Enhanced photocatalytic performance of electrospun hollow titanium dioxide nanofibers decorated with graphene quantum dots

2020 ◽  
Vol 56 (3) ◽  
pp. 2138-2149 ◽  
Author(s):  
Peipei Huo ◽  
Peng Zhao ◽  
Xiaobo Shi ◽  
Ziyan Zhou ◽  
Bo Liu
RSC Advances ◽  
2016 ◽  
Vol 6 (108) ◽  
pp. 106508-106515 ◽  
Author(s):  
Yan Li ◽  
Lifeng Wang ◽  
Juan Ge ◽  
Jun Wang ◽  
Qiyao Li ◽  
...  

GQDs surface modified ZnO + Cu heterostructure photocatalysts was prepared via a simple spin-coating and annealing process, which exhibits enhanced photocatalytic performance.


Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 438 ◽  
Author(s):  
Fei Li ◽  
Ming Li ◽  
Yi Luo ◽  
Ming Li ◽  
Xinyu Li ◽  
...  

In this study, nitrogen-doped graphene quantum dots (N-GQDs) and a TiO2 nanocomposite were synthesized using a simple hydrothermal route. Ammonia water was used as a nitrogen source to prepare the N-GQDs. When optically characterized by UV-vis, N-GQDs reveal stronger absorption peaks in the range of ultraviolet (UV) light than graphene quantum dots (GQDs). In comparison with GQDs/TiO2 and pure TiO2, the N-GQDs/TiO2 have significantly improved photocatalytic performance. In particular, it was found that, when the added amount of ammonia water was 50 mL, the content of pyridinic N and graphitic N were as high as 22.47% and 31.44%, respectively. Most important, the photocatalytic activity of N-GQDs/TiO2-50 was about 95% after 12 min. The results illustrated that pyridinic N and graphitic N play a significant role in photocatalytic performance.


2020 ◽  
Vol 10 (2) ◽  
pp. 596 ◽  
Author(s):  
Fubao Zhang ◽  
Chen Yang ◽  
Xiao-Xiong Wang ◽  
Ru Li ◽  
Zhong Wan ◽  
...  

We report the fabrication of polyvinylidene fluoride (tetrabutyl titanate)/polyvinyl pyrrolidone ((tetrabutyl titanate))-graphene quantum dots [PVDF(TBT)/PVP(TBT)-GQDs] film photocatalyst with enhanced photocatalytic performance. The polyvinylidene fluoride (tetrabutyl titanate)/polyvinyl pyrrolidone ((tetrabutyl titanate)) [PVDF(TBT)/PVP(TBT)] film was first prepared with a dual-electrospinning method and then followed by attaching graphene quantum dots (GQDs) to the surface of the composite film through a hydrothermal method. Later, part of the PVP in the composite film was dissolved by a hydrothermal method. As a result, a PVDF(TBT)/PVP(TBT)-GQDs film photocatalyst with a larger specific surface area was achieved. The photocatalytic degradation behavior of the PVDF(TBT)/PVP(TBT)-GQDs film photocatalyst was examined by using Rhodamine B as the target contaminant. The PVDF(TBT)/PVP(TBT)-GQDs photocatalyst showed a higher photocatalytic efficiency than PVDF(TBT)-H2O, PVDF(TBT)/PVP(TBT)-H2O, and PVDF(TBT)-GQDs, respectively. The enhanced photocatalytic efficiency can be attributed to the broader optical response range of the PVDF(TBT)/PVP(TBT)-GQDs photocatalyst, which makes it useful as an effective photocatalyst under white light irradiation.


2018 ◽  
Vol 6 (3) ◽  
pp. 255-269 ◽  
Author(s):  
Zhigang Chen ◽  
Zhenzhen Zhao ◽  
Jinyuan Liu ◽  
Xingwang Zhu ◽  
Liang Wang ◽  
...  

Molecules ◽  
2019 ◽  
Vol 24 (2) ◽  
pp. 344 ◽  
Author(s):  
Xiong Sun ◽  
Hui-Jun Li ◽  
Nanquan Ou ◽  
Bowen Lyu ◽  
Bojie Gui ◽  
...  

Nitrogen doped graphene quantum dots (NGQDs) were successfully prepared via a hydrothermal method using citric acid and urea as the carbon and nitrogen precursors, respectively. Due to different post-treatment processes, the obtained NGQDs with different surface modifications exhibited blue light emission, while their visible-light absorption was obviously different. To further understand the roles of nitrogen dopants and N-containing surface groups of NGQDs in the photocatalytic performance, their corresponding composites with TiO2 were utilized to degrade RhB solutions under visible-light irradiation. A series of characterization and photocatalytic performance tests were carried out, which demonstrated that NGQDs play a significant role in enhancing visible-light driven photocatalytic activity and the carrier separation process. The enhanced photocatalytic activity of the NGQDs/TiO2 composites can possibly be attributed to an enhanced visible light absorption ability, and an improved separation and transfer rate of photogenerated carriers.


2015 ◽  
Vol 17 (28) ◽  
pp. 18645-18652 ◽  
Author(s):  
Jun Wang ◽  
Yan Li ◽  
Juan Ge ◽  
Bo-Ping Zhang ◽  
Wan Wan

A Ag–graphene quantum dots (GQDs)–ZnO ternary photocatalyst was prepared using GQDs as both a reducing agent and a cation solvent. Photodegradation performance was improved because of the synergic effect of Ag and GQDs.


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