Incorporation of waste materials into portland cement clinker synthesized from natural raw materials

2009 ◽  
Vol 44 (10) ◽  
pp. 2617-2627 ◽  
Author(s):  
Irvin A. Chen ◽  
Maria C. G. Juenger
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Cement Clinker ◽  
Waste Materials ◽  
Portland Cement Clinker

scholarly journals Moroccan oil shale and coal waste as alternative raw materials in Portland cement clinker manufacture. Clinkerisation reactions and clinker characterisation

2018 ◽  
Vol 68 (331) ◽  
pp. 166
Author(s):  
S. Chhaiba ◽  
M. T. Blanco-Varela ◽  
A. Diouri
Keyword(s):  
Particle Size ◽  
Oil Shale ◽  
Raw Materials ◽  
Cement Industry ◽  
Cement Clinker ◽  
Waste Materials ◽  
Coal Waste ◽  
Energy Costs ◽  
Portland Cement Clinker ◽  
Cement Manufacture

For some time the cement industry has been seeking procedures to effectively lower the higher energy costs involved in cement manufacture. Timahdit oil shale and Jerada coal waste could potentially be used as alternative raw materials to produce clinker. This study explored the possibility of applying those materials to a greener use, based on the reactivity and burnability of raw mixes containing Moroccan oil shale and coal waste. The findings showed that, irrespective of particle size, oil shale mixes delivered higher reactivity than coal waste materials, although reactivity was highest in the oil shale clinker with a particle size < 45 μm. The clinkers bearing oil shale with a particle size < 90 μm or a blend of oil shale and coal waste with a size < 45 μm contained higher proportions of alite ( > 70 %).

scholarly journals METHODS OF REPEATED USE OF CEMENT DUST

2019 ◽  
Author(s):  
М.Ш. Саламанова ◽  
С.А. Алиев ◽  
Р.С.-А. Муртазаева
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Cement Industry ◽  
Cement Clinker ◽  
Liquid Sodium ◽  
Portland Cement Clinker ◽  
Repeated Use ◽  
Electrostatic Precipitators ◽  
Rotary Kilns ◽  
Technogenic Raw Materials

В процессе обжига портландцементного клинкера в электрофильтрах вращающихся печей скапливается большое количество пыли, как клинкерной, так и аспирационной, поэтому рациональное использование этих продуктов, содержащих определенную долю полноценного сырьевого ресурса, является актуальной задачей индустрии цемента. В данной работе представлены результаты исследований цементной пыли, проведен энергодисперсионный и сравнительный анализ исследуемых порошков, а также приводится возможный способ утилизации цементной пыли для получения бесклинкерных цементов щелочной активации и бетонов на их основе. Разработанные рецептуры бесклинкерных вяжущих с применением отходов цементной промышленности и натриевого жидкостекольного затворителя позволят получать менее затратные, прочные и долговечные композиты, которые позволят частично заменять традиционный бетон на дорогом портландцементе. Работа выполнена в рамках исследований по реализации научного проекта 1848200001 Высококачественные бетоны с повышенными эксплуатационными свойствами на основе местного природного и техногенного сырья , получившего поддержку Российского фонда фундаментальных исследований (РФФИ). In the process of firing Portland cement clinker in electrostatic precipitators, in rotary kilns, a large amount of harmful substances, both clinker and aspiration, accumulates, therefore rational use of these products leads to certain shares of a fullfledged river resource, which are derived from industrial cement. It should be noted that the reuse of dust electrostatic precipitators is impossible. The basis for obtaining durable and more resourceefficient composites is based on modern technological methods that contribute to the improvement of technical and physicomechanical properties, with the integrated application of technogenic raw materials and liquid sodium binder. The developed clinkerfree binder formulations using the cement industry wastes and sodiumbased sludge glass will make it possible to produce less expensive, durable, and durable composites that will partially replace traditional concrete with expensive portland cement.

