High Surface Area CuMn2O4 Prepared by Silica-Aquagel Confined co-precipitation. Characterization and Testing in Steam Reforming of Methanol (SRM)

2007 ◽  
Vol 118 (1-2) ◽  
pp. 8-14 ◽  
Author(s):  
Gregorio Marbán ◽  
Teresa Valdés-Solís ◽  
Antonio B. Fuertes
2016 ◽  
Vol 40 (3) ◽  
pp. 2655-2660 ◽  
Author(s):  
Emma Oakton ◽  
Jérémy Tillier ◽  
Georges Siddiqi ◽  
Zlatko Mickovic ◽  
Olha Sereda ◽  
...  

High surface area Nb and Sb-doped tin oxides are prepared by co-precipitation. The differences in conductivity are rationalised using HT-XRD, SSNMR and Nb K-edge XANES characterisation.


RSC Advances ◽  
2012 ◽  
Vol 2 (21) ◽  
pp. 8145 ◽  
Author(s):  
Mohamed A. Ebiad ◽  
Dalia R. Abd El-Hafiz ◽  
Radwa A. Elsalamony ◽  
Lamia. S. Mohamed

2015 ◽  
Vol 1096 ◽  
pp. 161-168 ◽  
Author(s):  
Richard Yeboah Abrokwah ◽  
Vishwanath G. Deshmane ◽  
Sri Lanka Owen ◽  
Debasish Kuila

We have synthesized mesoporous SiO2(MCM-41) and TiO2encapsulated bimetallic Cu-Ni nanocatalysts using an optimized one-pot hydrothermal procedure. The catalysts were characterized using BET, XRD, TGA-DSC and HRTEM techniques. While bimetallic Cu-Ni/MCM-41catalysts have high surface area- 634-1000 m2/g, Cu-Ni/TiO2yields surface area of 250-350 m2/g depending on the metal loading (5-10 wt%). The XRD studies confirmed a long range ordered structure in Cu-Ni/MCM-41 and the presence of the catalytically active anatase phase in the crystalline Cu-Ni/TiO2. The results from HRTEM studies were consistent with the mesoporosity of both supports. These catalysts were tested for methanol conversion and H2/CO selectivity via steam reforming of methanol (SRM) reactions in a fixed bed reactor. There is a distinct difference in the performance of these two supports. Bimetallic 3.33%Cu6.67%Ni/TiO2catalyst showed an impressive 99% H2selectivity at as low as 150°C and a maximum conversion of 92% at 250 °C but 3.33%Cu6.67%Ni/MCM-41 catalyst did not show any H2selectivity at 150°C and only ~12% conversion at 250°C. The effect of each support and relative metal loadings on the activity and selectivity of the SRM reaction products at different temperatures is discussed.


2018 ◽  
Vol 3 (3) ◽  
pp. 244-250 ◽  
Author(s):  
Dereck N. F. Muche ◽  
Flavio L. Souza ◽  
Ricardo H. R. Castro

A non-system specific method for the synthesis of metal oxide nanoparticles with high homogeneity, spherical morphology and high surface areas is proposed based on an aqueous precipitation.


RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12607-12613
Author(s):  
Rong-Jun Huang ◽  
Subramanian Sakthinathan ◽  
Te-Wei Chiu ◽  
Chaofang Dong

Hydrothermal synthesis of CuCrO2 nanopowder for H2 production by methanol steam reforming.


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