scholarly journals Moroccan oil shale and coal waste as alternative raw materials in Portland cement clinker manufacture. Clinkerisation reactions and clinker characterisation

2018 ◽  
Vol 68 (331) ◽  
pp. 166
Author(s):  
S. Chhaiba ◽  
M. T. Blanco-Varela ◽  
A. Diouri
Keyword(s):  
Particle Size ◽  
Oil Shale ◽  
Raw Materials ◽  
Cement Industry ◽  
Cement Clinker ◽  
Waste Materials ◽  
Coal Waste ◽  
Energy Costs ◽  
Portland Cement Clinker ◽  
Cement Manufacture

For some time the cement industry has been seeking procedures to effectively lower the higher energy costs involved in cement manufacture. Timahdit oil shale and Jerada coal waste could potentially be used as alternative raw materials to produce clinker. This study explored the possibility of applying those materials to a greener use, based on the reactivity and burnability of raw mixes containing Moroccan oil shale and coal waste. The findings showed that, irrespective of particle size, oil shale mixes delivered higher reactivity than coal waste materials, although reactivity was highest in the oil shale clinker with a particle size < 45 μm. The clinkers bearing oil shale with a particle size < 90 μm or a blend of oil shale and coal waste with a size < 45 μm contained higher proportions of alite ( > 70 %).

scholarly journals METHODS OF REPEATED USE OF CEMENT DUST

2019 ◽  
Author(s):  
М.Ш. Саламанова ◽  
С.А. Алиев ◽  
Р.С.-А. Муртазаева
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Cement Industry ◽  
Cement Clinker ◽  
Liquid Sodium ◽  
Portland Cement Clinker ◽  
Repeated Use ◽  
Electrostatic Precipitators ◽  
Rotary Kilns ◽  
Technogenic Raw Materials

В процессе обжига портландцементного клинкера в электрофильтрах вращающихся печей скапливается большое количество пыли, как клинкерной, так и аспирационной, поэтому рациональное использование этих продуктов, содержащих определенную долю полноценного сырьевого ресурса, является актуальной задачей индустрии цемента. В данной работе представлены результаты исследований цементной пыли, проведен энергодисперсионный и сравнительный анализ исследуемых порошков, а также приводится возможный способ утилизации цементной пыли для получения бесклинкерных цементов щелочной активации и бетонов на их основе. Разработанные рецептуры бесклинкерных вяжущих с применением отходов цементной промышленности и натриевого жидкостекольного затворителя позволят получать менее затратные, прочные и долговечные композиты, которые позволят частично заменять традиционный бетон на дорогом портландцементе. Работа выполнена в рамках исследований по реализации научного проекта 1848200001 Высококачественные бетоны с повышенными эксплуатационными свойствами на основе местного природного и техногенного сырья , получившего поддержку Российского фонда фундаментальных исследований (РФФИ). In the process of firing Portland cement clinker in electrostatic precipitators, in rotary kilns, a large amount of harmful substances, both clinker and aspiration, accumulates, therefore rational use of these products leads to certain shares of a fullfledged river resource, which are derived from industrial cement. It should be noted that the reuse of dust electrostatic precipitators is impossible. The basis for obtaining durable and more resourceefficient composites is based on modern technological methods that contribute to the improvement of technical and physicomechanical properties, with the integrated application of technogenic raw materials and liquid sodium binder. The developed clinkerfree binder formulations using the cement industry wastes and sodiumbased sludge glass will make it possible to produce less expensive, durable, and durable composites that will partially replace traditional concrete with expensive portland cement.

scholarly journals Utilization of Iron Ore Tailings as Raw Material for Portland Cement Clinker Production

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Li Luo ◽  
Yimin Zhang ◽  
Shenxu Bao ◽  
Tiejun Chen
Keyword(s):  
Portland Cement ◽  
Iron Ore ◽  
Mechanical Performance ◽  
Mineralogical Composition ◽  
Cement Industry ◽  
Raw Material ◽  
Cement Clinker ◽  
Iron Ore Tailings ◽  
Portland Cement Clinker ◽  
Clinker Production