Effect of Phosphogypsum on the Clinkerization Temperature of Portland Cement Clincker

2012 ◽  
Vol 730-732 ◽  
pp. 94-99 ◽  
Author(s):  
Maria Margarida Rolim Augusto Lima ◽  
L.F.C. Braz ◽  
Regina da Conceição Corredeira Monteiro ◽  
J.P. Veiga
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Raw Materials ◽  
Cement Clinker ◽  
X Ray Diffraction ◽  
X Ray ◽  
Portland Cement Clinker ◽  
Alternative Material ◽  
Heating Up ◽  
Mineralogical Compositions

Phosphogypsum (PG) is a pollutant residue resulting from the production of phosphoric acid in the phosphated fertilizers industry. About 180 millions of tons of PG are generated worldwide per year, which originates storage problems because of the environmental restrictions and the high costs of storage spaces. Taking into account the mineralizer properties of PG it has been studied a way to valorize this residue as an alternative material in the production of Portland cement clinker. The PG and the raw-materials (limestone, marl, sand and iron oxide) were chemical, mineralogical and thermally characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and differential thermal analysis and termogravimetric analysis (DTA/TGA). After milling, the phosphogypsum was mixed with the raw-materials in different amounts up to 10% weight. The raw mixtures were submitted to two types of firing schedules, heating up to 1500°C without any holding time or heating up to 1350°C and holding for 20 minutes. After firing, the clinkers were analyzed by optical microscopy, milled and characterized in terms of chemical and mineralogical compositions. The clinkers were used to produce cement mortar according to NP EN 196-1 standard. The resultant test specimens were mechanically tested at 2 and 28 days according to the same standard. The obtained results show a reduction of about 140°C in the clinkerization temperature, when a raw mixture with 5% phosphogypsum was used. Standard clinkers, without phosphogypsum addition, which were fired at 1500°C, originated test specimens with a compressive strength of 48.1MPa at 28 days. Test specimens produced with clinker containing 5% phosphogypsum present higher compressive strength values at 28 days, being 55.1MPa for clinkers produced at 1500°C, and 49.4 MPa for clinkers produced at 1350°C.

Preparation of Low-Heat Portland Cement Clinker with Coal Gangue

2011 ◽  
Vol 306-307 ◽  
pp. 861-864
Author(s):  
Guang Li Chen ◽  
Xing Hua Fu ◽  
Wen Hong Tao
Keyword(s):  
Portland Cement ◽  
Calcium Silicate ◽  
Calcium Silicate Hydrate ◽  
Raw Materials ◽  
Coal Gangue ◽  
Cement Clinker ◽  
Mix Proportion ◽  
Portland Cement Clinker ◽  
Hydration Characteristics

A kind of low-heat Portland cement clinker was prepared with coal gangue, limestone and gypsum through optimizing the mix proportion of raw materials, and its properties and hydration characteristics were studied. The results showed that the cement clinker meeting the demands of mid (low)-heat Portland cement standard could be prepared with 35% (by weight, the same below) coal gangue, 57-60% limestone and 6-8% gypsum. The raw materials were burned at 1380°C for 40 minutes. The main hydrates were calcium silicate hydrate (C-S-H) gel, ettringite (AFt), monosulfate (AFm) and Ca(OH)2.

scholarly journals Application of the system-object approach to simulation of the conversion of raw materials into a portlandcement clinker

2021 ◽  
Vol 6 (3) ◽  
pp. 65-71
Author(s):  
Nikita G. Reznikov ◽  
◽  
Alexander G. Zhikharev ◽  
Keyword(s):  
Experimental Data ◽  
Chemical Composition ◽  
Portland Cement ◽  
Simulation Model ◽  
Raw Materials ◽  
Cement Clinker ◽  
Simulation Environment ◽  
Portland Cement Clinker ◽  
Two Component

The article discusses the construction of a simulation model of the abstract process of converting raw materials into Portland cement clinker in the UFOModeler simulation environment. An algorithm for generating a pseudo-random oxide (chemical) composition of components based on experimental data of real production and calculation for two-component and three-component raw mixtures has been developed. An algorithm for calculating the main indicators of the composition of clinker based on. The analysis of the obtained results is carried out.

