Long term ageing of polyamide 6 and polyamide 6 reinforced with 30% of glass fibers: temperature effect

2018 ◽  
Vol 25 (7) ◽  
Author(s):  
Imen Ksouri ◽  
Nader Haddar
Author(s):  
Christian Windhoevel ◽  
Chendhil Periasamy ◽  
George Todd ◽  
Justin Wang ◽  
Bertrand Leroux ◽  
...  

2019 ◽  
Vol 30 (6) ◽  
pp. 2833-2843 ◽  
Author(s):  
Adam Gnatowski ◽  
Agnieszka Kijo-Kleczkowska ◽  
Rafał Gołębski ◽  
Kamil Mirek

Purpose The issues concerning the prediction of changes in properties of polymer materials as a result of adding reinforcing fibers are currently widely discussed in the field of polymer material processing. This paper aims to present strengths and weaknesses of composites based on polymer materials strengthened with fibers. It touches upon composite cracking at the junction of a matrix and its reinforcement. It also discusses the analysis of changes in properties of chosen materials as a result of adding reinforcing fibers. The paper shows improvement in the strength of polymer materials with fiber addition, which is extremely important, because these types of composites are used in the aerospace, automotive and electrical engineering industries. Design/methodology/approach Comparing the properties of matrix strength with fiber properties is practically impossible. Thus, fiber tensile strength and composite tensile strength shall be compared (González et al., 2011): tensile (glass fiber GF) = 900 [MPa], elongation ΔL≈ 0; yield point (polyamide 66) = 70−90 [MPa], elongation Δ[%] = 3,5-18; tensile (polyamide 66 + 15% GF) = 80-125 [MPa], elongation Δ[%] ≈ 0; tensile (polyamide 66 + 30% GF) = 190 [MPa], elongation Δ[%] ≈ 0; yield point (polyamide 6) = 45-85 [MPa], elongation Δ[%] = 4-15; tensile (polyamide 6 + 15% GF) = 80-125 [MPa], elongation Δ[%] ≈ 0; tensile (polyamide 6 + 30% GF) = 95-130 [MPa] elongation Δ[%] ≈ 0. Comparison of properties of selected polymers and composites is presented in Tables 1−10 and Figures 1 and 2. The measurement methodology is presented in detail in the paper Kula et al. (2018). The increase in fiber content (to the extent discussed) leads to the increase in yield strength stresses and hardness. The value of yield strength for polyamide with the addition of fiberglass grows gradually with the increase in fiber content. The hardness of the composite of polyamide with glass balls increases together with the increase in reinforcement content. The changes of these values do not occur linearly. The increase in fiber content has a slight impact on density change (the increase of about 1 g/mm3 per 10 per cent). Findings The use of polymers as a matrix allows to give composites features such as: lightness, corrosion resistance, damping ability, good electrical insulation and thermal and easy shaping. Polymers used as a matrix perform the following functions in composites: give the desired shape to the products, allow transferring loads to fibers, shape thermal, chemical and flammable properties of composites and increase the possibilities of making composites. Fiber-reinforced polymer composites are the effect of searching for new construction materials. Glass fibers show tensile strength, stiffness and brittleness, while the polymer matrix has viscoelastic properties. Glass fibers have a uniform shape and dimensions. Fiber-reinforced composites are therefore used to increase strength and stiffness of materials. Polymers have low tensile strength, exhibit high deformability. Polymers reinforced by glass fiber have a high modulus of elasticity and therefore provide better the mechanical properties of the material. Composites with glass fibers do not exhibit deformations in front of cracking. An increase in the content of glass fiber in composites increases the tensile strength of the material. Polymers reinforced by glass fiber are currently one of the most important construction materials and are widely used in the aerospace, automotive and electro-technical industries. Originality/value The paper presents the test results for polyethylene composites with 25 per cent and 50 per cent filler coming from recycled car carpets of various car makes. The tests included using differential scanning calorimetry, testing material hardness, material tensile strength and their dynamic mechanical properties.


Author(s):  
Hyon Wook Ji ◽  
Dan Daehyun Koo ◽  
Jeong-Hee Kang

Cured-in-place pipe (CIPP), as a kind of trenchless sewer rehabilitation technology, is a method to repair sewer pipe using unsaturated polyester resin. This study develops a CIPP liner using hot water or steam curing as well as glass fiber, in contrast to traditional methods, which use nonwoven fabric. Composite material samples were fabricated by combining liner materials using various methods, and the structural characteristics of the liners were compared and analyzed through short- and long-term flexural strength tests. A long-term test was conducted for 10,000 h, and the results revealed 13.3 times higher flexural strength and 8 times higher flexural modulus than the American Society for Testing Materials minimum criteria for CIPP short-term properties. The maximum creep retention factor was 0.64, thereby reducing the design thickness of the CIPP by up to 54%. The structural characteristics also improved when glass fibers were mixed with traditional CIPP liner, making it possible to reduce the thickness by 30%. Glass fibers result in high structural strength when combined with unsaturated polyester resin. Structural strength increased, even when glass fibers were mixed with traditional CIPP liner. The main contribution of this research is the development of a high strength CIPP liner and improvement of the structural properties of CIPP lining without using the specially formulated resin or lining materials.


2016 ◽  
Vol 819 ◽  
pp. 580-584
Author(s):  
Jamal Umer ◽  
Ivan Saprounov ◽  
Igor Emri ◽  
Barbara Zupančič ◽  
Muhammad Wakil Shahzad

Polymers always show time-dependent mechanical properties. In order to use polymers in engineering applications, long-term mechanical propertes should be characterized. Free volume theroy is the mostly used theory to predict and model the mechanical properties of polymers. The effect of temperature is modelled thorugh William-Landel-Ferry (WLF) equation, whereas, the combined effect of temperature and pressure is modelled by Filler-Moonan-Tschoegl (FMT) equation. Both of the models are based on free volume theory. A set of expermentations were performed to investigate the validity of free volume concpet for one of the most important engineering polymer; i.e. Polyamide-6.


2009 ◽  
Vol 48 (3) ◽  
pp. 526-536 ◽  
Author(s):  
Ying Shu ◽  
Xiaohe Li ◽  
Lin Ye
Keyword(s):  

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 678 ◽  
Author(s):  
Andreea Elena Miron (Lungu) ◽  
Marioara Moldovan ◽  
Cristina Alexandra Prejmerean ◽  
Doina Prodan ◽  
Mihaela Vlassa ◽  
...  

Reconstructive bone surgery of the head and neck could prove challenging in terms of postoperative healing and recovery. Fighting infection during the healing period is one of the critical factors of the long-term survival of an implant. The aim of the study was to develop an innovative composition suitable for an antibacterial craniofacial implant that should have the capacity to continuously and constantly release the amount of gentamicin necessary to prevent the post-surgical infections. For this purpose, a series of composite materials based on dimethacrylic monomers, hydroxyapatite and ZrO2, with (series B) or without the addition of polymethyl methacrylate (series A), reinforced with woven E-glass fibers (FRC) were obtained using the laminate lay-up process. Gentamicin was included in all FRC sample matrices to confer an antimicrobial effect. The results show that after extraction of the residual monomers from the FRC samples in different solvents (chloroform, acetone and ethyl alcohol), the cumulative amount of released gentamicin after 12 days was between 7.05–11.38 mg for A samples and 11.21–14.52 mg for B samples. The microbiological protocol showed that gentamicin induces a two weeks-lasting antimicrobial effect maintained over the minimal inhibitory concentration for P. aeruginosa and S. aureus.


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