The cement industry has for some time been seeking alternative raw material for the Portland cement clinker production. The aim of this research was to investigate the possibility of utilizing iron ore tailings (IOT) to replace clay as alumina-silicate raw material for the production of Portland cement clinker. For this purpose, two kinds of clinkers were prepared: one was prepared by IOT; the other was prepared by clay as a reference. The reactivity and burnability of raw meal, mineralogical composition and physical properties of clinker, and hydration characteristic of cement were studied by burnability analysis, differential thermal analysis, X-ray diffraction, and hydration analysis. The results showed that the raw meal containing IOT had higher reactivity and burnability than the raw meal containing clay, and the use of IOT did not affect the formation of characteristic mineralogical phases of Portland cement clinker. Furthermore, the physical and mechanical performance of two cement clinkers were similar. In addition, the use of IOT was found to improve the grindability of clinker and lower the hydration heat of Portland cement. These findings suggest that IOT can replace the clay as alumina-silicate raw material for the preparation of Portland cement clinker.

scholarly journals A Proposition of an In Situ Production of a Blended Cement

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2289 ◽  
Author(s):  
Jacek Halbiniak ◽  
Jacek Katzer ◽  
Maciej Major ◽  
Izabela Major
Keyword(s):  
Research Program ◽  
Raw Materials ◽  
Blended Cement ◽  
Cement Industry ◽  
Waste Materials ◽  
Long Distance ◽  
Cement Production ◽  
Concrete Production

Many byproducts and waste materials with pozzolanic properties can substitute natural raw materials in cement production. Some of these waste materials like fly ash and blast furnace slag are commonly harnessed by cement industry. Others are of seldom use due to limitations of the very centralized cement production systems currently in use. In the authors opinion, it is necessary to change this system to enable efficient utilization of various waste materials that are available locally (e.g., white and red ceramics). In this study, a new partially centralized system of cement production is proposed. The adoption of a new system would significantly reduce the volume of long-distance transportation and enable utilization of numerous locally available waste materials that are currently dismissed. The last stage of production of the ready-to-use cement would take place in situ. The cement would be produced on demand and be immediately used for concrete production on-site. The research program was conducted considering the importance of the quality of cements obtained in the new way, substituting up to 12% of its mass by white ceramics. The research program was proof of concept of the proposed cement production system. It was shown that the quality of “in situ cement” does not differ from standard cements.

scholarly journals OPTIMIZATION OF RAW MIX COMPOSITION OF SEREBRYANSKY CEMENT PLANT

2020 ◽  
pp. 13-20
Author(s):  
M. Nikitina ◽  
A. Erygina ◽  
T.I. Timoshenko
Keyword(s):  
Cost Efficiency ◽  
Raw Materials ◽  
Cement Industry ◽  
Cement Clinker ◽  
Chemical Transformations ◽  
The Moment ◽  
Physical And Chemical ◽  
To Receive ◽  
Selection Of

now a top trend of technical development in the cement industry of Russia, is optimization of all technological repartitions of production. Obtaining the quality portlandtsement is multiple-factor process. It is influenced not only by the physical and chemical transformations of raw materials occurring during the firing of cement clinker, but also what will be the composition of the raw mixture and whether this mixture is prepared qualitatively. Work consists in a research and selection of an optimum compounding of raw mix, with the purpose to receive cement with high rates of quality. This direction will allow: first, to expand a source of raw materials, to process raw materials which go to dumps because in it is mute a large amount of quartz and impurity connections contains; secondly, to make small reconstruction of the line of preparation of raw mix. At the moment, the plant works on mixed mixtures of aluminosilicate raw materials, i.e. two types of aluminosilicate raw materials which are previously mixed in certain ratios therefore it affects on the accuracy of dispensing of components are used. Accuracy of dispensing of modern batchers, a component ± (1 … 2) %, is often insufficient. In this regard, the new option of optimum composition of mix is offered and investigated. This option of a "clean" mixing of components, will allow to improve process of mixing of initial raw materials, to operate process of drawing up proportions of mixes in a supply line of materials. And also it will allow to eliminate long-term deviations, guaranteeing the solution of problems at the earliest stage of their emergence. Receiving a qualitative ready-made product, reduction of costs for energy resources and cost efficiency of the proposed solution is result of this work

scholarly journals STRUCTURE AND PROPERTIES OF CONNECTING ALKALINE ACTIVATION USING CEMENT DUST

2019 ◽  
Vol 46 (2) ◽  
pp. 148-157
Author(s):  
S. A. Aliev ◽  
R. S.-A. Murtazayevа ◽  
M. Sh. Salamanova
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Physicomechanical Properties ◽  
Cement Industry ◽  
Cement Clinker ◽  
Liquid Sodium ◽  
Electrostatic Precipitators ◽  
Rotary Kilns ◽  
Technogenic Raw Materials ◽  
Technological Methods

