2O2and Fe0/H2O2) has been performed. The molar ratio of Fenton’s type reagents has been varied in the range of 1 : 5 up to 1 : 50 at 0.5 and 1.0 mM concentrations of iron salts and iron powder. Experiments have been conducted for two hours in a batch reactor with magnetic stirring, ambient conditions and pH 3. The process efficiency and formation of degradation by-products have been determined on the basis of results obtained by UV/VIS spectrophotometric, total organic carbon (TOC) and high performance liquid chromatography (HPLC) analyses. The optimal Fenton and Fenton ``like" processes parameters have been applied in the photo reactor, too. It has been observed that simultaneous utilization of UV irradiation with Fenton's and Fenton ``like" reagents increases the degradation of DO39 dye. Degradation of the dye in dilute aqueous solution follows pseudo-first order kinetics. The maximal decolourization of 20 mg L-1 DO39 in water of 93.2% and TOC degradation of 76.9% were obtained using Fe3+/H2O2= 1 : 5 molar ratio. The results indicate that the treatment of DO39 dye wastewater with UV/Fe3 +/H2O2 system was found to be the most efficient.


2019 ◽  
Vol 233 (10) ◽  
pp. 1447-1468 ◽  
Author(s):  
Kajal Gautam ◽  
Sushil Kumar ◽  
Suantak Kamsonlian

Abstract Reactive dyes are essential materials for the modern lifestyle due to rapid industrialization and urbanization, but they cause adverse effects on the environment. This research work aimed to decolourize the synthetic aqueous solution containing Reactive Black B (RBB) dye using electrocoagulation (EC) process with iron electrodes in batch reactor. The effect of operational parameters such as initial pH (3–9), the distance between electrodes (0.5–2 cm), current density (1.1–8.4 mA/cm2) and initial dye concentration (100–400 mg/L), was investigated in the presence of sodium chloride to maintain the conductivity of electrolytes. Under optimal value of process parameters, high decolourization (99.6%) was obtained at 25 min. The experimental data showed that pseudo-second order kinetics with a correlation coefficient (R2 = 0.97) and Sips isotherm with a correlation coefficient (R2 = 0.98) were found to be well fitted for kinetic and adsorption equilibrium models, respectively. The economic efficiency was also calculated on the basis of electrical energy consumption (EEC), specific electrical energy consumption (SEEC), and current efficiency, respectively. Moreover, characterization of EC generated sludge was also carried out by proximate analysis, IR spectra and XRD analysis. The results revealed that EC process using Fe electrode is quite efficient and clean process for decolourization of reactive dye from aqueous solution.


2018 ◽  
Vol 85 (3) ◽  
pp. 379-383 ◽  
Author(s):  
Peter Leonard ◽  
Emma Tarpey ◽  
William Finnegan ◽  
Xinmin Zhan

This Research Communication describes an investigation into the viability of an Intermittently Aerated Sequencing Batch Reactor (IASBR) for the treatment of dairy processing wastewater at laboratory-scale. A number of operational parameters have been varied and the effect has been monitored in order to determine optimal conditions for maximising removal efficiencies. These operational parameters include Hydraulic Retention Time (HRT), Solids Retention Time (SRT), aeration rate and cycle length. Real dairy processing wastewater and synthetic wastewater have been treated using three laboratory-scale IASBR units in a temperature controlled room. When the operational conditions were established, the units were seeded using sludge from a municipal wastewater treatment plant for the first experiment, and sludge from a dairy processing factory for the second and third experiment. In experiment three, the reactors were fed on real wastewater from the wastewater treatment plant at this dairy processing factory. These laboratory-scale systems will be used to demonstrate over time that the IASBR system is a consistent, viable option for treatment of dairy processing wastewater in this sector. In this study, the capacity of a biological system to remove both nitrogen and phosphorus within one reactor will be demonstrated. The initial operational parameters for a pilot-scale IASBR system will be derived from the results of the study.


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