Determination of single photon ionization cross sections for quantitative analysis of complex organic mixtures

2007 ◽  
Vol 389 (6) ◽  
pp. 1941-1951 ◽  
Author(s):  
Thomas Adam ◽  
Ralf Zimmermann
2013 ◽  
Vol 111 (4) ◽  
Author(s):  
R. C. Bilodeau ◽  
N. D. Gibson ◽  
C. W. Walter ◽  
D. A. Esteves-Macaluso ◽  
S. Schippers ◽  
...  

1971 ◽  
Vol 13 ◽  
pp. 83-87 ◽  
Author(s):  
Howard F. Savage ◽  
Charles A. Boitnott

A crossed beam apparatus has been used to measure the emission and ionization cross sections for the prominent spectral features of Na, Ca, Mg, and Fe in collisions with N2 and O2 over the velocity range of 30 to 120 km/s. From the emission and ionization cross sections, the absolute luminous efficiencies in air were determined over the range of meteor velocities. The maximum luminous efficiencies for the brightest features were: greater than 1 percent for the Na D-lines, 0.2 percent for the CaI(2) singlet, 0.06 percent for the MgI(2) and MgI(3) triplets, and O.4 percent for Fe over the visible spectral range. These luminous efficiencies are valid for free molecular flow conditions for velocities above about 30 km/s and are directly applicable to spectroscopic observations of faint meteors. The luminous efficiency of a typical stone will be presented and compared with the efficiencies determined by other investigators. In contrast to previous work, the luminous efficiency found for stone in the present investigation decreases with velocity above about 50 km/s.


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