Objectives In the process of firing Portland cement clinker in electrostatic precipitators, in rotary kilns, a large amount of harmful substances, both clinker and aspiration, accumulates, therefore rational use of these products leads to certain shares of a full-fledged river resource, which are derived from industrial cement. It should be noted that the reuse of dust electrostatic precipitators is impossible.Method The basis for obtaining durable and more resource-efficient composites is based on modern technological methods that contribute to the improvement of technical and physicomechanical properties, with the integrated application of technogenic raw materials and liquid sodium binder.Result The basis for obtaining durable and more resource-efficient composites is based on modern technological methods that contribute to the improvement of technical and physicomechanical properties, with the integrated application of technogenic raw materials and liquid sodium binder.Conclusion The developed clinker-free binder formulations using the cement industry wastes and sodium-based sludge glass will make it possible to produce less expensive, durable, and durable composites that will partially replace traditional concrete with expensive portland cement. 

Life Cycle Assessment of Comprehensive Utilization of Calcium Carbide Slag in Cement Kiln

2020 ◽  
Vol 993 ◽  
pp. 1487-1495
Author(s):  
Xin Ping Lin ◽  
Ai Wei Liu ◽  
Yun Fa Feng ◽  
Qi Ling Chen ◽  
Tao Chen ◽  
...  
Keyword(s):  
Life Cycle Assessment ◽  
Emission Reduction ◽  
Calcium Carbide ◽  
Cement Industry ◽  
Cement Clinker ◽  
Cement Kiln ◽  
Cement Production ◽  
Comprehensive Utilization ◽  
Carbide Slag ◽  
Portland Cement Clinker

The recycling utilization of solid waste is an important technical means for the sustainable development of the cement industry in China. Calcium carbide slag is a special solid waste in China, which can be used for cement production with a great advantage on CO2 emission reduction. With an view to providing methodological and data support for the development of policies in the cement industry, this paper quantitatively analyzes the environmental effects/environmental benefits of the comprehensive utilization of calcium carbide slag in cement kiln by comparing the traditional system of Portland cement clinker completely produced by natural resources with the system of cement clinker produced by calcium carbide slag based on the life cycle assessment (LCA) method given in standards and specifications of ISO 14040 series. The results show that the latter system has a better effect in material saving and carbon emission reduction, will increase the energy consumption in cement production process, and also slightly increase other pollutants (e.g. SOx, NOx, etc.) emission. The GWP, AP and EP indicators of the calcium carbide slag cement clinker system decrease compared with those of the Portland cement clinker system, while other indicators do not differ much or even slightly increase.

Effect of Phosphogypsum on the Clinkerization Temperature of Portland Cement Clincker

2012 ◽  
Vol 730-732 ◽  
pp. 94-99 ◽  
Author(s):  
Maria Margarida Rolim Augusto Lima ◽  
L.F.C. Braz ◽  
Regina da Conceição Corredeira Monteiro ◽  
J.P. Veiga
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Raw Materials ◽  
Cement Clinker ◽  
X Ray Diffraction ◽  
X Ray ◽  
Portland Cement Clinker ◽  
Alternative Material ◽  
Heating Up ◽  
Mineralogical Compositions

Phosphogypsum (PG) is a pollutant residue resulting from the production of phosphoric acid in the phosphated fertilizers industry. About 180 millions of tons of PG are generated worldwide per year, which originates storage problems because of the environmental restrictions and the high costs of storage spaces. Taking into account the mineralizer properties of PG it has been studied a way to valorize this residue as an alternative material in the production of Portland cement clinker. The PG and the raw-materials (limestone, marl, sand and iron oxide) were chemical, mineralogical and thermally characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD) and differential thermal analysis and termogravimetric analysis (DTA/TGA). After milling, the phosphogypsum was mixed with the raw-materials in different amounts up to 10% weight. The raw mixtures were submitted to two types of firing schedules, heating up to 1500°C without any holding time or heating up to 1350°C and holding for 20 minutes. After firing, the clinkers were analyzed by optical microscopy, milled and characterized in terms of chemical and mineralogical compositions. The clinkers were used to produce cement mortar according to NP EN 196-1 standard. The resultant test specimens were mechanically tested at 2 and 28 days according to the same standard. The obtained results show a reduction of about 140°C in the clinkerization temperature, when a raw mixture with 5% phosphogypsum was used. Standard clinkers, without phosphogypsum addition, which were fired at 1500°C, originated test specimens with a compressive strength of 48.1MPa at 28 days. Test specimens produced with clinker containing 5% phosphogypsum present higher compressive strength values at 28 days, being 55.1MPa for clinkers produced at 1500°C, and 49.4 MPa for clinkers produced at 1350°C.

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