Microwave dielectric properties of (1−x)(Ca0.88Sr0.12)TiO3–x(Bi0.5Na0.5)TiO3 high dielectric constant ceramics

2017 ◽  
Vol 29 (5) ◽  
pp. 4035-4040 ◽  
Author(s):  
Qi Deng ◽  
Chun-e Huang ◽  
He Wang ◽  
Li Zhao ◽  
Chunying Shen
Author(s):  
Jiawen Shi ◽  
Xingyu Chen ◽  
Weijun Zhang ◽  
Haijun Mao ◽  
Fenglin Wang ◽  
...  

In this paper, the effects of glass-ceramics sintering aid, La2O3–B2O3–CaO–P2O5 (LBCP), on the sinterability, microstructure, and microwave dielectric properties of 0.5(Ca[Formula: see text]Nd[Formula: see text]TiO3–0.5(Li[Formula: see text]Nd[Formula: see text]TiO3 (CNT–LNT) ceramic have been investigated. The results indicated that LBCP glass-ceramics has good wettability to CNT–LNT (contact angle at 980[Formula: see text]C is 31.9[Formula: see text]), and it can be used as an effective sintering aid to reduce the sintering temperature of CNT–LNT ceramic from 1300[Formula: see text]C to 980[Formula: see text]C. LBCP glass-ceramics did not change the main crystal phase (perovskite structure) of the sample, but a small amount of LaBO3 and LaPO4 phases was precipitated. Since the LaBO3 and LaPO4 phases are low-loss phases, it is believed that the crystal phases can improve the dielectric properties of the sample, especially the dielectric loss. The samples with 10 wt.% of glass additive sintered for 4 h at 980[Formula: see text]C exhibit the optimized properties: a high dielectric constant of 80.8 and a [Formula: see text] value of 2031 GHz. The high [Formula: see text] and [Formula: see text] value, coupled with a relatively low sintering temperature, suggest that the optimized compositions have the potential to be used in microwave low-temperature co-fired ceramics applications.


2017 ◽  
Vol 726 ◽  
pp. 210-214
Author(s):  
Xu Wang ◽  
Ren Li Fu ◽  
Yue Xu ◽  
Yang Yang ◽  
Jun De Cai ◽  
...  

xBaZn2Ti4O11–(1-x)BaNd2Ti4O12 (x = 0.18–0.30) ceramics were prepared by solid-state reaction method and their microwave dielectric properties were investigated with the purpose of finding a microwave ceramics with high dielectric constant (εr), high quality factor (Q×f ) and zero temperature coefficient of resonant frequency (τf).The two phase system BaZn2Ti4O11–BaNd2Ti4O12 affected the unit cell volume and the microstructure, the microwave dielectric properties (εr, Q×f, τf). As increasing x from 0.18 to 0.30, the main phase composition was BaNd2Ti4O12. Therefore, the εr decreased from 64.9 to 60.3 and the Q×f values raised from 11,350GHz to 13,210GHz, and the τf values decreased from 7ppm/° to -5ppm/°.The 0.22BaZn2Ti4O11–0.78BaNd2Ti4O12 ceramics sintered at 1250°C for 4 h displayed the best dielectric constant εr,Q×f and τf, as 63.9, 12380 GHz and-0.1 ppm/° respectively.


2014 ◽  
Vol 04 (04) ◽  
pp. 1450034 ◽  
Author(s):  
Chian Heng Lee ◽  
Jumiah Hassan ◽  
Mansor Hashim ◽  
Raba'ah Syahidah Aziz ◽  
Norlaily Mohd Saiden

The desirable characteristics of Ba 6-3x Nd 8+2x Ti 18 O 54 include high dielectric constant, low loss tangent, and high quality factor developed a new field for electronic applications. The microwave dielectric properties of Ba 6-3x Nd 8+2x Ti 18 O 54, with x = 0.15 ceramics at different sintering temperatures (600–1300°C) were investigated. The phenomenon of polarization produced by the applied electric field was studied. The dielectric properties with respect to frequency from 1 MHz to 1.5 GHz were measured using Impedance Analyzer, and the results were compared and analyzed. The highest dielectric permittivity and lowest loss factor were defined among the samples. The complex dielectric modulus was evaluated from the measured parameters of dielectric measurement in the same frequency range, and used to differentiate the contribution of grain and grain boundary.


2011 ◽  
Vol 326 ◽  
pp. 127-130
Author(s):  
Xian Li Huang ◽  
Fu Ping Wang ◽  
Ying Song

In the present work, the microstructure and microwave dielectric properties of BaTi4O9 ceramics derived from a sol-gel precursor were presented. Density measuring results demonstrated that the largest densities of ceramic sample about 96.7% could be reached by virtue of a cool iso-static press and a sintering process at at 1300 °C for 6 hours. The dielectric constant (εr), quality factor (Q×f) and the temperature coefficients (τf) of the BaTi4O9 ceramic samples were 36.65, 28000 GHz, +20.2 ppm/°C, respectively. XRD, SEM and XPS were used to characterize the microstructure of the ceramics samples. Substantial Ti3+ was proposed to be the cause of dielectric loss.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Asad Ali ◽  
Sarir Uddin ◽  
Madan Lal ◽  
Abid Zaman ◽  
Zafar Iqbal ◽  
...  

AbstractSn-doped BaTi4O9 (BT4) dielectric ceramics were prepared by a mixed oxide route. Preliminary X-ray diffraction (XRD) structural study shows that the ceramic samples have orthorhombic symmetry with space group (Pnmm). Scanning electron microscopy (SEM) shows that the grain size of the samples decreases with an increase in Sn4+ content. The presence of the metal oxide efficient group was revealed by Fourier transform infrared (FTIR) spectroscopy. The photoluminescence spectra of the ceramic samples reported red color ~ 603, 604, 606.5 and 605 nm with excitation energy ~ 2.06, 2.05, 2.04 and 2.05 eV for Sn4+ content with x = 0.0, 0.3, 0.5, and 0.7, respectively. The microwave dielectric properties of these ceramic samples were investigated by an impedance analyzer. The excellent microwave dielectric properties i.e. high dielectric constant (εr = 57.29), high-quality factor (Qf = 11,852), or low-dielectric loss (3.007) has been observed.


1999 ◽  
Vol 14 (9) ◽  
pp. 3567-3570 ◽  
Author(s):  
Ji-Won Choi ◽  
Chong-Yun Kang ◽  
Seok-Jin Yoon ◽  
Hyun-Jai Kim ◽  
Hyung-Jin Jung ◽  
...  

The microwave dielectric properties of Ca[(Li1/3Nb2/3)1−xMx]O3−δ (M = Sn, Ti, 0 ≤ x ≤ 0.5) ceramics were investigated. In general, the ceramics prepared were multiphase materials. However, single-phase specimens having orthorhombic perovskite structure similar to CaTiO3 could be obtained in the vicinity of Sn = 0.2 to 0.3, and Ti = 0.2. As Sn concentration increased, the dielectric constant (εr) decreased and the quality factor (Q) significantly increased within the limited Sn concentration. As Ti concentration increased, the dielectric constant (εr) increased, the quality factor (Q) decreased, and the temperature coefficient of resonant frequency (τf) changed from a negative to positive value. The temperature coefficient of resonant frequency of 0 ppm/°C was realized at Ti = 0.2. The Q · fo value and εr for this composition were found to be 26100 GHz and 38.6, respectively.


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