MANUFACTURE OF MODIFIED ARBOLIT FROM LOCAL RAW MATERIALS: OPTIMIZATION OF COMPOSITION AND PROPERTIES OF RAW MATERIAL COMPONENTS

2019 ◽  
Vol 16 (3) ◽  
pp. 352-365
Author(s):  
A. K. Matyeva
Keyword(s):  
Phosphoric Acid ◽  
Portland Cement ◽  
Raw Materials ◽  
Porous Polymer ◽  
Raw Material ◽  
Cement Clinker ◽  
Liquid Sodium ◽  
Kyrgyz Republic ◽  
Portland Cement Clinker ◽  
Clay Component

Introduction. The creation of energy-saving materials involves the use of local raw materials for products with improved physic-mechanical properties. The author carries optimization of the rational composition and properties of modified arbolite from plant-gypsum composition (PGC). In addition, the author uses modifiers on new ways of preparing the aggregate according to the method of experimental and statistical modeling.Materials and methods. The author used the cereal straw grown in the Kyrgyz Republic (CS), G-5 and G-7 construction gypsum based on local raw materials, ash from the Bishkek Heat and Power Plant (BHPP), portland cement clinker PCC, natural clay (ganch). Moreover, the clay component of the Toloykonsky deposit was used as the clay component. The author also added the liquid glass, latex SCS, the low-concentration resin LCR-3066 + catalyst of ionic type (CIT) as modifiers for the formation of the porous polymer-silicate systems. The paper marked the plasticizing additives in the manufacture of arbolite as SCS, LCR and CIT components. As a retarder the setting of gypsum was added a partial salt 1-hydroxyethylidene-1, 1-diphosphonic acid with triethanolamine and flame retardants. The tests were carried out according to standard methods. To optimize the composition and properties of the polymersilicate-gypsum composition (PSGC), the author carried out a three-factor experiment according to the B3 plan, where three prescription factors varied: X1 – straw content,%; X2 – content of polymer silicate additives (PSA) + plasticizer,%; X3 – gypsum content + portland cement clinker as a nitroperimethyl phosphoric acid (NPA) and flame gypsum retarder.Results. The research showed that at 28 days of age for cement-free gypsum compositions as the content of straw increased, the strength was almost unchanged. When comparing the strength of the same samples of 2 and 28 days strength with the maximum filling of gypsum, the author defined that the PSA content should not exceed 12% when the straw additive was 26% and further PSA increasing did not increase the strength.Discussion and conclusions. As a result, the author achieves maximum strength of the arbolit, when the content of G-7 gypsum is 28-32%, ash is 18-22% and PSC is 8-10%. The maximum value of strength and water resistance of the material is achieved with a rational ratio of components: straw – 24–28%, G-7 gypsum – 30–32% + NSPL – 0,05%; ash – 18–22%; resin – 3066-8-12% + catalyst – 0,3% (87% sulfuric acid, 13% phosphoric acid); PCC – 3–5%; clay-gypsum (ganch) – 2%; liquid sodium glass – 12%; plasticizers CIT – 0,15%, SCS – 0,2%, LCR – 0,15%; modified hardener – 0,5% and water.

scholarly journals PORTLAND CEMENT WITH NATURAL MINERAL ADDITIVES

2019 ◽  
pp. 192-201 ◽  
Author(s):  
A. E. Mestnikov ◽  
A. I. Kudyakov ◽  
V. N. Rozhin
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Setting Time ◽  
Standard Test ◽  
Cement Clinker ◽  
The Arctic ◽  
Natural Mineral ◽  
The North ◽  
Portland Cement Clinker ◽  
Mineral Additives

One of the most effective developments of energy saving in the production of Portland cement used worldwide, is joint grinding of Portland cement clinker with injected mineral additives, such as pozzolanic rocks, ashes and slags.The aim of this work is to substantiate the possibility of the quality cement production using joint grinding of Portland cement clinker with natural mineral additives with a view to the of production location.River (quartz-feldspar) sands of the Lena basin and large-tonnage raw materials (zeolitecontaining rocks of the Khonguruu deposit) are considered as mineral additives to Portland cement. The study uses both standard test methods and the X-ray phase analysis for binders and concretes.The activity of the mineral additives to Portland cement is studied. The main properties of clinker, gypsum stone and mineral additives are studied to organize the production of quality Portland cement and products for the support of construction projects in the North-Eastern part of the Arctic and the North of Russia. The effect from additives and fineness of zeolitecontaining clinker and quartz-feldspar sand is studied relative to the thickness and setting time of the cement paste and cement mortar strength.It is shown that the types CEM II/A-P 32.5N and CEM II / A-P 42.5N Portland cement can be produced from imported Portland cement clinker and local mineral additives saving 5–15 % Portland cement clinker.

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